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公开(公告)号:US20240152047A1
公开(公告)日:2024-05-09
申请号:US18482295
申请日:2023-10-06
Applicant: Rohm and Haas Electronic Materials LLC
Inventor: ANASTASIA LILY PATTERSON , RACHEL SNYDER , Greg Alan Hostetler , Charles Roger Kinzie , Bethany Seckman , Deyan Wang , Hee Jae Yoon , Su Min Lee , Heelim Lee
IPC: G03F7/00 , C08F220/06
CPC classification number: G03F7/0005 , C08F220/06
Abstract: Disclosed is a formulation comprising a copolymer comprising one or more bifunctional high refractive index first monomers comprising a high refractive index aromatic core and further comprising one or more UV- or thermally-reactive groups (A) and one or more second monomers comprising a high refractive index core and further comprising one or more groups capable of reacting to increase the solubility of the copolymer in aqueous media (B), and one or more solvents. The formulation may optionally contain additional components. Further disclosed are methods for forming optical thin films from the formulation and optical devices containing the optical thin films.
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公开(公告)号:US20220214616A1
公开(公告)日:2022-07-07
申请号:US17564476
申请日:2021-12-29
Inventor: Joshua Kaitz , Brian Malbrecht , Deyan Wang , Michael Henry Howard, JR.
Abstract: A photoresist composition, comprising a first polymer comprising a first repeating unit comprising an acid-labile group, and a second polymer comprising a repeating unit derived from one or more monomers of formula (4); a photoacid generator; and a solvent, wherein Z1, Z2, R1, R2, and L are as described herein, and P is a polymerizable group.
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公开(公告)号:US20210341840A1
公开(公告)日:2021-11-04
申请号:US17231417
申请日:2021-04-15
Applicant: Rohm and Haas Electronic Materials LLC
Inventor: Sheng Liu , James F. Cameron , Shintaro YAMADA , Iou-Sheng KE , Keren ZHANG , Suzanne M. Coley , Li Cui , Paul J. LaBeaume , Deyan Wang
Abstract: Coating compositions comprise: a curable compound comprising: a core chosen from a C6 carbocyclic aromatic ring, a C2-5 heterocyclic aromatic ring, a C9-30 fused carbocyclic aromatic ring system, a C4-30 fused heterocyclic aromatic ring system, C1-20 aliphatic, and C3-20 cycloaliphatic, and three or more substituents of formula (1) wherein at least two substituents of formula (1) are attached to the aromatic core; and wherein: Ar1 is chosen from a C6 carbocyclic aromatic ring, a C2-5 heterocyclic aromatic ring, a C9-30 fused carbocyclic aromatic ring system, and a C4-30 fused heteroocyclic aromatic ring system; Z is a substituent independently chosen from OR1, protected hydroxyl, carboxyl, protected carboxyl, SR1, protected thiol, —O—C(═O)—C1-6 alkyl, halogen, and NHR2; wherein each R1 is independently chosen from H, C1-10 alkyl, C2-10 unsaturated hydrocarbyl, and C5-30 aryl; each R2 is independently chosen from H, C1-10 alkyl, C2-10 unsaturated hydrocarbyl, C5-30 aryl, C(═O)—R1, and S(═O)2—R1; x is an integer from 1 to the total number of available aromatic ring atoms in Ar1; and * denotes the point of attachment to the core; provided that no substituents of formula (1) are in an ortho position to each other on the same aromatic ring of the core; a polymer; and one or more solvents, wherein the total solvent content is from 50 to 99 wt % based on the coating composition. Coated substrates formed with the coating compositions and methods of forming electronic devices using the compositions are also provided. The compositions, coated substrates and methods find particular applicability in the manufacture of semiconductor devices.
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公开(公告)号:US20210277219A1
公开(公告)日:2021-09-09
申请号:US17163604
申请日:2021-02-01
Applicant: Rohm and Haas Electronic Materials LLC
Inventor: Deyan Wang , Yixuan Song
Abstract: There is disclosed an optically clear shear thickening fluid and a protection assembly comprising the optically clear shear thickening fluid. It further relates to uses of the optically clear shear thickening fluid in electronic devices, particularly in optical display devices. The optically clear shear thickening fluid includes: (a) a solid nanoparticle having an average particle size equal to or less than 100 nm; (b) at least one polymer; and (c) a liquid medium. The at least one polymer is substantially soluble in the liquid medium.
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公开(公告)号:US20190235385A1
公开(公告)日:2019-08-01
申请号:US16245631
申请日:2019-01-11
Applicant: Rohm and Haas Electronic Materials LLC
Inventor: Cong Liu , Doris H. Kang , Deyan Wang , Cheng-Bai Xu , Mingqi Li , Irvinder Kaur
IPC: G03F7/11 , G03F7/038 , G03F7/09 , G03F7/16 , G03F7/00 , G03F7/40 , G03F7/20 , H01L21/027 , G03F7/38 , B05C11/08
Abstract: Photoresist topcoat compositions, comprising: a first polymer comprising a first repeat unit of general formula (I) and a second repeat unit of general formula (II): wherein: R1 independently represents H, F or optionally fluorinated C1 to C4 alkyl; R2 represents optionally fluorinated linear, branched or cyclic C1 to C20 alkyl; L1 represents a single bond or a multivalent linking group; and n is an integer of from 1 to 5; a second polymer comprising a first repeat unit of general formula (III) and a second repeat unit of general formula (IV): wherein: R3 independently represents H, F or optionally fluorinated C1 to C4 alkyl; R4 represents linear, branched or cyclic C1 to C20 alkyl; R5 represents linear, branched or cyclic C1 to C20 fluoroalkyl; L2 represents a single bond or a multivalent linking group; and n is an integer of from 1 to 5; and a solvent. Coated substrates coated with the described topcoat compositions and methods of processing a photoresist composition are also provided. The invention finds particular applicability in the manufacture of semiconductor devices.
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公开(公告)号:US10222699B2
公开(公告)日:2019-03-05
申请号:US14525044
申请日:2014-10-27
Applicant: Rohm and Haas Electronic Materials LLC
Inventor: Deyan Wang , Cheng-Bai Xu , George G. Barclay
IPC: G03F7/004 , G03F7/20 , H01L21/027 , C08F220/22 , C08F220/24 , C08F220/26 , G03F7/039 , G03F7/075 , G03F7/038
Abstract: New photoresist compositions are provided that are useful for immersion lithography. Preferred photoresist compositions of the invention comprises two or more distinct materials that can be substantially non-mixable with a resin component of the resist. Particularly preferred photoresists of the invention can exhibit reduced leaching of resist materials into an immersion fluid contacting the resist layer during immersion lithography processing.
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公开(公告)号:US10197918B2
公开(公告)日:2019-02-05
申请号:US15730875
申请日:2017-10-12
Applicant: Rohm and Haas Electronic Materials LLC
Inventor: Cong Liu , Doris H. Kang , Deyan Wang , Cheng-Bai Xu , Mingqi Li , Irvinder Kaur
IPC: G03F7/11 , G03F7/09 , G03F7/038 , B05C11/08 , G03F7/00 , G03F7/16 , H01L21/027 , G03F7/40 , G03F7/38
Abstract: Photoresist topcoat compositions, comprising: a first polymer comprising a first repeat unit of general formula (I) and a second repeat unit of general formula (II): wherein: R1 independently represents H, F or optionally fluorinated C1 to C4 alkyl; R2 represents optionally fluorinated linear, branched or cyclic C1 to C20 alkyl; L1 represents a single bond or a multivalent linking group; and n is an integer of from 1 to 5; a second polymer comprising a first repeat unit of general formula (III) and a second repeat unit of general formula (IV): wherein: R3 independently represents H, F or optionally fluorinated C1 to C4 alkyl; R4 represents linear, branched or cyclic C1 to C20 alkyl; R5 represents linear, branched or cyclic C1 to C20 fluoroalkyl; L2 represents a single bond or a multivalent linking group; and n is an integer of from 1 to 5; and a solvent. Coated substrates coated with the described topcoat compositions and methods of processing a photoresist composition are also provided. The invention finds particular applicability in the manufacture of semiconductor devices.
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公开(公告)号:US20180286598A1
公开(公告)日:2018-10-04
申请号:US15764543
申请日:2015-09-29
Inventor: Deyan Wang , Xiuyan Wang , Shaoguang Feng , Qiaowei Li , Qingqing Pang , Peter Trefonas, III , Zhijian Lu , Hongyu Chen
Abstract: A method of making a multilayer structure is provided, comprising providing a substrate; providing a coating composition, comprising: a liquid carrier and a MX/graphitic carbon precursor material having a formula (I); disposing the coating composition on the substrate to form a composite; optionally, baking the composite; annealing the composite under a forming gas atmosphere; whereby the composite is converted into an MX layer and a graphitic carbon layer disposed on the substrate providing the multilayer structure; wherein the MX layer is interposed between the substrate and the graphitic carbon layer in the multilayer structure.
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公开(公告)号:US20180273388A1
公开(公告)日:2018-09-27
申请号:US15764485
申请日:2015-09-29
Applicant: Rohm and Haas Electronic Materials LLC
Inventor: Deyan Wang , Xiuyan Wang , Shaoguang Feng , Qiaowei Li , Qingqing Pang , Peter Trefonas, III , Hongyu Chen
IPC: C01B32/205 , C09D5/00
CPC classification number: C01B32/205 , C01B32/184 , C01B32/20 , C01P2002/72 , C01P2002/82 , C01P2004/04 , C09D5/008
Abstract: A method of making a graphitic carbon sheet is provided, comprising providing a substrate; providing a coating composition, comprising: a liquid carrier and a MX/graphitic carbon precursor material having a formula (I); disposing the coating composition on the substrate to form a composite; optionally, baking the composite; annealing the composite under a forming gas atmosphere; whereby the composite is converted into an MX layer and a graphitic carbon layer disposed on the substrate providing a multilayer structure; wherein the MX layer is interposed between the substrate and the graphitic carbon layer in the multilayer structure; exposing the multilayer structure to an acid; and, recovering the graphitic carbon layer as the freestanding graphitic carbon sheet.
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公开(公告)号:US20180224741A1
公开(公告)日:2018-08-09
申请号:US15747897
申请日:2016-07-11
Applicant: Rohm and Haas Electronic Materials LLC
Inventor: Peng-Wei Chuang , Deyan Wang , Jibin Sun , Peter Trefonas, III , Kathleen M. O'Connell
IPC: G03F7/00 , G03F7/004 , G03F7/037 , G03F7/16 , G03F7/20 , G03F7/32 , G03F7/40 , H01L27/32 , H01L51/56 , H01L51/52 , C08F220/18 , C09D133/08 , C08G61/12 , C09D165/00
CPC classification number: G03F7/0007 , C08F220/18 , C08F2800/20 , C08G61/124 , C08G2261/124 , C08G2261/1412 , C08G2261/1422 , C08G2261/1426 , C08G2261/148 , C08G2261/228 , C08G2261/3221 , C08G2261/3324 , C08G2261/3327 , C08G2261/95 , C09D133/08 , C09D165/00 , G03F7/0044 , G03F7/0226 , G03F7/0233 , G03F7/037 , G03F7/162 , G03F7/168 , G03F7/2004 , G03F7/327 , G03F7/40 , H01L27/3246 , H01L51/5221 , H01L51/56
Abstract: A photoimageable composition for preparing a polymeric binder having of one or more of monomer unit copolymers, a photoactive compound, and one or more organometallic compounds is provided. The copolymers include one or more hydroxyl or carboxyl functional groups that react with the organometallic compound to form a crosslinked network upon curing. The photoimageable compositions may be particularly useful in forming a pixel-defining layer of an electronic device. such as an organic light emitting diode. In particular, photoimageable compositions in accordance with embodiments of the present invention are insoluble in the developer prior to exposure to radiation, soluble in the developer following radiation exposure, and have relatively high glass transition temperatures (Tg) making them useful in forming a pixel-defining layer.
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