公开(公告)号：US20160144345A1

公开(公告)日：2016-05-26

申请号：US14430026

申请日：2013-09-12

Applicant: JX NIPPON OIL & ENERGY CORPORATION

Inventor： Yoshiyuki NAGAYASU ,  Kazuaki HAYASAKA ,  Eri KOSAKA ,  Koshi TAKAHAMA

IPC: B01J23/75 ,  B01J23/89 ,  B01J35/10 ,  C10G2/00 ,  B01J37/08

CPC classification number: B01J23/75 ,  B01J21/08 ,  B01J23/462 ,  B01J23/8913 ,  B01J32/00 ,  B01J35/023 ,  B01J35/08 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1061 ,  B01J37/0201 ,  B01J37/0207 ,  B01J37/0244 ,  B01J37/08 ,  B01J37/18 ,  C10G2/00 ,  C10G2/332 ,  C10G2/333 ,  C10G2/334

Abstract: A process for producing a Fischer-Tropsch synthesis catalyst according to the present invention comprises a step of calcining a carrier precursor containing silica calcined at a temperature T1 and a zirconium compound at a temperature T2 to obtain a carrier; and a step of calcining a catalyst precursor containing the carrier and a cobalt compound and/or a ruthenium compound at a temperature T3, wherein the content of the zirconium compound in the carrier precursor is 0.01 to 7% by mass in terms of zirconium oxide based on the total mass of the catalyst, and T1, T2, and T3 satisfy conditions represented by expressions (1) to (3): T1≧T3  (1) 250° C.≦T2≦450° C.  (2) 250° C.≦T3≦450° C.  (3).

Abstract translation: 根据本发明的费 - 托合成催化剂的制造方法包括：在温度T2下煅烧含有在温度T1煅烧的二氧化硅的载体前体和锆化合物的步骤，得到载体; 以及在T3的温度下煅烧含有载体和钴化合物和/或钌化合物的催化剂前体的步骤，其中载体前体中的锆化合物的含量以氧化锆为基准计为0.01〜7质量％ 对于催化剂的总质量，T1，T2和T3满足由式（1）至（3）表示的条件：T1≥T3（1）250℃＆lt; L2; T2＆nlE; 450℃（2）250 ℃和nlE; T3＆nlE; 450℃（3）。

公开(公告)号：US20160136625A1

公开(公告)日：2016-05-19

申请号：US14902233

申请日：2014-07-03

Applicant: TOTAL RESEARCH & TECHNOLOGY FELUY ,  CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (CNRS)

Inventor： Kok-Giap HAW ,  Jean-Michel GOUPIL ,  Jean-Pierre GILSON ,  Valentin VALTCHEV ,  Nikolai NESTERENKO ,  Delphine MINOUX ,  Jean-Pierre DATH

IPC: B01J29/40 ,  B01J35/10 ,  B01J37/08 ,  C07C4/18

CPC classification number: B01J29/40 ,  B01J29/00 ,  B01J29/005 ,  B01J29/041 ,  B01J29/043 ,  B01J29/405 ,  B01J29/44 ,  B01J35/0006 ,  B01J35/0013 ,  B01J35/023 ,  B01J35/1019 ,  B01J35/1061 ,  B01J35/109 ,  B01J35/1095 ,  B01J37/0009 ,  B01J37/0201 ,  B01J37/0203 ,  B01J37/0207 ,  B01J37/0209 ,  B01J37/0211 ,  B01J37/0246 ,  B01J37/08 ,  B01J37/28 ,  B01J2229/18 ,  B01J2229/186 ,  B01J2229/20 ,  B01J2229/42 ,  B01J2229/62 ,  B01J2229/64 ,  C07C4/18 ,  C07C2529/068 ,  C07C2529/076 ,  C07C2529/40 ,  C07C2529/44 ,  C07C2529/48 ,  C07C2529/80 ,  C10G3/44 ,  C10G3/45 ,  C10G3/47 ,  C10G11/02 ,  C10G11/18 ,  C10G29/205 ,  C10G35/06 ,  C10G35/085 ,  C10G45/60 ,  C10G45/62 ,  C10G47/02 ,  C10G47/12 ,  C10G50/00 ,  Y02P20/52 ,  Y02P30/20 ,  C07C15/04 ,  C07C15/085

Abstract: A catalyst composition contains an inorganic porous material with pore diameters of at least 2 nm and of crystals of molecular sieve. The crystals of molecular sieve have an average diameter, measured by scanning electron microscopy, not bigger than 50 nm. The catalyst composition has a concentration of acid sites ranges from 50 to 1200 μmol/g measured by TPD NH3 adsorption. An XRD pattern of the catalyst composition is the same as an XRD pattern of the inorganic porous material.

Abstract translation: 催化剂组合物含有孔径至少为2nm的无机多孔材料和分子筛结晶。 分子筛晶体的平均直径通过扫描电子显微镜测得，不大于50nm。 该催化剂组合物通过TPD NH 3吸附测定的酸性位点浓度范围为50〜1200μmol/ g。 催化剂组合物的XRD图与无机多孔材料的XRD图谱相同。

公开(公告)号：US09339797B2

公开(公告)日：2016-05-17

申请号：US14124365

申请日：2012-05-29

Applicant: Raphael Idem ,  Ataullah Khan Mohammed ,  Bappy Saha

Inventor： Raphael Idem ,  Ataullah Khan Mohammed ,  Bappy Saha

IPC: C01B3/26 ,  B01J23/00 ,  B01J23/02 ,  B01J23/08 ,  B01J23/40 ,  B01J23/42 ,  B01J23/58 ,  B01J21/04 ,  B01J23/78 ,  C01B3/40 ,  B01J37/03 ,  B01J37/10 ,  B01J37/18 ,  B01J37/02 ,  B01J23/755 ,  B01J23/83 ,  B01J35/00 ,  B01J37/00 ,  B01J21/06 ,  B01J21/10 ,  B01J23/10

CPC classification number: B01J23/78 ,  B01J21/04 ,  B01J21/066 ,  B01J21/10 ,  B01J23/002 ,  B01J23/02 ,  B01J23/10 ,  B01J23/755 ,  B01J23/83 ,  B01J35/0053 ,  B01J35/0066 ,  B01J37/0018 ,  B01J37/009 ,  B01J37/0201 ,  B01J37/0205 ,  B01J37/031 ,  B01J37/10 ,  B01J37/18 ,  C01B3/26 ,  C01B3/40 ,  C01B2203/0238 ,  C01B2203/1052 ,  C01B2203/1058 ,  C01B2203/1082 ,  Y02P20/52 ,  B01J2523/00 ,  B01J2523/23 ,  B01J2523/31 ,  B01J2523/48 ,  B01J2523/22

Abstract: The present application describes a catalyst that is suitable for the CO2 reforming of methane-rich gases, such as biogas, that is resistant to poisoning by sulfur. The catalyst comprises from about 5 wt % to about 20 wt % Ni and 0 wt % to about 10 wt % Co supported on a support having a formula selected from: (a) Al2O3; (b) M1aOb—Al2O3; and (c) M1aOb—ZrO2—Al2O3, where M1aOb is either CaO or MgO.

Abstract translation: 本申请描述了一种适用于耐甲烷中毒的富甲烷气体如沼气的二氧化碳重整的催化剂。 催化剂包含约5重量％至约20重量％的Ni和0重量％至约10重量％的Co负载在具有选自以下的式的载体上：（a）Al 2 O 3; （b）M1aOb-Al2O3; 和（c）M1aOb-ZrO2-Al2O3，其中M1ab是CaO或MgO。

公开(公告)号：US09339796B2

公开(公告)日：2016-05-17

申请号：US13896578

申请日：2013-05-17

Applicant: Petroraza SAS

Inventor： Jose Edgar Patiño ,  Farid Bernardo Cortés

IPC: B01J23/755 ,  B01J35/00 ,  C10G49/04 ,  B01J23/89 ,  E21B43/00 ,  B01J35/02 ,  B01J21/04 ,  B01J35/10 ,  B01J37/02 ,  C10G1/08 ,  C10G11/02 ,  B01J23/78

CPC classification number: C10G11/04 ,  B01J21/04 ,  B01J23/755 ,  B01J23/78 ,  B01J23/892 ,  B01J23/8946 ,  B01J35/0013 ,  B01J35/002 ,  B01J35/006 ,  B01J35/023 ,  B01J35/1014 ,  B01J37/0201 ,  B01J37/0207 ,  C10G1/08 ,  C10G11/02 ,  C10G49/04 ,  C10G2300/4037 ,  E21B43/00

Abstract: Novel catalysts comprising nickel oxide nanoparticles supported on alumina nanoparticles, methods of their manufacture, heavy oil compositions contacted by these nanocatalysts and methods of their use are disclosed. The novel nanocatalysts are useful, inter alia, in the upgrading of heavy oil fractions or as aids in oil recovery from well reservoirs or downstream processing.

Abstract translation: 公开了包含负载在氧化铝纳米颗粒上的氧化镍纳米粒子的新型催化剂，其制造方法，与这些纳米催化剂接触的重油组合物及其使用方法。 新型纳米催化剂尤其可用于重油馏分的升级或作为从油井或下游加工中回收油的辅助工具。

公开(公告)号：US20160129424A1

公开(公告)日：2016-05-12

申请号：US14893643

申请日：2013-07-23

Applicant: HINDUSTAN PETROLEUM CORPORATION LTD. ,  INDIAN INSTITUTE OF TECHNOLOGY, DELHI ,  CENTRE FOR HIGH TECHNOLOGY (CHT)

Inventor： Kamal Kishore Pant ,  Sushil Kumar Saraswat ,  Annaji Rajiv Kumar Tompala ,  Kanaparthi Ramesh ,  Venkata Chalapathi Rao Peddy ,  Venkateswarlu Choudary Nettem ,  Sri Ganesh Gandham

IPC: B01J23/80 ,  C01B3/26 ,  C01B31/02 ,  B01J37/08 ,  B01J37/18

CPC classification number: B01J23/80 ,  B01J21/04 ,  B01J37/0201 ,  B01J37/031 ,  B01J37/035 ,  B01J37/08 ,  B01J37/18 ,  B82Y40/00 ,  C01B3/26 ,  C01B32/162 ,  C01B32/17 ,  C01B2202/34 ,  C01B2202/36 ,  C01B2203/0277 ,  C01B2203/1076 ,  C01B2203/1241 ,  C01P2004/04 ,  C01P2004/13 ,  C01P2004/61

Abstract: In accordance with the present subject matter there is provided a process for catalytic decomposition of lower hydrocarbons to produce carbon oxides free hydrogen and bamboo shaped carbon nanotubes over a catalyst composition. The process for catalytic decomposition of lower hydrocarbons comprises contacting lower hydrocarbon over a catalyst composition, where the catalyst composition comprising, a catalyst, at least one modifying agent and a support material.

Abstract translation: 根据本主题，提供了催化分解低级烃以在催化剂组合物上产生不含碳氧化物的氢和竹形碳纳米管的方法。 低级烃的催化分解方法包括使催化剂组合物上的低级烃接触，其中催化剂组合物包含催化剂，至少一种改性剂和载体材料。

公开(公告)号：US09333487B2

公开(公告)日：2016-05-10

申请号：US14539508

申请日：2014-11-12

Applicant: KING FAHD UNIVERSITY OF PETROLEUM AND MINERALS ,  KING ABDULAZIZ CITY FOR SCIENCE AND TECHNOLOGY

Inventor： Saleem Ur Rahman ,  Shakeel Ahmed ,  Mohammad Mozahar Hossain ,  Shahid Muhammad Bashir

IPC: B01J23/14 ,  B01J23/755 ,  C25B11/04 ,  B01J37/02 ,  B01J37/08 ,  B01J37/34

CPC classification number: B01J23/14 ,  B01J23/755 ,  B01J37/0201 ,  B01J37/0213 ,  B01J37/08 ,  B01J37/341 ,  C25B11/0452

Abstract: The catalytic composition for the electrochemical reduction of carbon dioxide is a metal oxide supported by multi-walled carbon nanotubes. The metal oxide may be nickel oxide (NiO) or tin dioxide (SnO2). The metal oxides form 20 wt % of the catalyst. In order to make the catalysts, a metal oxide precursor is first dissolved in deionized water to form a metal oxide precursor solution. The metal oxide precursor solution is then sonicated and the solution is impregnated in a support material composed of multi-walled carbon nanotubes to form a slurry. The slurry is then sonicated to form a homogeneous solid solution. Solids are removed from the homogeneous solid solution and dried in an oven for about 24 hours at a temperature of about 110° C. Drying is then followed by calcination in a tubular furnace under an argon atmosphere for about three hours at a temperature of 450° C.

Abstract translation: 用于二氧化碳的电化学还原的催化组合物是由多壁碳纳米管支撑的金属氧化物。 金属氧化物可以是氧化镍（NiO）或二氧化锡（SnO 2）。 金属氧化物形成20重量％的催化剂。 为了制备催化剂，首先将金属氧化物前体溶解在去离子水中以形成金属氧化物前体溶液。 然后将金属氧化物前体溶液超声处理，并将溶液浸渍在由多壁碳纳米管组成的载体材料中以形成浆料。 然后将浆液超声处理以形成均匀的固溶体。 将固体从均匀的固溶体中除去，并在烘箱中在约110℃的温度下干燥约24小时。然后在管式炉中在氩气气氛下在450℃的温度下煅烧约3小时 C。

公开(公告)号：US20160126561A1

公开(公告)日：2016-05-05

申请号：US14765721

申请日：2014-01-29

Applicant: JOHNSON MATTHEY FUEL CELLS LIMITED

Inventor： Rachel Louise O'MALLEY ,  Enrico PETRUCCO

IPC: H01M4/92 ,  H01M8/1018 ,  H01M8/1004

CPC classification number: H01M4/921 ,  B01J21/18 ,  B01J23/466 ,  B01J23/6484 ,  B01J23/6486 ,  B01J37/0201 ,  H01M4/86 ,  H01M4/881 ,  H01M4/8828 ,  H01M4/8842 ,  H01M4/925 ,  H01M4/926 ,  H01M8/1004 ,  H01M8/1018 ,  H01M2004/8684 ,  H01M2008/1095 ,  H01M2250/20 ,  H01M2300/0082 ,  Y02E60/521 ,  Y02T90/32

Abstract: A method of operating a fuel cell having an anode, a cathode and a polymer electrolyte membrane disposed between the anode and the cathode, includes feeding the anode with an impure hydrogen stream having low levels of carbon monoxide up to 5 ppm, and wherein the anode includes an anode catalyst layer including a carbon monoxide tolerant catalyst material, wherein the catalyst material includes: (i) a binary alloy of PtX, wherein X is a metal selected from the group consisting of Ti, V and Cr, and wherein the atomic percentage of platinum in the alloy is from 45 to 80 atomic % and the atomic percentage of X in the alloy is from 20 to 55 atomic %; and (ii) a support material on which the PtX alloy is dispersed; wherein the total loading of platinum in the anode catalyst layer is from 0.01 to 0.2 mgPt/cm2.

Abstract translation: 一种操作具有设置在阳极和阴极之间的阳极，阴极和聚合物电解质膜的燃料电池的方法包括向阳极供给具有低至5ppm的一氧化碳含量低的不纯氢气流，并且其中阳极 包括含有一氧化碳耐受性催化剂材料的阳极催化剂层，其中催化剂材料包括：（i）PtX的二元合金，其中X是选自Ti，V和Cr的金属，其中原子百分比 的合金中的铂为45〜80原子％，合金中的X的原子百分比为20〜55原子％。 和（ii）分散有PtX合金的载体材料; 其中铂在阳极催化剂层中的总负载量为0.01至0.2mgPt / cm 2。

公开(公告)号：US20160122260A1

公开(公告)日：2016-05-05

申请号：US14919626

申请日：2015-10-21

Applicant: Chevron U.S.A. Inc.

Inventor： Bi-Zeng Zhan ,  Stacey Ian Zones ,  Christopher M. Lew

IPC: C07C2/58

CPC classification number: C10G29/205 ,  B01J29/74 ,  B01J37/0201 ,  C07C2529/74 ,  C10G2400/02

Abstract: Provided is an improved alkylation process using a delaminated SSZ-70 catalyst. The process comprises contacting a hydrocarbon feedstock comprising olefins and isoparaffins with a catalyst comprising delaminated SSZ-70 under alkylating reaction conditions. The delaminated SSZ-70 offers a zeolite layer with a single unit cell of thickness in one dimension, allowing an elimination of mass transfer in comparison with regular SSZ-70. This prevents coke formation inside zeolite channels and improves catalyst stability.

Abstract translation: 提供了使用脱层SSZ-70催化剂的改进的烷基化方法。 该方法包括在烷基化反应条件下使包含烯烃和异链烷烃的烃原料与包含脱层SSZ-70的催化剂接触。 分层SSZ-70在一个维度上提供了具有单个单元电池单元的沸石层，与常规SSZ-70相比，可以消除传质。 这防止了沸石通道内的焦炭形成，并提高了催化剂的稳定性。

公开(公告)号：US20160114315A1

公开(公告)日：2016-04-28

申请号：US14918613

申请日：2015-10-21

Applicant: SHELL OIL COMPANY

Inventor： Alexei Grigorievich GABRIELOV

IPC: B01J31/02 ,  C10G45/08 ,  B01J37/02 ,  B01J31/34 ,  B01J31/28

CPC classification number: B01J31/0207 ,  B01J21/04 ,  B01J23/882 ,  B01J31/28 ,  B01J31/34 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1061 ,  B01J37/0201 ,  B01J37/0203 ,  B01J37/0205 ,  B01J37/28 ,  C10G45/08 ,  C10G2300/70

Abstract: A composition that comprises a support material having incorporated therein a metal component and impregnated with an additive compound that is an acetoacetic acid compound. The composition includes the support material that is impregnated with the additive compound and is useful in the hydroprocessing of hydrocarbon feedstocks, especially in the denitrogenation and desulfurization of distillate feedstocks to make ultra low sulfur diesel.

Abstract translation: 一种组合物，其包括其中掺入金属组分并浸渍有作为乙酰乙酸化合物的添加剂化合物的载体材料。 该组合物包括浸渍有添加剂化合物的载体材料，并且可用于烃原料的加氢处理，特别是在馏出物原料的脱氮和脱硫中以制备超低硫柴油。

公开(公告)号：US20160114314A1

公开(公告)日：2016-04-28

申请号：US14520978

申请日：2014-10-22

Applicant: King Fahd University of Petroleum and Minerals

Inventor： Mohammad Ashraf ALI ,  Shakeel Ahmed

IPC: B01J29/78 ,  B01J35/00 ,  B01J37/08 ,  B01J35/04 ,  B01J37/02 ,  C07C1/22 ,  B01J29/76

CPC classification number: B01J29/78 ,  B01J23/74 ,  B01J29/072 ,  B01J29/076 ,  B01J29/46 ,  B01J29/76 ,  B01J35/0006 ,  B01J35/04 ,  B01J37/0201 ,  B01J37/0215 ,  B01J37/0246 ,  B01J37/08 ,  C07C1/20 ,  C07C2529/46 ,  C07C2529/48 ,  C07C2529/76 ,  C07C2529/78 ,  Y02P20/52 ,  Y02P30/42 ,  C07C11/06

Abstract: A catalyst system and a process for methanol to light olefin conversion with enhanced selectivity towards propylene. The catalyst system comprises a honeycomb monolith catalyst support coated with nanozeolite catalysts on the edges and inside the channels of the support structure. The nanozeolite catalysts have been pre-modified with metal. The catalyst system gives higher hydrothermal stability to the catalyst compared to randomly packed pellet catalyst and allows methanol to be converted to predominantly propylene at a low temperature, with decreased selectivity towards C2, higher olefins and paraffinic hydrocarbons.

Abstract translation: 一种催化剂体系和一种甲醇使烯烃转化率降低的方法，对丙烯具有更高的选择性。 催化剂体系包括在支撑结构的通道的边缘和内部涂覆有纳米沸石催化剂的蜂窝单体催化剂载体。 纳米沸石催化剂已经用金属预先修饰。 与随机填充的颗粒催化剂相比，催化剂体系对催化剂具有更高的水热稳定性，并允许甲醇在低温下转化为主要的丙烯，对C2，高级烯烃和链烷烃的选择性降低。