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公开(公告)号：US20170183576A1
公开(公告)日：2017-06-29
申请号：US15390784
申请日：2016-12-27
Applicant: ExxonMobil Research and Engineering Company
Inventor： Timothy L. Hilbert , Michael B. Carroll , Ajit B. Dandekar , Sara L. Yohe , Stephen H. Brown , Tracie L. Owens , April D. Ross , Eric B. Senzer , Steven Pyl , Rugved P. Pathare , Lisa I-Ching Yeh , Bradley R. Fingland , Keith K. Aldous , Anjaneya S. Kovvali , Kendall S. Fruchey
IPC: C10G67/04 , C10M101/02
CPC classification number: C10G67/049 , C01B3/48 , C01B2203/0283 , C01B2203/065 , C10G55/02 , C10G65/043 , C10G67/04 , C10G67/0418 , C10G67/0445 , C10G67/0454 , C10G67/0463 , C10G67/0481 , C10G2300/1077 , C10G2300/202 , C10G2300/206 , C10G2300/301 , C10G2300/304 , C10G2400/10 , C10J3/82 , C10J2300/0906 , C10J2300/0913 , C10J2300/1618 , C10K1/004 , C10K3/04 , C10M101/02 , C10M2203/1006 , C10M2203/1085 , C10N2220/022 , C10N2220/023 , C10N2230/02
Abstract: Methods are provided for forming lubricant base stocks from feeds such as vacuum resid or other 510° C.+ feeds. A feed can be deasphalted and then catalytically and/or solvent processed to form lubricant base stocks, including bright stocks that are resistant to haze formation.
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公开(公告)号：US20190078027A1
公开(公告)日：2019-03-14
申请号：US16115775
申请日：2018-08-29
Applicant: ExxonMobil Research and Engineering Company
Inventor： Mark A. Deimund , Samia Ilias , Randolph J. Smiley , Ajit B. Dandekar , Scott J. Weigel , Darryl D. Lacy
Abstract: Systems and methods are provided for upgrading a heavy cracked feedstock in a single reaction stage under fixed bed hydroprocessing conditions, including exposing the feedstock to a first bulk or supported mixed metal catalyst comprising Ni and Mo; exposing the feedstock to a second bulk or supported mixed metal catalyst comprising Ni and W; and exposing the feedstock to a third catalyst comprising a zeolite-based hydrocracking catalyst.
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公开(公告)号：US20180105761A1
公开(公告)日：2018-04-19
申请号：US15715555
申请日：2017-09-26
Applicant: ExxonMobil Research and Engineering Company
Inventor： Jason T. Calla , Ajit B. Dandekar , Scott J. Weigel , Darryl D. Lacy , Wenyih F. Lai , Sara L. Yohe
IPC: C10M105/00 , B01J8/04 , C10G57/00 , C10G69/02
CPC classification number: C10M105/00 , B01J8/0492 , B01J29/0325 , B01J29/043 , C10G57/00 , C10G65/08 , C10G65/12 , C10G69/02 , C10G2300/302 , C10G2400/10 , C10M2203/003
Abstract: Systems and methods are provided for producing lubricant basestocks using a process flow that includes a conversion catalyst that can provide a desired improvement in viscosity index at a reduced or minimized amount of feed conversion. An initial processing stage can be used to produce a lubricant boiling range fraction with a reduced or minimized heteroatom content. After a separation, at least a portion of the lubricant boiling range portion can be exposed to a conversion catalyst that has an effective pore size of at least 8.0 Angstroms, a total surface area of at least 200 m2/g, and/or an Alpha value of 20 or less, where the conversion catalyst includes a supported Group 8-10 noble metal. The methods can allow for increased yields of high viscosity index lubricant boiling range products from a process flow for lubricant base stock and/or blend stock production.
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公开(公告)号：US20170283717A1
公开(公告)日：2017-10-05
申请号：US15468406
申请日：2017-03-24
Applicant: ExxonMobil Research and Engineering Company
Inventor： Ajit B. Dandekar , Bradley R. Fingland , Kendall S. Fruchey , Scott J. Weigel
IPC: C10G69/02 , C10M101/02
Abstract: Systems and methods are provided for producing lubricant basestocks having a reduced or minimized aromatics content. A first processing stage can perform an initial amount of hydrotreating and/or hydrocracking. A first separation stage can then be used to remove fuels boiling range (and lower boiling range) compounds. The remaining lubricant boiling range fraction can then be exposed under hydrocracking conditions to a USY catalyst including a supported noble metal, such as Pt and/or Pd. The USY catalyst can have a desirable combination of catalyst properties, such as a unit cell size of 24.30 or less (or 24.24 or less), a silica to alumina ratio of at least 50 (or at least 80), and an alpha value of 20 or less (or 10 or less). In some aspects, the effluent from the second (hydrocracking) stage can be dewaxed without further separation. In such aspects, a portion of the dewaxed effluent can be used as a recycle quench stream to cool the hydrocracking effluent prior to entering the dewaxing reactor.
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公开(公告)号：US09487723B2
公开(公告)日：2016-11-08
申请号：US13803378
申请日：2013-03-14
Applicant: ExxonMobil Research and Engineering Company
Inventor： Gretchen L. Holtzer , Ajit B. Dandekar , Charles L. Baker, Jr. , Bradley R. Fingland , Bryan E. Hagee , Cathleen Yung , Frank C. Wang , Eugenio Sanchez , Rugved Prakash Pathare
IPC: C07F5/04 , C10G71/00 , C10G65/00 , C10G63/02 , C10M101/02 , C10G69/02 , C10G45/64 , C10G65/04 , C10G65/12 , C10L1/08 , B01J29/74 , B01J35/02
CPC classification number: C10M101/02 , B01J29/7461 , B01J35/026 , B01J2229/36 , B01J2229/42 , C10G45/64 , C10G65/00 , C10G65/043 , C10G65/12 , C10G69/02 , C10G71/00 , C10G2300/1059 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , C10G2300/302 , C10G2300/4081 , C10G2400/02 , C10G2400/04 , C10G2400/10 , C10L1/08
Abstract: Provided are high viscosity high quality Group II lube base stocks with improved properties produced by an integrated hydrocracking and dewaxing process. In one form, the Group II lube base stock includes greater than or equal to 90 wt. % saturates, and less than 10 wt. % aromatics, and has an aromatic performance ratio between 1.0 and 5.0. Also provided are lubricant formulations including the high viscosity high quality Group II lube base stock.
Abstract translation: 提供了通过一体化加氢裂化和脱蜡过程产生的具有改进性能的高粘度高品质II组润滑油基础油料。 在一种形式中，II组润滑油基础油包含大于或等于90wt。 ％饱和，小于10wt。 ％的芳族化合物，并且具有1.0至5.0的芳族性能比。 还提供润滑剂配方，包括高粘度高质量的II组润滑油基础油。
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Patent Agency Ranking
16.发明授权公开(公告)号：US08932454B2
公开(公告)日：2015-01-13
申请号：US13719634
申请日：2012-12-19
Applicant: ExxonMobil Research and Engineering Company
Inventor： Jianxin Jason Wu , Ajit B. Dandekar , Christopher G. Oliveri
IPC: C10G47/18 , C10G47/20 , B01J29/16 , B01J29/12 , B01J37/10 , B01J29/08 , B01J35/10 , C01B39/24 , B01J29/14 , C01B39/02
CPC classification number: B01J29/126 , B01J29/084 , B01J29/088 , B01J29/146 , B01J29/166 , B01J35/109 , B01J37/10 , B01J2229/16 , B01J2229/20 , B01J2229/22 , B01J2229/36 , B01J2229/42 , C01B39/026 , C01B39/24 , C10G47/18 , C10G47/20
Abstract: This invention relates to the composition, method of making and use of a hydrocracking catalyst that is comprised of a new Y zeolite which exhibits an exceptionally low small mesoporous peak around the 40 Å (angstrom) range as determined by nitrogen adsorption measurements. The hydrocracking catalysts of invention exhibit improved distillate yield and selectivity as well as improved conversions at lower temperatures than conventional hydrocracking catalysts containing Y zeolites. The hydrocracking catalysts herein are particularly useful in the hydrocracking processes as disclosed herein, particularly for conversion of heavy hydrocarbon feedstocks such as gas oils and vacuum tower bottoms and an associated maximization and/or improved selectivity of the distillate yield obtained from such hydrocracking processes.
Abstract translation: 本发明涉及由新型Y沸石组成的加氢裂化催化剂的组合物，制备和使用方法，其通过氮吸附测量测定显示在大约40埃（埃）范围内具有极低的小介孔峰。 本发明的加氢裂化催化剂在比含有Y沸石的常规加氢裂化催化剂更低的温度下显示出提高的馏出物产率和选择性以及改进的转化率。 本文所述的加氢裂化催化剂特别适用于本文公开的加氢裂化方法，特别是用于转化重质烃原料如瓦斯油和真空塔底物，以及相应的最大化和/或从这些加氢裂化方法获得的馏出物产率的选择性提高。
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公开(公告)号：US20130264246A1
公开(公告)日：2013-10-10
申请号：US13803378
申请日：2013-03-14
Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
Inventor： Gretchen L. Holtzer , Ajit B. Dandekar , Charles L. Baker , Bradley R. Fingland , Bryan E. Hagee , Cathleen Yung , Frank C. Wang , Eugenio Sanchez , Rugved Prakash Pathare
IPC: C10M101/02 , C10G69/02
CPC classification number: C10M101/02 , B01J29/7461 , B01J35/026 , B01J2229/36 , B01J2229/42 , C10G45/64 , C10G65/00 , C10G65/043 , C10G65/12 , C10G69/02 , C10G71/00 , C10G2300/1059 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , C10G2300/302 , C10G2300/4081 , C10G2400/02 , C10G2400/04 , C10G2400/10 , C10L1/08
Abstract: Provided are high viscosity high quality Group II lube base stocks with improved properties produced by an integrated hydrocracking and dewaxing process. In one form, the Group II lube base stock includes greater than or equal to 90 wt. % saturates, and less than 10 wt. % aromatics, and has an aromatic performance ratio between 1.0 and 5.0. Also provided are lubricant formulations including the high viscosity high quality Group II lube base stock.
Abstract translation: 提供了通过一体化加氢裂化和脱蜡过程产生的具有改进性能的高粘度高品质II组润滑油基础油料。 在一种形式中，II组润滑油基础油包含大于或等于90wt。 ％饱和，小于10wt。 ％的芳族化合物，并且具有1.0至5.0的芳族性能比。 还提供润滑剂配方，包括高粘度高质量的II组润滑油基础油。
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公开(公告)号：US10808185B2
公开(公告)日：2020-10-20
申请号：US15390790
申请日：2016-12-27
Applicant: ExxonMobil Research and Engineering Company
Inventor： Timothy L. Hilbert , Michael B. Carroll , Ajit B. Dandekar , Sara L. Yohe , Stephen H. Brown , Tracie L. Owens , April D. Ross , Eric B. Senzer , Steven Pyl , Rugved P. Pathare , Lisa I-Ching Yeh , Bradley R. Fingland , Keith K. Aldous , Anjaneya S. Kovvali , Kendall S. Fruchey , Sara K. Green , Camden N. Henderson
IPC: C10G67/00 , C10G67/04 , C10G55/02 , C10G65/04 , C10K1/00 , C10K3/04 , C10M101/02 , C01B3/48 , C10J3/82 , C10N20/02 , C10N20/00 , C10N30/02
Abstract: Methods are provided for forming lubricant base stocks from feeds such as vacuum resid or other 510° C.+ feeds. A feed can be deasphalted and then catalytically and/or solvent processed to form lubricant base stocks, including bright stocks that are resistant to haze formation.
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公开(公告)号：US10550341B2
公开(公告)日：2020-02-04
申请号：US15390896
申请日：2016-12-27
Applicant: ExxonMobil Research and Engineering Company
Inventor： Mohsen N. Harandi , Doron Levin , Himanshu Gupta , James R. Lattner , Glenn C. Wood , Keith K. Aldous , Timothy L. Hilbert , Michael B. Carroll , Ajit B. Dandekar , Sara L. Yohe , Stephen H. Brown , Tracie L. Owens , April D. Ross , Eric B. Senzer , Steven Pyl
IPC: C10G65/12 , C10M101/02 , C10G67/04 , C10G55/02 , C10G65/04 , C10K1/00 , C10K3/04 , C01B3/48 , C10J3/82
Abstract: Methods are provided for producing lubricant base stocks from deasphalted oils formed by sequential deasphalting. The deasphalted oil can be exposed a first deasphalting process using a first solvent that can provide a lower severity of deasphalting and a second deasphalting process using a second solvent that can provide a higher severity of deasphalting. This can result in formation of at least a deasphalted oil and a resin fraction. The resin fraction can represent a fraction that traditionally would have been included as part of a deasphalter rock fraction.
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公开(公告)号：US20190309231A1
公开(公告)日：2019-10-10
申请号：US16359099
申请日：2019-03-20
Applicant: ExxonMobil Research and Engineering Company
Inventor： Brandon J. O'Neill , Sara L. Yohe , Ajit B. Dandekar
Abstract: Systems and methods are provided for reducing the end point of distillate fuel boiling range fractions while reducing or minimizing conversion of the distillate fuel to naphtha or light ends. To perform end point reduction, a distillate boiling range fraction is exposed to a conversion catalyst that has a total surface area of at least 200 m2/g, an average pore size of 12 Angstroms or more, and/or a low acidity, where the conversion catalyst includes a supported Group 8-10 metal, such as a supported Group 8-10 noble metal. Such a conversion catalyst can have improved activity for reducing end point of a distillate fuel fraction while reducing or minimizing conversion relative to 177° C. Performing end point reduction using such a catalyst can allow for increased yields of distillate fuel boiling range products by allowing increased amounts of heavy feed components to be included in the input to a distillate fuel processing train.
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