公开(公告)号：US20150258532A1

公开(公告)日：2015-09-17

申请号：US14434115

申请日：2013-10-01

Applicant: SANTOKU CORPORATION

Inventor： Shinya Matsuo ,  Tadatoshi Murota

IPC: B01J23/10 ,  B01J37/04 ,  C01B3/40 ,  B01J23/00 ,  B01D53/94 ,  B01J23/89 ,  B01J37/08

CPC classification number: B01J23/10 ,  B01D53/945 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2255/1025 ,  B01D2255/2065 ,  B01D2255/2066 ,  B01D2255/20715 ,  B01D2255/20738 ,  B01D2255/20753 ,  B01D2255/20761 ,  B01D2255/407 ,  B01J23/002 ,  B01J23/42 ,  B01J23/464 ,  B01J23/72 ,  B01J23/745 ,  B01J23/755 ,  B01J23/892 ,  B01J23/894 ,  B01J37/0201 ,  B01J37/0207 ,  B01J37/031 ,  B01J37/04 ,  B01J37/08 ,  B01J37/10 ,  B01J2523/00 ,  B01J2523/824 ,  B01J2523/847 ,  C01B3/40 ,  C01B2203/0233 ,  C01B2203/1047 ,  C01B2203/1058 ,  C01B2203/1064 ,  C01B2203/1076 ,  C01B2203/1082 ,  C01G25/00 ,  Y02P20/52 ,  Y02T10/22 ,  B01J2523/3712 ,  B01J2523/3718 ,  B01J2523/48

Abstract: Provided are a method for producing a composite oxide and the composite oxide, which finds use as an easy-to-handle catalyst material having a high reforming rate of hydrocarbon to hydrogen even when oxidized. The method includes the steps of: (a) preparing a Ce aqueous solution not less than 80 mol % of which Ce ions are tetravalent, and a Zr aqueous solution containing Zr ions; (b1) mixing the Zr aqueous solution and a portion of the Ce aqueous solution to prepare a mixed aqueous solution (X1); (c1) hydrothermally processing solution (X1); (b2) adding the remainder of the Ce aqueous solution prepared in step (a) to a colloidal solution (Y1) of a composite salt obtained from step (c1) to prepare a colloidal solution (Y2) of a composite salt; (c2) hydrothermally processing solution (Y2) obtained from step (b2); (d) mixing a colloidal solution (Y3) of a composite salt obtained from step (c2) with an alkaline solution and a surfactant to prepare a precipitate; and (e) calcining the precipitate.

Abstract translation: 提供一种复合氧化物和复合氧化物的制造方法，其即使在被氧化时也被用作具有高烃重整速率的易于处理的催化剂材料。 该方法包括以下步骤：（a）制备不少于CeO 4为80％的Ce水溶液和含有Zr离子的Zr水溶液; （b1）将Zr水溶液和一部分Ce水溶液混合，制备混合水溶液（X1）; （c1）水热处理液（X1）; （b2）将步骤（a）中制备的Ce水溶液的剩余部分添加到由步骤（c1）获得的复合盐的胶体溶液（Y1）中以制备复合盐的胶体溶液（Y2）; （c2）从步骤（b2）获得的水热处理溶液（Y2）; （d）将由步骤（c2）获得的复合盐的胶体溶液（Y3）与碱性溶液和表面活性剂混合以制备沉淀物; 和（e）煅烧沉淀物。

公开(公告)号：US20150251169A1

公开(公告)日：2015-09-10

申请号：US14430769

申请日：2014-08-20

Applicant: MAZDA MOTOR CORPORATION

Inventor： Takashi Baba ,  Hiroshi Yamada ,  Koichiro Harada ,  Yoshiyuki Sato ,  Masahiko Shigetsu ,  Akihide Takami

IPC: B01J29/068 ,  B01J23/63 ,  B01J23/58 ,  F02D41/02 ,  B01J35/02 ,  B01J37/02 ,  B01D53/94 ,  F01N3/18 ,  B01J35/00 ,  B01J35/04

CPC classification number: B01J29/068 ,  B01D53/9418 ,  B01D53/9422 ,  B01D53/944 ,  B01D53/9468 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2255/1025 ,  B01D2255/2042 ,  B01D2255/2063 ,  B01D2255/2065 ,  B01D2255/2066 ,  B01D2255/2068 ,  B01D2255/20715 ,  B01D2255/2092 ,  B01D2255/50 ,  B01D2255/9025 ,  B01D2255/91 ,  B01D2255/912 ,  B01D2255/9202 ,  B01J23/464 ,  B01J23/58 ,  B01J23/63 ,  B01J35/0006 ,  B01J35/023 ,  B01J35/04 ,  B01J37/0201 ,  B01J37/0244 ,  B01J37/0246 ,  B01J2229/18 ,  F01N3/0842 ,  F01N3/103 ,  F01N3/18 ,  F01N3/2828 ,  F01N2510/0684 ,  F02D41/0235

Abstract: An exhaust gas purify catalyst includes a substrate (1), an oxidation catalyst layer (2) formed on the substrate (1) and containing zeolite and at least one catalytic metal, an LNT layer (3) formed on the oxidation catalyst layer (2) and containing an NOx storage material and at least one catalytic metal, and an NOx reduction layer (4) formed on the LNT layer (3) and containing Rh acting as a catalytic metal and at least one of alumina or zirconia, wherein the NOx reduction layer (4) has a larger content of Rh than that in each of the oxidation catalyst layer (2) and the LNT layer (3).

Abstract translation: 废气净化催化剂包括基材（1），形成在基材（1）上并含有沸石和至少一种催化金属的氧化催化剂层（2），形成在氧化催化剂层（2）上的LNT层 ），并且含有NO x存储材料和至少一种催化金属和形成在所述LNT层（3）上并且含有作为催化金属的Rh和氧化铝或氧化锆中的至少一种的NOx还原层（4），其中所述NOx 还原层（4）的Rh含量比氧化催化剂层（2）和LNT层（3）的含量大。

公开(公告)号：US09108845B2

公开(公告)日：2015-08-18

申请号：US13256623

申请日：2010-03-25

Applicant: Takashi Nabeta ,  Nobuhiko Horiuchi ,  Kenichi Sugimoto ,  Kenji Iwata ,  Masami Murakami

Inventor： Takashi Nabeta ,  Nobuhiko Horiuchi ,  Kenichi Sugimoto ,  Kenji Iwata ,  Masami Murakami

IPC: C01B7/00 ,  C01B7/04 ,  B01J23/83 ,  B01J35/00 ,  B01J35/08 ,  B01J35/10 ,  B01J37/00 ,  B01J37/02 ,  B01J21/08 ,  B01J35/02

CPC classification number: C01B7/04 ,  B01J21/08 ,  B01J23/83 ,  B01J35/002 ,  B01J35/023 ,  B01J35/08 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1047 ,  B01J37/0045 ,  B01J37/0201

Abstract: The invention provides a chlorine production catalyst that shows excellent reaction activity in the oxidation reaction of hydrogen chloride with oxygen into chlorine, is inexpensive and can be supplied stably, and is suited for use in a fluidized-bed reactor. The invention also provides a chlorine production process using the catalyst. The chlorine production catalyst of the invention includes spherical particles containing copper element (A), an alkali metal element (B) and a lanthanoid element (C) and having an average sphericity of not less than 0.80. The lanthanoid element (C) has a bond dissociation energy with oxygen at 298 K of 100 to 185 kcal/mol. The content of the copper element (A) in the catalyst is 0.3 wt % to 4.5 wt %.

Abstract translation: 本发明提供了氯化氢与氧气在氯中氧化反应中优异的反应活性的氯生产催化剂，价格便宜，可稳定供应，适用于流化床反应器。 本发明还提供了使用该催化剂的氯生产方法。 本发明的氯生产催化剂包括含有铜元素（A），碱金属元素（B）和镧系元素（C）的球形颗粒，其平均球形度不小于0.80。 镧系元素（C）具有在298K的氧与100至185kcal / mol的键解离能。 催化剂中的铜元素（A）的含量为0.3重量％〜4.5重量％。

公开(公告)号：US09108155B2

公开(公告)日：2015-08-18

申请号：US13326570

申请日：2011-12-15

Applicant: Sung Mu Choi ,  Jung Min Seo ,  Hyun Sik Han ,  Eun Seok Kim ,  Jeong Bae Lee

Inventor： Sung Mu Choi ,  Jung Min Seo ,  Hyun Sik Han ,  Eun Seok Kim ,  Jeong Bae Lee

IPC: B01J23/10 ,  B01D53/94 ,  F01N3/035 ,  F01N3/022 ,  B01J23/66 ,  B01J23/89 ,  B01J35/02 ,  B01J35/04 ,  B01J37/00 ,  B01J37/02

CPC classification number: B01D53/944 ,  B01D53/9477 ,  B01D2255/104 ,  B01D2255/106 ,  B01D2255/2065 ,  B01D2255/2066 ,  B01D2255/20738 ,  B01D2255/2092 ,  B01D2255/40 ,  B01D2255/9155 ,  B01J23/10 ,  B01J23/66 ,  B01J23/894 ,  B01J35/023 ,  B01J35/04 ,  B01J37/0009 ,  B01J37/0036 ,  B01J37/0201 ,  F01N3/0222 ,  F01N3/035 ,  F01N2330/06 ,  F01N2510/065 ,  F01N2510/0682 ,  Y02T10/22

Abstract: The present invention provides a non-PGM catalyst for burning carbon soot without using a noble metal, the non-PGM catalyst comprising: a cerium-praseodymium complex oxide and an iron oxide, the cerium-praseodymium complex oxide impregnated with silver (Ag). The cerium-praseodymium complex oxide illustratively consists of 60 to 95 wt % of cerium oxide and 5 to 40 wt % of praseodymium oxide, and silver (Ag) impregnated in the complex oxide is 1.5 to 3.0 parts by weight of the total weight of the complex oxide. The iron oxide may be an oxide in a form of particles separate from the cerium-praseodymium complex oxide in which silver is impregnated, and may be 0.5 to 2 parts by weight of the total weight of the cerium praseodymium complex oxide.

公开(公告)号：US20150225321A1

公开(公告)日：2015-08-13

申请号：US14429465

申请日：2013-09-23

Applicant: SOLVAY SA

Inventor： Fangzheng Su

IPC: C07C29/60 ,  C08G63/00 ,  D01F6/62 ,  C08G63/16

CPC classification number: C07C29/60 ,  B01J23/6567 ,  B01J29/08 ,  B01J29/18 ,  B01J29/40 ,  B01J29/65 ,  B01J29/70 ,  B01J29/7007 ,  B01J29/7015 ,  B01J29/7038 ,  B01J29/85 ,  B01J37/0201 ,  C07C29/132 ,  C07C67/08 ,  C08G63/00 ,  C08G63/16 ,  D01F6/62 ,  D10B2331/04 ,  C07C31/205 ,  C07C69/28

Abstract: A process for manufacturing 1,3-propanediol by reacting glycerol with hydrogen in the presence of a supported catalyst, the supported catalyst comprising at least one iridium compound and at least one rhenium compound, both compounds being supported on a zeolite, wherein the zeolite exhibits an MFI, a MEL, a BEA, a MOR, a FAU, a FER, a MWW, a CHA, a LTA, a ATO or a AEL framework type, and wherein the said zeolite is at least partially in the hydrogen form.

Abstract translation: 一种在负载型催化剂存在下使甘油与氢反应制备1,3-丙二醇的方法，所述载体催化剂包括至少一种铱化合物和至少一种铼化合物，两种化合物都支持在沸石上，其中沸石表现出 MFI，MEL，BEA，MOR，FAU，FER，MWW，CHA，LTA，ATO或AEL骨架型，并且其中所述沸石至少部分为氢形式。

公开(公告)号：US09101914B2

公开(公告)日：2015-08-11

申请号：US14006841

申请日：2012-03-28

Applicant: Junji Ito ,  Yasunari Hanaki ,  Tetsuro Naito ,  Misaki Akaishi ,  Hironori Wakamatsu

Inventor： Junji Ito ,  Yasunari Hanaki ,  Tetsuro Naito ,  Misaki Akaishi ,  Hironori Wakamatsu

IPC: B01J21/00 ,  B01J23/00 ,  B01J25/00 ,  B01J29/00 ,  B01J23/10 ,  B01J23/889 ,  B01D53/94 ,  F01N3/28 ,  B01J23/34 ,  B01J23/83 ,  B01J21/06 ,  B01J37/02 ,  B01J35/00

CPC classification number: B01J23/8892 ,  B01D53/945 ,  B01D2255/204 ,  B01D2255/2042 ,  B01D2255/2045 ,  B01D2255/2063 ,  B01D2255/2065 ,  B01D2255/20715 ,  B01D2255/2073 ,  B01D2255/20738 ,  B01D2255/20746 ,  B01D2255/20753 ,  B01D2255/908 ,  B01D2255/9202 ,  B01J21/066 ,  B01J23/002 ,  B01J23/10 ,  B01J23/34 ,  B01J23/83 ,  B01J35/002 ,  B01J35/006 ,  B01J37/0201 ,  B01J2523/00 ,  F01N3/2828 ,  Y02T10/22 ,  B01J2523/24 ,  B01J2523/3706 ,  B01J2523/842 ,  B01J2523/3712 ,  B01J2523/3725 ,  B01J2523/48 ,  B01J2523/72 ,  B01J2523/847

Abstract: An exhaust gas purifying catalyst having a high purifying ability even if noble metal is not used as an essential component, an exhaust gas purifying monolith catalyst, and a method for manufacturing an exhaust gas purifying catalyst, are provided. The exhaust gas purifying catalyst includes an oxide having an oxygen storage and release capacity, and an oxide represented by the following formula (1) supported on the oxide having the oxygen storage and release capacity, LaxM1−xM′O3−δ  (1) (wherein La represents lanthanum, M represents at least one element selected from the group consisting of barium (Ba), strontium (Sr) and calcium (Ca), M′ represents at least one element selected from the group consisting of iron (Fe), cobalt (Co), nickel (Ni) and manganese (Mn), δ represents an oxygen deficient amount, and x and δ fulfill conditions represented by 0

Abstract translation: 提供了即使不使用贵金属作为必要成分，具有高净化能力的废气净化催化剂，废气净化整料催化剂，以及废气净化催化剂的制造方法。 废气净化催化剂包括具有储氧和释放能力的氧化物和负载在具有储氧和释放能力的氧化物上的下式（1）表示的氧化物，LaxM1-xM'O3-δ（1）（ 其中La表示镧，M表示选自钡（Ba），锶（Sr）和钙（Ca）中的至少一种元素，M'表示选自铁（Fe）， 钴（Co），镍（Ni）和锰（Mn），δ表示氧缺乏量，x和δ分别满足由0

公开(公告)号：US09096562B2

公开(公告)日：2015-08-04

申请号：US13950973

申请日：2013-07-25

Applicant: Scientific Design Company, Inc.

Inventor： Andrzej Rokicki ,  Jason Durand ,  Rudy Anthony Morin ,  Wojciech Suchanek

IPC: C07D301/10 ,  B01J7/00 ,  B01J37/08 ,  B01J38/12 ,  B01J21/04 ,  B01J23/50 ,  B01J23/96 ,  B01J35/00 ,  B01J37/02 ,  B01J8/10 ,  B01J35/10

CPC classification number: C07D301/10 ,  B01J7/00 ,  B01J21/04 ,  B01J23/50 ,  B01J23/96 ,  B01J35/0013 ,  B01J35/006 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1061 ,  B01J37/0201 ,  B01J37/0203 ,  B01J37/08 ,  B01J38/12 ,  Y02P20/52 ,  Y02P20/584

Abstract: A method for producing ethylene oxide comprising: providing one or more feed components, wherein the one or more feed components contains at least ethylene obtained by dehydrating ethanol; contacting the one or more feed components with a desulfurization catalyst comprising a high surface area support and an amount of silver, wherein at least 20% of the silver is present as oxidized silver; and contacting the one or more feed components with a silver-containing epoxidation catalyst disposed inside an ethylene oxide reactor to form a reaction gas comprising ethylene oxide.

Abstract translation: 一种生产环氧乙烷的方法，包括：提供一种或多种进料组分，其中所述一种或多种进料组分至少包含通过使乙醇脱水得到的乙烯; 使一种或多种进料组分与包含高表面积载体和一定量的银的脱硫催化剂接触，其中至少20％的银以氧化银的形式存在; 并使一种或多种进料组分与设置在环氧乙烷反应器内部的含银环氧化催化剂接触以形成包含环氧乙烷的反应气体。

公开(公告)号：US09095844B2

公开(公告)日：2015-08-04

申请号：US13704282

申请日：2010-06-29

Applicant: Young Min Chung ,  Tae Jin Kim ,  Seung Hoon Oh ,  Dilek Ayse Boga ,  Pieter C. A. Bruijnincx ,  Bert M. Weckhuysen

Inventor： Young Min Chung ,  Tae Jin Kim ,  Seung Hoon Oh ,  Dilek Ayse Boga ,  Pieter C. A. Bruijnincx ,  Bert M. Weckhuysen

IPC: B01J23/72 ,  B01J23/89 ,  B01J21/04 ,  B01J21/10 ,  B01J29/04 ,  B01J37/02 ,  B01J37/18 ,  C01B3/32

CPC classification number: B01J23/8926 ,  B01J21/04 ,  B01J21/10 ,  B01J29/049 ,  B01J37/0201 ,  B01J37/18 ,  C01B3/326 ,  C01B2203/0233 ,  C01B2203/107 ,  C01B2203/1076 ,  C01B2203/1211 ,  Y02P20/145 ,  Y02P20/52

Abstract: Disclosed herein is a catalyst for aqueous-phase reforming of biomass-derived polyols, which comprises platinum and copper as active metals and a mixture of magnesia and alumina as a support. The catalyst contains a small amount of platinum and, at the same time, has high hydrogen selectivity and low methane selectivity.

Abstract translation: 本文公开了一种用于生物质衍生的多元醇的水相重整的催化剂，其包含铂和铜作为活性金属以及氧化镁和氧化铝作为载体的混合物。 催化剂含有少量铂，同时具有高氢选择性和低甲烷选择性。

公开(公告)号：US20150209760A1

公开(公告)日：2015-07-30

申请号：US14427491

申请日：2013-08-22

Applicant: Mitsui Mining & Smelting Co., Ltd.

Inventor： Takahito Asanuma ,  Yasuhide Yamaguchi ,  Yunosuke Nakahara

IPC: B01J23/63 ,  B01J23/10 ,  B01J35/00 ,  B01J35/10 ,  B01J35/02

CPC classification number: B01J23/63 ,  B01D53/945 ,  B01D2255/1023 ,  B01D2255/407 ,  B01D2255/908 ,  B01D2255/9205 ,  B01D2255/9207 ,  B01J21/066 ,  B01J23/002 ,  B01J23/10 ,  B01J23/44 ,  B01J35/0006 ,  B01J35/002 ,  B01J35/02 ,  B01J35/023 ,  B01J35/1009 ,  B01J35/1014 ,  B01J35/1061 ,  B01J35/1066 ,  B01J37/0201 ,  B01J37/0248 ,  B01J37/03 ,  B01J37/08 ,  B01J37/18 ,  Y02T10/22

Abstract: Provided is an exhaust-gas-purification catalyst carrier that contains a ceria-zirconia complex oxide having a pyrochlore phase and a novel exhaust-gas-purification catalyst carrier that exhibit excellent OSC performance at any temperature region of a low temperature (around 400° C.) and a high temperature (around 800° C.). Proposed is the exhaust-gas-purification catalyst carrier containing a ceria-zirconia complex oxide which has a pyrochlore phase and is 7.0 m2/g or more in specific surface area and in the range of 100 Å to 700 Å in crystallite size.

Abstract translation: 提供了一种废气净化催化剂载体，其包含具有烧绿石相的二氧化铈 - 氧化锆复合氧化物和新的废气净化催化剂载体，其在低温（约400℃）的任何温度区域表现出优异的OSC性能 ）和高温（约800℃）。 提出了含有二氧化铈 - 氧化锆复合氧化物的废气净化催化剂载体，其具有烧绿石相，比表面积为7.0m 2 / g以上，微晶尺寸为100〜700。

公开(公告)号：US09089838B2

公开(公告)日：2015-07-28

申请号：US13818527

申请日：2011-08-22

Applicant: Aurel Wolf ,  Leslaw Mleczko ,  Oliver Felix-Karl Schlüter

Inventor： Aurel Wolf ,  Leslaw Mleczko ,  Oliver Felix-Karl Schlüter

IPC: C01B7/00 ,  B01J27/13 ,  B01J27/135 ,  B01J23/00 ,  B01J23/40 ,  B01J23/42 ,  B01J23/62 ,  B01J23/14 ,  B01J35/10 ,  B01J37/02 ,  B01J37/08 ,  C01B7/04 ,  B01J37/00

CPC classification number: B01J23/626 ,  B01J23/14 ,  B01J35/1014 ,  B01J37/0009 ,  B01J37/0201 ,  B01J37/0207 ,  B01J37/08 ,  C01B7/04

Abstract: The present invention relates to a catalyst for preparation of chlorine by catalytic gas phase oxidation of hydrogen chloride with oxygen, in which the catalyst comprises calcined tin dioxide as a support and at least one halogen-containing ruthenium compound, and to the use thereof.

Abstract translation: 本发明涉及一种通过氯气与氧气的催化气相氧化制备氯的催化剂，其中催化剂包含煅烧二氧化锡作为载体和至少一种含卤素的钌化合物及其用途。