公开(公告)号：US20150314268A1

公开(公告)日：2015-11-05

申请号：US14799673

申请日：2015-07-15

Applicant: CRISTAL USA INC.

Inventor： Steve M. Augustine ,  David M. Chapman ,  Dennis F. Clark

IPC: B01J23/28 ,  B01J37/00

CPC classification number: B01J23/28 ,  B01D53/565 ,  B01D53/9418 ,  B01D2255/20707 ,  B01D2255/20769 ,  B01D2255/30 ,  B01J21/063 ,  B01J23/22 ,  B01J27/051 ,  B01J27/19 ,  B01J27/199 ,  B01J35/1014 ,  B01J37/00 ,  B01J37/0201 ,  B01J2523/00 ,  B01J2523/41 ,  B01J2523/47 ,  B01J2523/68

Abstract: Catalyst support materials, catalysts, methods of making such and uses thereof are described. Methods of making catalyst support material include combining anatase titanic slurry with i) a low molecular weight form of silica; and ii) a source of Mo to form a TiO2—MoO3-SiO2 mixture. Catalyst support material include from about 86% to about 94% weight anatase titanium dioxide; from about 0.1% to about 10% weight MoO3; and from about 0.1% to about 10% weight SiO2. Low molecular weight forms of silica include forms of silica having a volume weighted median size of less than 4 nm and average molecular weight of less than 44,000, either individually or in a combination of two or more thereof. Catalyst include such catalyst support material with from about 0.1 to about 3% weight of V2O5 and optionally from about 0.01% to about 2.5% weight P.

Abstract translation: 描述了催化剂载体材料，催化剂，制备方法和用途。 制备催化剂载体材料的方法包括将锐钛矿钛浆料与i）低分子量二氧化硅组合; 和ii）Mo的源以形成TiO 2 -MoO 3 -SiO 2混合物。 催化剂载体材料包括约86％至约94％重量的锐钛矿型二氧化钛; 约0.1重量％至约10重量％的MoO 3; 和约0.1％至约10％重量的SiO 2。 二氧化硅的低分子量形式包括体积加权中值大小小于4nm，平均分子量小于44,000的二氧化硅的形式，单独地或两种或更多种的组合。 催化剂包括这样的催化剂载体材料，其具有约0.1至约3重量％的V 2 O 5和任选的约0.01重量％至约2.5重量％的P.

公开(公告)号：US09174202B2

公开(公告)日：2015-11-03

申请号：US13516411

申请日：2010-12-08

Applicant: Karin Marchand ,  Bertrand Guichard ,  Mathieu Digne ,  Michael Rebeilleau ,  Sylvie Lopez ,  Antoine Hugon ,  Audrey Bonduelle

Inventor： Karin Marchand ,  Bertrand Guichard ,  Mathieu Digne ,  Michael Rebeilleau ,  Sylvie Lopez ,  Antoine Hugon ,  Audrey Bonduelle

IPC: B01J31/04 ,  B01J27/14 ,  B01J23/28 ,  B01J23/75 ,  B01J27/19 ,  B01J37/02 ,  C10G45/04 ,  C10G45/08 ,  C10G45/46 ,  C10G45/48 ,  C10G47/12 ,  C10G49/04

CPC classification number: B01J27/14 ,  B01J23/28 ,  B01J23/75 ,  B01J27/19 ,  B01J37/0201 ,  C10G45/04 ,  C10G45/08 ,  C10G45/46 ,  C10G45/48 ,  C10G47/12 ,  C10G49/04 ,  C10G2300/1055 ,  C10G2300/202 ,  C10G2300/70 ,  C10G2400/04

Abstract: A catalyst usable in hydrotreatment processes: an alumina-based amorphous support, phosphorus, a C1-C4 dialkyl succinate, acetic acid and a hydro-dehydrogenizing function of at least one group VIII element and at least one group VIB element, preferably made up of cobalt and molybdenum, a catalyst whose Raman spectrum comprises the most intense bands characteristic of the Keggin heteropolyanions (974 and/or 990 cm−1), C1-C4 dialkyl succinate and acetic acid (896 cm−1). Preferably, the dialkyl succinate concerned is dimethyl succinate and its main band is at 853 cm−1.

Abstract translation: 可用于加氢处理方法的催化剂：氧化铝基无定形载体，磷，C 1 -C 4二烷基琥珀酸酯，乙酸和至少一种VIII族元素和至少一种VIB族元素的加氢脱氢功能，优选由 钴和钼，其拉曼光谱包括Keggin杂多阴离子（974和/或990cm-1），C 1 -C 4二烷基琥珀酸酯和乙酸（896cm -1）特征的最强烈的带。 优选地，琥珀酸二烷基酯是琥珀酸二甲酯，其主带是853cm -1。

公开(公告)号：US20150306580A1

公开(公告)日：2015-10-29

申请号：US14648451

申请日：2013-11-26

Applicant: IFP ENERGIES NOUVELLES

Inventor： Antoine DAUDIN ,  Elodie DEVERS ,  Marc-Antoine LELIAS

IPC: B01J27/19 ,  B01J21/04 ,  C10G45/08 ,  B01J37/08 ,  B01J37/02 ,  B01J37/10 ,  B01J35/00 ,  B01J35/10

CPC classification number: B01J27/19 ,  B01J21/04 ,  B01J23/88 ,  B01J23/882 ,  B01J23/888 ,  B01J27/1853 ,  B01J27/188 ,  B01J35/0006 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1047 ,  B01J37/0201 ,  B01J37/0207 ,  B01J37/0209 ,  B01J37/08 ,  B01J37/10 ,  C10G45/08

Abstract: The present invention concerns a hydrotreatment catalyst comprising a support, at least one metal selected from group VIB and at least one metal selected from group VIII of the periodic table, the quantity of metal from group VIB, expressed as the oxides, being in the range 6% to 25% by weight with respect to the total catalyst weight, the quantity of metal from group VIII, expressed as the oxides, being in the range 0.5% to 7% by weight with respect to the total catalyst weight, the support comprising at least 90% by weight of alumina, in which said alumina is obtained from a mixed and extruded boehmite gel, and in which the specific surface area of said catalyst is in the range 60 to 250 m2/g.

Abstract translation: 本发明涉及一种加氢处理催化剂，该催化剂包含载体，至少一种选自组VIB的金属和选自元素周期表第Ⅷ族中的至少一种金属，来自VIB族的金属的数量，以氧化物的形式表示， 相对于总催化剂重量为6重量％至25重量％，表示为氧化物的VIII族金属的量相对于总催化剂重量为0.5重量％至7重量％，载体包含 至少90重量％的氧化铝，其中所述氧化铝由混合挤出的勃姆石凝胶获得，其中所述催化剂的比表面积为60-250m2 / g。

公开(公告)号：US20150298101A1

公开(公告)日：2015-10-22

申请号：US14436357

申请日：2013-10-30

Applicant: DAICEL CORPORATION

Inventor： Keiichi TOMISHIGE ,  Yoshinao NAKAGAWA ,  Yasuteru KAJIKAWA ,  Yuuichirou HIRAI

IPC: B01J23/888 ,  C07C29/132 ,  B01J35/00 ,  B01J23/652 ,  B01J23/44 ,  B01J23/656 ,  C07D307/20 ,  B01J23/30

CPC classification number: B01J23/888 ,  B01J21/18 ,  B01J23/30 ,  B01J23/44 ,  B01J23/6527 ,  B01J23/6567 ,  B01J29/48 ,  B01J35/0006 ,  B01J37/0201 ,  B01J37/04 ,  C07C29/132 ,  C07D307/20 ,  Y02P20/588 ,  C07C31/207

Abstract: An object of the present invention is to provide a method for producing 3-hydroxytetrahydrofuran that can be used as a raw material for 1,3-butane diol, using as a raw material a compound that can be derived from biomass.The present invention relates to a method for producing 3-hydroxytetrahydrofuran including a step of reacting 1,4-anhydroerythritol and hydrogen to produce 3-hydroxytetrahydrofuran. In the production method, the step of reacting 1,4-anhydroerythritol and hydrogen is preferably allowed to proceed in the presence of a catalyst comprising a carrier and at least one oxide selected from the group consisting of an oxide of a Group 6 element and an oxide of a Group 7 element, the oxide being supported on the carrier.

Abstract translation: 本发明的目的是提供一种可用作1,3-丁二醇的原料的3-羟基四氢呋喃的制备方法，该方法使用可以衍生自生物质的化合物作为原料。 本发明涉及一种生产3-羟基四氢呋喃的方法，包括使1,4-脱水thr thr醇与氢反应生成3-羟基四氢呋喃的步骤。 在制造方法中，优选使1,4-脱水赤藓糖醇和氢气反应的步骤在含有载体和至少一种选自第6族元素的氧化物和 第7族元素的氧化物，氧化物负载在载体上。

公开(公告)号：US09162217B2

公开(公告)日：2015-10-20

申请号：US14117214

申请日：2012-05-17

Applicant: Shinichi Nakata ,  Sumio Kato ,  Masataka Ogasawara ,  Atsunori Ono ,  Yohei Takahashi ,  Takashi Wakabayashi ,  Yunosuke Nakahara

Inventor： Shinichi Nakata ,  Sumio Kato ,  Masataka Ogasawara ,  Atsunori Ono ,  Yohei Takahashi ,  Takashi Wakabayashi ,  Yunosuke Nakahara

IPC: B01J23/02 ,  B01J23/38 ,  B01J23/58 ,  B01J27/18 ,  B01D53/94 ,  B01J23/42 ,  B01J23/44 ,  B01J27/185 ,  C01B25/32 ,  C01B25/45 ,  F01N3/10 ,  B01J37/03 ,  B01J35/10 ,  B01J37/02

CPC classification number: B01J27/1806 ,  B01D53/945 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2255/1025 ,  B01D2255/2042 ,  B01D2255/2045 ,  B01D2255/9207 ,  B01J23/42 ,  B01J23/44 ,  B01J27/1856 ,  B01J35/1014 ,  B01J37/0201 ,  B01J37/031 ,  C01B25/32 ,  C01B25/45 ,  F01N3/101 ,  Y02T10/22

Abstract: An apatite compound represented by general formula: A10(PO4)6(OH)2 (wherein A represents Ba or a combination of Ba and Sr and/or Ca) is used as a carrier. This exhaust gas purifying catalyst is obtained by having the apatite compound carrier support a noble metal component.

Abstract translation: 以通式：A10（PO4）6（OH）2（其中A表示Ba或Ba和Sr和/或Ca的组合）表示的磷灰石化合物用作载体。 该废气净化催化剂通过使磷灰石化合物载体担载贵金属成分而得到。

公开(公告)号：US09150479B1

公开(公告)日：2015-10-06

申请号：US14385917

申请日：2013-05-29

Applicant: Dow Global Technologies LLC

Inventor： David G. Barton ,  Adam Chojecki ,  Paul R. Elowe ,  Beata A. Kilos

IPC: C07C41/09 ,  C09K5/10 ,  C09K5/00

CPC classification number: C07C41/09 ,  B01J21/066 ,  B01J27/10 ,  B01J37/0201 ,  B01J37/031 ,  C09K5/00 ,  C07C43/275

Abstract: Provided is a process for preparing a diaryl ether compound through the dehydration of an aromatic alcohol compound in the presence of a dehydration catalyst. The dehydration catalyst is an oxide of a heavy rare earth element, wherein the heavy rare earth element is terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium, or mixtures thereof.

Abstract translation: 提供了通过在脱水催化剂的存在下通过芳族醇化合物的脱水来制备二芳基醚化合物的方法。 脱水催化剂是重稀土元素的氧化物，其中重稀土元素是铽，镝，钬，铒，ium，镱，镥或其混合物。

公开(公告)号：US20150274610A1

公开(公告)日：2015-10-01

申请号：US14735447

申请日：2015-06-10

Applicant: Shell Oil Company

Inventor： Peter Tanev TANEV ,  Armin LANGE DE OLIVEIRA

IPC: C07C2/76 ,  B01J37/08 ,  B01J37/02 ,  B01J31/26

CPC classification number: C07C2/76 ,  B01J23/28 ,  B01J29/076 ,  B01J29/48 ,  B01J31/26 ,  B01J35/023 ,  B01J37/0201 ,  B01J37/0203 ,  B01J37/08 ,  B01J37/086 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2523/06 ,  C07C2523/08 ,  C07C2523/10 ,  C07C2523/14 ,  C07C2523/20 ,  C07C2523/22 ,  C07C2523/26 ,  C07C2523/28 ,  C07C2523/30 ,  C07C2523/34 ,  C07C2523/36 ,  C07C2523/42 ,  C07C2523/46 ,  C07C2523/50 ,  C07C2523/72 ,  C07C2523/745 ,  C07C2523/75 ,  C07C2523/755 ,  C07C2529/40 ,  C07C2529/65 ,  C07C2531/26 ,  Y02P20/52 ,  C07C15/04

Abstract: A catalyst for converting methane to aromatic hydrocarbons is described herein. The catalyst comprises an active metal or a compound thereof, and an inorganic oxide support wherein the active metal is added to the support in the form of metal oxalate. The metal oxalate-derived catalyst exhibits superior performance in the conversion of methane-rich feed to aromatics products relative to catalysts prepared from non-oxalate metal precursors. A method of making the catalyst and a method of using the catalyst are also described.

Abstract translation: 本文描述了将甲烷转化为芳族烃的催化剂。 催化剂包含活性金属或其化合物，以及无机氧化物载体，其中活性金属以草酸金属的形式加入到载体中。 相对于由非草酸盐金属前体制备的催化剂，草酸金属催化剂在富含甲烷的进料与芳烃产物的转化中表现出优异的性能。 还描述了制备催化剂的方法和使用该催化剂的方法。

公开(公告)号：US20150273448A1

公开(公告)日：2015-10-01

申请号：US14670868

申请日：2015-03-27

Applicant: HINDUSTAN PETROLEUM CORPORATION LIMITED

Inventor： Raman Ravishankar ,  Sunil Mehla ,  Peddy Venkata Chalapathi Rao ,  Nettem Venkateswarlu Choudary ,  Sriganesh Gandham

IPC: B01J29/40 ,  B01J37/04 ,  B01J37/02 ,  C10G63/00 ,  B01J23/10

CPC classification number: B01J29/405 ,  B01J23/10 ,  B01J29/061 ,  B01J35/026 ,  B01J37/0009 ,  B01J37/0201 ,  B01J37/04 ,  B01J2229/186 ,  B01J2229/20 ,  B01J2229/42 ,  C10G35/065 ,  C10G35/095 ,  C10G45/00 ,  C10G50/00 ,  C10G55/06 ,  C10G63/04 ,  C10G69/123 ,  C10G2300/1044 ,  C10G2300/1088 ,  C10G2400/02

Abstract: The present disclosure relates to a catalyst composition comprising (a) at least one rare earth metal, (b) at least one zeolite, and (c) at least one diluent, wherein, said rare earth metal is impregnated in at least one of (b) and (c); the ratio of said zeolite to said diluent ranges from 1:9 to 9:1; and the amount of said rare earth metal is in the range of 0.1 to 20 w/w %. The present disclosure also relates to a process for preparing a catalyst composition. Further, the present disclosure relates to a process for reducing the olefin content in a hydrocarbon stream using the catalyst of the present disclosure.

Abstract translation: 本公开涉及一种催化剂组合物，其包含（a）至少一种稀土金属，（b）至少一种沸石和（c）至少一种稀释剂，其中所述稀土金属浸渍在 b）和（c）; 所述沸石与所述稀释剂的比例为1:9至9:1; 并且所述稀土金属的量在0.1至20w / w％的范围内。 本公开还涉及制备催化剂组合物的方法。 此外，本公开涉及使用本公开的催化剂降低烃流中的烯烃含量的方法。

公开(公告)号：US20150266007A1

公开(公告)日：2015-09-24

申请号：US14669187

申请日：2015-03-26

Applicant: Manjola Mancka ,  Yunkui Li ,  Jeffery LaChapelle ,  Wei Wu ,  David Shepard

Inventor： Manjola Mancka ,  Yunkui Li ,  Jeffery LaChapelle ,  Wei Wu ,  David Shepard

IPC: B01J29/70 ,  B01J29/76 ,  B01J35/04 ,  C01B39/08 ,  B01J35/00 ,  B01J37/08 ,  B01J37/00 ,  B01D53/86 ,  C01B39/48 ,  B01J37/02

CPC classification number: B01J29/70 ,  B01D53/8628 ,  B01D53/9418 ,  B01D2253/108 ,  B01D2255/20707 ,  B01D2255/20715 ,  B01D2255/20738 ,  B01D2255/20746 ,  B01D2255/20761 ,  B01D2255/50 ,  B01D2255/9202 ,  B01J29/7049 ,  B01J29/72 ,  B01J29/76 ,  B01J35/0006 ,  B01J35/04 ,  B01J37/0018 ,  B01J37/0201 ,  B01J37/08 ,  B01J2229/16 ,  B01J2229/183 ,  C01B39/08 ,  C01B39/085 ,  C01B39/087 ,  C01B39/48

Abstract: The present disclosure generally provides novel STT-type zeolite materials called PIDC-120501, PIDC-120502, and PIDC-120805/120806 or PIDC-type zeolites and a method of making these zeolites. The present disclosure also provides for the use of these zeolite materials as a catalyst and a method of preparing said catalyst. The PIDC-type zeolites or STT-type zeolite materials may be used as a catalyst, such as in Selective Catalytic Reduction (SCR) applications.

Abstract translation: 本公开通常提供称为PIDC-120501，PIDC-120502和PIDC-120805/120806或PIDC型沸石的新型STT型沸石材料和制备这些沸石的方法。 本公开还提供了这些沸石材料作为催化剂的用途和制备所述催化剂的方法。 PIDC型沸石或STT型沸石材料可用作催化剂，例如选择性催化还原（SCR）应用。

公开(公告)号：US09138736B2

公开(公告)日：2015-09-22

申请号：US13637798

申请日：2011-03-29

Applicant: Kotaro Hayashi ,  Satoshi Nagao ,  Hideaki Suzuki

Inventor： Kotaro Hayashi ,  Satoshi Nagao ,  Hideaki Suzuki

IPC: B01J37/02 ,  B01D53/94 ,  B01J20/06 ,  B01J20/18 ,  B01J23/63 ,  B01J29/67 ,  B01J29/74 ,  B01J29/78 ,  B01J29/80 ,  B01J35/00 ,  B01J35/04 ,  B01J37/03 ,  F01N3/08 ,  B01J37/10 ,  B01J29/12 ,  B01J29/44 ,  F01N13/00 ,  B01J20/02 ,  B01J20/16

CPC classification number: B01J37/0248 ,  B01D53/944 ,  B01D53/945 ,  B01D53/9481 ,  B01D53/9486 ,  B01D2255/1023 ,  B01D2255/2065 ,  B01D2257/404 ,  B01D2258/01 ,  B01J20/0211 ,  B01J20/0222 ,  B01J20/0233 ,  B01J20/06 ,  B01J20/165 ,  B01J20/18 ,  B01J20/186 ,  B01J23/63 ,  B01J29/126 ,  B01J29/44 ,  B01J29/67 ,  B01J29/7415 ,  B01J29/7815 ,  B01J29/80 ,  B01J35/0006 ,  B01J35/04 ,  B01J37/0201 ,  B01J37/0246 ,  B01J37/031 ,  B01J37/038 ,  B01J37/10 ,  B01J2229/186 ,  F01N3/0807 ,  F01N3/0814 ,  F01N3/0835 ,  F01N3/0842 ,  F01N13/0093 ,  F01N2570/10 ,  Y02T10/22

Abstract: An exhaust purifying apparatus of an internal combustion engine is provided. The exhaust purifying apparatus includes a CO oxidation catalyst disposed in the exhaust flow passage of an internal combustion engine and capable of oxidizing and thereby purifying CO in the exhaust, and an HC adsorbent material loaded with a noble metal, for adsorbing HC in the exhaust. The exhaust purifying apparatus further includes an NOx adsorbent material for adsorbing NOx in the exhaust. These adsorbent materials are located on the upstream side in the exhaust flow direction with respect to the CO oxidation catalyst and disposed in order from the upstream. The CO oxidation catalyst contains Pd and CeO2 and is obtained by an oxidation treatment at a temperature of 850 to 950° C. The amount of Pd supported in the CO oxidation catalyst is from 0.1 to 2.5 mass % based on CeO2.

Abstract translation: 提供内燃机的排气净化装置。 排气净化装置包括：CO氧化催化剂，其设置在内燃机的排气流路中，能够氧化并净化排气中的CO;以及负载贵金属的HC吸附材料，用于吸附排气中的HC。 排气净化装置还包括用于吸附排气中的NOx的NOx吸附材料。 这些吸附材料相对于CO氧化催化剂位于排气流动方向的上游侧，并且从上游依次设置。 CO氧化催化剂含有Pd和CeO 2，通过在850〜950℃的温度下进行氧化处理得到。在CO氧化催化剂中负载的Pd的量为CeO 2 0.1〜2.5质量％。