公开(公告)号：US20170274364A1

公开(公告)日：2017-09-28

申请号：US15505785

申请日：2015-08-21

Applicant: SABIC Global Technologies B.V.

Inventor： Hicham Idriss ,  Maher Al-Oufi

IPC: B01J35/00 ,  B01J23/48 ,  B01J23/72 ,  C25B1/04 ,  C01B13/02 ,  C01B3/04 ,  C02F1/32 ,  B01J21/06 ,  B01J23/89

CPC classification number: B01J35/004 ,  B01J21/063 ,  B01J23/002 ,  B01J23/06 ,  B01J23/48 ,  B01J23/66 ,  B01J23/72 ,  B01J23/8913 ,  B01J35/0013 ,  B01J35/002 ,  B01J35/006 ,  B01J35/10 ,  B01J37/0203 ,  B01J37/0207 ,  B01J37/024 ,  B01J37/088 ,  B01J2523/00 ,  C01B3/042 ,  C01B13/0207 ,  C02F1/32 ,  C25B1/003 ,  C25B1/04 ,  C25B3/02 ,  Y02E60/364 ,  Y02E60/368 ,  B01J2523/18 ,  B01J2523/47 ,  B01J2523/824 ,  B01J2523/845

Abstract: A photocatalyst and a method for producing hydrogen and oxygen from water by photocatalytic electrolysis are disclosed. The photocatalyst includes a photoactive material and metal or metal alloy material (15)—e.g. pure particles or alloys of Au, Pd and Ag—capable of having plasmon resonance properties deposited on the surface of the photoactive material. The photoactive material includes a p-n junction (17) formed by contact of a n-type semiconductor material (10), such as mixed phase TiO2 nano particles (anatase to rutile ratio of 1.5 to 1 or greater), and a p-type semiconductor material (16), such as CoO or Cu2O.

公开(公告)号：US09770706B2

公开(公告)日：2017-09-26

申请号：US14891212

申请日：2014-06-05

Applicant: SAUDI BASIC INDUSTRIES CORPORATION

Inventor： Chandra Mondal Kartick ,  Mayank Harishbhai Vyas ,  Sankar Sasmal

IPC: C01B3/40 ,  B01J21/04 ,  B01J21/06 ,  B01J21/08 ,  B01J21/10 ,  B01J21/12 ,  B01J21/14 ,  B01J23/02 ,  B01J23/10 ,  B01J23/75 ,  B01J23/755 ,  B01J23/78 ,  B01J23/83 ,  B01J23/835 ,  B01J23/847 ,  B01J35/10 ,  B01J37/00 ,  B01J37/02 ,  B01J37/08

CPC classification number: B01J23/78 ,  B01J35/10 ,  B01J35/1038 ,  B01J35/1061 ,  B01J37/0036 ,  B01J37/0201 ,  B01J37/0236 ,  B01J37/08 ,  C01B3/40 ,  C01B2203/0238 ,  C01B2203/1052 ,  C01B2203/1058 ,  C01B2203/1082 ,  C01B2203/1094 ,  C01B2203/1241 ,  Y02P20/52

Abstract: A catalyst for performing carbon dioxide reforming of methane to produce syngas, that includes cobalt, nickel and magnesium oxides disposed a support.

公开(公告)号：US20170189896A1

公开(公告)日：2017-07-06

申请号：US15314853

申请日：2015-05-27

Applicant: L'Air Liquide, Société Anonyme pour I'Etude et I'Exploitation des Procédés Georges Claude ,  Centre National de la Recherche Scientifique ,  L'ECOLE SUPERIEURE DE CHIMIE-PHYSIQUE-ELECTRONIQUE DE LYON

Inventor： Marie BASIN ,  Caroline BERTAIL ,  Pascal DEL-GALLO ,  Daniel GARY ,  Amara FEZOUA ,  Nik LYGEROS ,  Clémence NIKITINE ,  Isabelle PITAULT ,  Frédéric BORNETTE

IPC: B01J35/02 ,  B01J35/10

CPC classification number: B01J35/026 ,  B01J8/0214 ,  B01J19/30 ,  B01J23/28 ,  B01J23/56 ,  B01J23/74 ,  B01J35/023 ,  B01J35/04 ,  B01J35/10 ,  B01J35/1028 ,  B01J2208/00539 ,  B01J2219/30265 ,  B01J2219/30416 ,  B01J2219/30475 ,  B01J2219/3083 ,  B01J2219/312 ,  C01B3/40 ,  C01B2203/0233 ,  C01B2203/0238 ,  C01B2203/0244 ,  C01B2203/0261 ,  C01B2203/0266 ,  C01B2203/1217 ,  C01B2203/1223 ,  C01B2203/1229 ,  C01B2203/1235 ,  C01B2203/1241 ,  C01B2203/1247 ,  C07C1/0425 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2521/10 ,  C07C2523/02 ,  C07C2523/10 ,  C07C2523/28 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/46 ,  C07C2523/72 ,  C07C2523/745 ,  C07C2523/75 ,  C07C2523/755 ,  C10G35/06 ,  C10G35/085 ,  Y02P20/142 ,  Y02P20/52 ,  C07C9/04

Abstract: A catalyst for catalytic reactors of which the outer shape is a helix with n blades, where n is greater than or equal to 1, wherein the stack void fraction percentage is between 75% and 85% and the surface area/volume ratio is greater than 1000 square meters/square meters.

公开(公告)号：US20170136448A1

公开(公告)日：2017-05-18

申请号：US15417146

申请日：2017-01-26

Applicant: Bi-Zeng ZHAN

Inventor： Bi-Zeng ZHAN

IPC: B01J29/16 ,  C10G67/04 ,  B01J35/10 ,  C10G65/12 ,  B01J23/888 ,  B01J35/00

CPC classification number: B01J29/166 ,  B01J21/12 ,  B01J23/882 ,  B01J23/883 ,  B01J23/888 ,  B01J29/084 ,  B01J35/0006 ,  B01J35/002 ,  B01J35/10 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B01J37/04 ,  C10G65/12 ,  C10G67/04 ,  C10G2400/10

Abstract: Hydrocracking catalysts and hydrocracking processes for the selective production of lube base stocks are disclosed. The hydrocracking catalyst contains a low acidity, highly dealuminated USY zeolite having a zeolite acid site density of from 1 to 100 micromole/g, a catalyst support, and one or more metals. The hydrocracking catalysts can maximize lube base stock yield while providing for effective impurity removal and VI enhancement at lower hydrocracking conversions.

公开(公告)号：US20170050897A1

公开(公告)日：2017-02-23

申请号：US15308514

申请日：2015-06-22

Applicant: SABIC Global Technologies B.V.

Inventor： Hicham Idriss

IPC: C07C1/24 ,  B01J21/06 ,  B01J37/08 ,  B01J35/02 ,  B01J35/10 ,  B01J37/02 ,  B01J23/52 ,  B01J35/00

CPC classification number: C07C1/24 ,  B01J21/063 ,  B01J23/52 ,  B01J35/0013 ,  B01J35/002 ,  B01J35/023 ,  B01J35/026 ,  B01J35/10 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1057 ,  B01J35/1061 ,  B01J35/1066 ,  B01J37/0018 ,  B01J37/0221 ,  B01J37/036 ,  B01J37/08 ,  B01J37/16

Abstract: Disclosed is a catalyst capable of producing benzene from ethanol comprising a titanium dioxide support, gold nanostructures dispersed on the surface of the titanium dioxide support, and ethanol adsorbed onto the surface of the titanium dioxide support, wherein the catalyst is capable of producing benzene from the adsorbed ethanol such that the benzene carbon yield from the adsorbed ethanol is at least 10% when the catalyst is heated to a temperature of 350 to 700 K.

Abstract translation: 公开了一种能够从乙醇生产苯的催化剂，其包含二氧化钛载体，分散在二氧化钛载体的表面上的金纳米结构和吸附在二氧化钛载体的表面上的乙醇，其中催化剂能够从 吸附的乙醇使得当催化剂加热至350至700K的温度时，来自吸附的乙醇的苯碳产率至少为10％。

公开(公告)号：US09573124B2

公开(公告)日：2017-02-21

申请号：US14283302

申请日：2014-05-21

Applicant: Adeola Florence Ojo ,  Yihua Zhang ,  Stacey Ian Zones ,  Guan-Dao Lei

Inventor： Adeola Florence Ojo ,  Yihua Zhang ,  Stacey Ian Zones ,  Guan-Dao Lei

IPC: C01B39/00 ,  B01J29/74 ,  C01B39/02 ,  B01J37/18 ,  B01J29/70 ,  B01J35/00 ,  B01J35/10 ,  C10G45/64 ,  C10G25/03 ,  C10G29/20 ,  C10G47/16

CPC classification number: B01J29/74 ,  B01J20/18 ,  B01J20/28061 ,  B01J20/28071 ,  B01J20/3057 ,  B01J20/3078 ,  B01J20/3085 ,  B01J29/7046 ,  B01J29/7492 ,  B01J35/002 ,  B01J35/10 ,  B01J35/1019 ,  B01J35/1038 ,  B01J37/0018 ,  B01J37/0207 ,  B01J37/082 ,  B01J37/18 ,  B01J37/30 ,  B01J2229/183 ,  B01J2229/186 ,  B01J2229/24 ,  B01J2229/38 ,  B01J2229/40 ,  B01J2229/42 ,  C01B39/026 ,  C01B39/06 ,  C01B39/48 ,  C01P2006/12 ,  C01P2006/14 ,  C10G25/03 ,  C10G29/205 ,  C10G45/64 ,  C10G47/16 ,  C10G65/043 ,  C10G2300/70

Abstract: A new crystalline molecular sieve designated SSZ-95 is disclosed. In general, SSZ-95 is synthesized from a reaction mixture suitable for synthesizing MTT-type molecular sieves and maintaining the mixture under crystallization conditions sufficient to form product. The product molecular sieve is subjected to a pre-calcination step, and ion-exchange to remove extra-framework cations, and a post-calcination step. The molecular sieve has a MTT-type framework and a H-D exchangeable acid site density of 0 to 50% relative to molecular sieve SSZ-32.

Abstract translation: 公开了一种称为SSZ-95的新型结晶分子筛。 通常，从适合于合成MTT型分子筛的反应混合物合成SSZ-95，并将混合物保持在足以形成产物的结晶条件下。 对产物分子筛进行预煅烧步骤，并进行离子交换以除去框架外的阳离子，并进行后煅烧步骤。 分子筛具有相对于分子筛SSZ-32的MTT型骨架和H-D可交换酸性位点的0-50％的密度。

公开(公告)号：US20170036198A1

公开(公告)日：2017-02-09

申请号：US15331925

申请日：2016-10-24

Applicant: WUHAN KAIDI ENGINEERING TECHNOLOGY RESEARCH INSTITUTE CO., LTD.

Inventor： Shasha RAO ,  Dechen SONG ,  Qianqian LIU ,  Shenke ZHENG

IPC: B01J31/02 ,  B01J21/08 ,  B01J35/00 ,  B01J35/10 ,  C10G2/00 ,  B01J33/00 ,  B01J37/02 ,  B01J37/00 ,  B01J37/08 ,  B01J23/75 ,  B01J35/02

CPC classification number: B01J31/0274 ,  B01J21/08 ,  B01J23/75 ,  B01J33/00 ,  B01J35/0006 ,  B01J35/0013 ,  B01J35/026 ,  B01J35/10 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B01J37/0018 ,  B01J37/0244 ,  B01J37/088 ,  C10G2/00

Abstract: A catalyst including cobalt, a carrier including silica, and a selective promoter including zirconium. The cobalt and the selective promoter are disposed on the surface of the carrier, and the outer surfaces of the active component cobalt and the selective promoter zirconium are coated with a shell layer including a mesoporous material. A method for preparing the catalyst, including: 1) soaking the carrier including silica into an aqueous solution including a zirconium salt, aging, drying, and calcining a resulting mixture to yield a zirconium-loaded carrier including silica; 2) soaking the zirconium-loaded carrier including silica into an aqueous solution including a cobalt salt, aging, drying, calcining a resulting mixture to yield a primary cobalt-based catalyst; 3) preparing a precursor solution of a mesoporous material; and 4) soaking the primary cobalt-based catalyst into the precursor solution of the mesoporous material; and crystalizing, washing, drying, and calcining a resulting mixture.

Abstract translation: 包括钴的催化剂，包含二氧化硅的载体和包含锆的选择性促进剂。 钴和选择性促进剂设置在载体的表面上，活性组分钴和选择性促进剂锆的外表面涂覆有包含介孔材料的壳层。 一种制备催化剂的方法，包括：1）将包含二氧化硅的载体浸入包含锆盐的水溶液中，老化，干燥和煅烧所得混合物，得到包含二氧化硅的负载锆的载体; 2）将包含二氧化硅的负载锆的载体浸入包括钴盐的水溶液中，老化，干燥，煅烧所得混合物，得到初级钴基催化剂; 3）制备介孔材料的前体溶液; 和4）将初级钴基催化剂浸入介孔材料的前体溶液中; 并对所得混合物进行结晶，洗涤，干燥和煅烧。

公开(公告)号：US09540573B2

公开(公告)日：2017-01-10

申请号：US14082687

申请日：2013-11-18

Applicant: Shell Oil Company

Inventor： Opinder Kishan Bhan

IPC: C10G45/08 ,  B01J21/04 ,  B01J23/755 ,  B01J23/882 ,  B01J27/19 ,  B01J35/10 ,  B01J37/00 ,  B01J37/08 ,  B01J23/28 ,  B01J23/75 ,  B01J23/88

CPC classification number: C10G45/08 ,  B01J21/04 ,  B01J23/28 ,  B01J23/75 ,  B01J23/755 ,  B01J23/88 ,  B01J23/882 ,  B01J27/19 ,  B01J35/10 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B01J35/108 ,  B01J37/0009 ,  B01J37/08 ,  C10G2300/1055 ,  C10G2300/202 ,  C10G2400/04

Abstract: A method of making a high activity catalyst composition suitable for use in the hydrodesulfurization of a middle distillate feed, such as diesel fuel, having a high concentration of sulfur, to thereby provide a low sulfur middle distillate product. The method comprises heat treating aluminum hydroxide under controlled temperature conditions thereby converting the aluminum hydroxide to gamma-alumina to give a converted aluminum hydroxide, and controlling the fraction of converted aluminum hydroxide that is gamma-alumina. A catalytic component is incorporated into the converted aluminum hydroxide to provide an intermediate, which is heat treated to provide the high activity catalyst composition. The high activity catalyst composition can suitably be used in the hydrodesulfurization of a middle distillate feed containing a high sulfur concentration.

Abstract translation: 制备高活性催化剂组合物的方法，该组合物适用于具有高浓度硫的中等馏出物（例如柴油）的加氢脱硫，从而提供低硫中间馏分产物。 该方法包括在受控温度条件下热处理氢氧化铝，从而将氢氧化铝转化为γ-氧化铝，得到转化的氢氧化铝，并控制转化的氢氧化铝为γ-氧化铝的馏分。 将催化组分并入转化的氢氧化铝中以提供中间体，其被热处理以提供高活性催化剂组合物。 高活性催化剂组合物可适用于含有高硫浓度的中间馏分进料的加氢脱硫。

公开(公告)号：US20160367971A1

公开(公告)日：2016-12-22

申请号：US14447196

申请日：2014-07-30

Applicant: Northeastern University

Inventor： Chuanwei Zhuo ,  Yiannis Levendis

IPC: B01J23/889 ,  C01B31/02 ,  B01J35/10 ,  B01J37/08 ,  B01J23/26 ,  B01J35/00

CPC classification number: B01J37/0225 ,  B01J23/8878 ,  B01J35/10 ,  B01J37/0226 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/162 ,  C01B2202/06 ,  C01B2202/08 ,  Y10S977/752 ,  Y10S977/843

Abstract: Methods for activating the surface of steel alloys to produce catalytic substrates for the synthesis of carbon nanomaterials by chemical vapor deposition are provided. Steel alloy substrates in a variety of forms are activated by brief (10 sec to 30 min) pre-treatment at high temperature (600-1000° C.) in an oxidizing environment (e.g., air) to activate the catalyst. Upon high temperature oxidative treatment, the initially smooth and protective chromium oxide coating layer of the steel alloy is destroyed, and the catalyst surface roughness progressively increases. Upon exposure of the pre-treated SS substrates to pyrolyzed hydrocarbon gases in nitrogen, carbon nanotubes are readily formed, and their diameters correlate with substrate surface roughness. Forests of vertically aligned nanotubes can be prepared with the method.

Abstract translation: 提供了通过化学气相沉积来激活钢合金表面以生产用于合成碳纳米材料的催化底物的方法。 各种形式的钢合金基材在氧化环境（例如空气）中在高温（600-1000℃）下进行短时间（10秒至30分钟）预处理以活化催化剂。 在高温氧化处理中，钢合金的初始光滑和保护性的氧化铬涂层被破坏，催化剂表面粗糙度逐渐增加。 将预处理过的SS衬底暴露于氮气中的热解烃类气体时，容易形成碳纳米管，其直径与衬底表面粗糙度相关。 可以用该方法制备垂直排列的纳米管的森林。

公开(公告)号：US20160348012A1

公开(公告)日：2016-12-01

申请号：US15054959

申请日：2016-02-26

Applicant: WELL RESOURCES INC.

Inventor： SUOQI ZHAO ,  QIANG WEI ,  CHUNMING XU ,  ZHIMING XU ,  XUEWEN SUN ,  KENG H. CHUNG

IPC: C10G65/00

CPC classification number: B01J35/10 ,  B01J23/882 ,  B01J23/883 ,  B01J23/888 ,  B01J29/166 ,  B01J35/0006 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B01J2229/18 ,  C10G21/003 ,  C10G47/34 ,  C10G67/049 ,  C10G2300/1077 ,  C10G2300/206

Abstract: There is provided a process of treating a heavy hydrocarbon-comprising material, comprising: contacting a feed material with at least a catalyst material within a contacting zone to effect generation of a total product such that a contacting zone material is disposed within the contacting zone and consists of the catalyst material and a feed/product-comprising mixture comprising the feed material and the total product, wherein the feed/product-comprising mixture includes a Conradson carbon residue content of at least 12 weight percent, based on the total weight of the feed/product-comprising mixture, and also includes an asphaltene content of less than two (2) weight percent, based on the total weight of the feed/product-comprising mixture, and wherein the feed material includes deasphalted heavy hydrocarbon-comprising material. A heavy hydrocarbon-containing feed for a catalytic hydroprocessing or catalytic hydrocracking process is also provided, wherein the feed comprises a deasphalted heavy hydrocarbon-comprising material having a Conradson carbon residue, CCR, content greater than about 12 wt % and an asphaltene content less than about 2 wt %. The feed results in reduced catalyst deactivation or catalyst coking during the catalytic hydroprocessing or catalytic hydrocracking process.

Abstract translation: 提供了一种处理重质烃的材料的方法，其包括：使进料与至少在接触区内的催化剂材料接触以产生总产物，使得接触区材料设置在接触区内， 由催化剂材料和包含进料和总产物的进料/产物混合物组成，其中所述进料/产物混合物包含基于总重量的至少12重量％的康拉逊碳残余物含量 进料/产品混合物，并且还包括基于所述进料/含产物的混合物的总重量的小于二（2）重量百分比的沥青质含量，并且其中所述进料包括脱沥青重质烃材料。 还提供了用于催化加氢处理或催化加氢裂化方法的重质含烃原料，其中所述进料包含含有Conradson碳残余物的CCR的脱沥青重质烃，含量大于约12重量％，沥青质含量小于 约2重量％。 进料导致在催化加氢处理或催化加氢裂化过程中减少催化剂失活或催化剂焦化。