Abstract:
Thermally stable, mechanically strong microporous glass articles with large pore volumes, surface areas, and varying pore sizes, and methods for making such articles are disclosed. In particle form, such as beads, the microporous glass articles are useful as catalyst supports in applications such as petroleum catalytic refiners, chemical processes and motor vehicle catalytic mufflers. The mechanical strength and the dimensional stability of the microporous glass articles at elevated temperatures can be improved if the articles are preshrunk, such as by brief exposure to high temperatures, before their intended use, and can be improved even further if treated with certain metal oxides.
Abstract:
The present invention relates to a moldable nanocomposite for producing a transparent article made of multicomponent fused silica glass, the moldable nanocomposite comprising: an organic binder; and a fused silica glass powder dispersed in the organic binder, the fused silica glass powder comprising fused silica glass particles having a diameter in the range from 5 nm to 500 nm, wherein the fused silica glass powder is pre-modified with a dopant and/or wherein at least one non-crystalline modifying agent is contained in the moldable nanocomposite and one or more dopant reagents selected from organoelement compounds, metal complexes and salts are contained in the moldable nanocomposite as the at least one non-crystalline modifying agent, and wherein the content of the fused silica glass powder in the moldable nanocomposite is at least 5 parts per volume based on 100 parts per volume of the organic binder. Further, the present invention relates to a method of producing a transparent article made of multicomponent fused silica glass.
Abstract:
Systems and methods for forming an oxidation protection system, on a composite structure is provided. In various embodiments, an oxidation protection system disposed on a substrate may comprise a borosilicate glass layer comprising a borosilicate glass, a base layer comprising a first pre-slurry composition comprising a first phosphate glass composition, and/or a sealing layer comprising a second pre-slurry composition comprising a second phosphate glass composition. The borosilicate glass layer, base layer, and/or sealing layer may be disposed in any suitable order relative to the composite structure.
Abstract:
A method of forming a doped silica-titania glass is provided. The method includes blending batch materials comprising silica, titania, and at least one dopant. The method also includes heating the batch materials to form a glass melt. The method further includes consolidating the glass melt to form a glass article, and annealing the glass article.
Abstract:
A glass composite for use in Extreme Ultra-Violet Lithography (EUVL) is provided. The glass composite includes a first silica-titania glass section. The glass composite further includes a second doped silica-titania glass section mechanically bonded to a surface of the first silica-titania glass section, wherein the second doped silica-titania glass section has a thickness of greater than about 1.0 inch.
Abstract:
Annealing treatments for modified titania-silica glasses and the glasses produced by the annealing treatments. The annealing treatments include an isothermal hold that facilitates equalization of non-uniformities in fictive temperature caused by non-uniformities in modifier concentration in the glasses. The annealing treatments may also include heating the glass to a higher temperature following the isothermal hold and holding the glass at that temperature for several hours. Glasses produced by the annealing treatments exhibit high spatial uniformity of CTE, CTE slope, and fictive temperature, including in the presence of a spatially non-uniform concentration of modifier.
Abstract:
Laser waveguides, methods and systems for forming a laser waveguide are provided. The waveguide includes an inner cladding layer surrounding a central axis and a glass core surrounding and located outside of the inner cladding layer. The glass core includes a laser-active material. The waveguide includes an outer cladding layer surrounding and located outside of the glass core. The inner cladding, outer cladding and/or core may surround a hollow central channel or bore and may be annular in shape.
Abstract:
A doped silica-titania (“DST”) glass article that includes a glass article having a glass composition comprising a silica-titania base glass containing titania at 7 to 14 wt. % and a balance of silica, and a dopant selected from the group consisting of (a) F at 0.7 to 1.5 wt. %, (b) B2O3 at 1.5 to 5 wt. %, (c) OH at 1000 to 3000 ppm, and (d) B2O3 at 0.5 to 2.5 wt. % and OH at 100 to 1400 ppm. The glass article has an expansivity slope of less than about 1.3 ppb/K2 at 20° C. For DST glass articles doped with F or B2O3, the OH level can be held to less than 10 ppm, or less than 100 ppm, respectively. In many aspects, the DST glass articles are substantially free of titania in crystalline form.
Abstract:
The present invention relates to an MMF with a structure for relaxing wavelength dependence of transmission bandwidth. In the MMF, a doping amount of a dopant for control of refractive index is adjusted, so as to make each of an OFL bandwidth at a wavelength of 850 nm and an OFL bandwidth at a wavelength of at least one of 980 nm, 1060 nm, and 1300 nm become not less than 1500 MHz·km, make the OFL bandwidth at the wavelength of at least one of 980 nm, 1060 nm, and 1300 nm become wider than the OFL bandwidth at the wavelength of 850 nm, and effectively suppress increase in transmission loss.
Abstract:
A boron-doped titania-silica glass containing 0.1 wt % to 8.0 wt % boron, 9.0 wt % to 16.0 wt % TiO2, and 76.0 wt % to 90.9 wt % SiO2. The glass may further include F, Nb, Ta, Al, Li, Na, K, Ca, and Mg, individually or in combinations of two or more, at levels up to 4 wt %. The glass may have an OH concentration of more than 10 ppm. The glass features a CTE slope at 20° C. of less than 1 ppb/K2. The fictive temperature of the glass is less than 825° C. and the peak CTE of the glass is less than 30 ppb/K. The glass has two crossover temperatures and a wide temperature interval over which CTE is close to zero. The uniformity of each crossover temperature relative to its average over a volume of at least 50 cm3 is within ±5° C.