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    SOLAR ENERGY BASED COUNTINUOUS PROCESS AND REACTOR SYSTEM FOR THE PRODUCTION OF AN ALKENE BY DEHYDROGENATION OF THE CORRESPONDING ALKANE
    63.
    发明申请
    SOLAR ENERGY BASED COUNTINUOUS PROCESS AND REACTOR SYSTEM FOR THE PRODUCTION OF AN ALKENE BY DEHYDROGENATION OF THE CORRESPONDING ALKANE 审中-公开
    通过对相应的碱进行脱氢生产烷基苯基的太阳能基于反应器的反应器和反应器系统

    公开(公告)号：US20150139896A1

    公开(公告)日：2015-05-21

    申请号：US14396622

    申请日：2013-04-19

    Applicant: SAUDI BASIC INDUSTRIES CORPORATION

    Inventor： Mohamed Sabri Abdelghani ,  Mustapha Karime ,  Zeeshan Nawaz ,  Abdullah Mohammad Al-Qahtani

    IPC: C07C5/48 ,  C01B3/38 ,  C07C5/333

    CPC classification number: C07C5/48 ,  C01B3/386 ,  C01B2203/0261 ,  C01B2203/0277 ,  C01B2203/0855 ,  C01B2203/107 ,  C01B2203/1088 ,  C07C5/3337 ,  C07C2529/068 ,  C10G35/04

    Abstract: A solar energy based continuous process and reactor system for the production of an alkene by dehydrogenation of the corresponding alkane is performed in a reactor which process comprises alternatingly performing a first mode and a second mode in the same reactor, wherein the first mode is a non-oxidative dehydrogenation wherein the non-oxidative dehydrogenation is performed by contacting the alkane with a suitable dehydrogenation catalyst at a temperature of at least 500° C. to produce the corresponding alkene and hydrogen and wherein the second mode is an oxidative dehydrogenation wherein the oxidative dehydrogenation is performed by contacting the alkane with a suitable dehydrogenation catalyst and an oxidation agent at a temperature from 300 to 500° C. to produce the corresponding alkene wherein the dehydrogenation catalyst for the oxidative dehydrogenation and the non-oxidative dehydrogenation are the same, wherein the heat for the first mode is provided by a solar energy source.

    Abstract translation: 用于通过相应烷烃脱氢生产烯烃的基于太阳能的连续方法和反应器系统在反应器中进行，该反应器包括在同一反应器中交替执行第一模式和第二模式，其中第一模式是非 氧化脱氢，其中所述非氧化脱氢是通过在至少500℃的温度下使所述烷烃与合适的脱氢催化剂接触以产生相应的烯烃和氢气进行的，其中所述第二模式是氧化脱氢，其中所述氧化脱氢 是通过使烷烃与合适的脱氢催化剂和氧化剂在300-500℃的温度下接触来制备相应的烯烃，其中用于氧化脱氢和非氧化脱氢的脱氢催化剂是相同的，其中 用于第一模式的热量由太阳能源提供 。

    TOLUENE METHYLATION WITH TRANSALKYLATION OF HEAVY AROMATICS
    66.
    发明申请
    TOLUENE METHYLATION WITH TRANSALKYLATION OF HEAVY AROMATICS 有权
    重金属离子交换甲基甲基化

    公开(公告)号：US20150073187A1

    公开(公告)日：2015-03-12

    申请号：US14022643

    申请日：2013-09-10

    Applicant: SAUDI BASIC INDUSTRIES CORPORATION

    Inventor： Ashim Kumar Ghosh ,  Mohamed Elbaccouch ,  Mohammad Shafiei ,  Murali Gopalakrishnan

    IPC: C07C2/66

    CPC classification number: C07C2/66 ,  C07C2/864 ,  C07C6/123 ,  C07C2529/40 ,  C07C15/08

    Abstract: A method of producing a purified mixed xylene comprising: introducing toluene and methanol to an alkylation reactor (32); reacting the toluene and the methanol in the alkylation reactor (32) to form a hydrocarbon stream (22) comprising a first mixed xylene, wherein the alkylation reactor (32) comprises an alkylation catalyst; separating the hydrocarbon stream (22) into a toluene stream (24) and a separated C8+ stream (14); introducing the toluene stream (24) to a transalkylation reactor (38) with a transalkylation catalyst to produce a transalkylated stream (17) comprising a second mixed xylene; adding the transalkylated stream (17) to the hydrocarbon stream (22); and separating a C8 product stream (19) comprising the purified mixed xylene from the separated C8+ stream (14).

    Abstract translation: 一种制备纯化的混合二甲苯的方法，包括：将甲苯和甲醇引入到烷基化反应器（32）中; 在烷基化反应器（32）中使甲苯和甲醇反应形成包含第一混合二甲苯的烃流（22），其中烷基化反应器（32）包含烷基化催化剂; 将烃流（22）分离成甲苯流（24）和分离的C8 +流（14）; 将甲苯物流（24）用烷基转移催化剂引入烷基转移反应器（38）以产生包含第二混合二甲苯的烷基转移反应流（17） 将烷基转移流（17）加入到烃流（22）中; 以及从分离的C8 +流（14）分离包含纯化的混合二甲苯的C8产物流（19）。

    CATALYST COMPONENT FOR THE POLYMERIZATION OF OLEFINS
    67.
    发明申请
    CATALYST COMPONENT FOR THE POLYMERIZATION OF OLEFINS 有权
    用于烯烃聚合的催化剂组分

    公开(公告)号：US20150038660A1

    公开(公告)日：2015-02-05

    申请号：US14380473

    申请日：2013-02-21

    Applicant: SAUDI BASIC INDUSTRIES CORPORATION

    Inventor： Mansour I. Taftaf ,  Nourdin Ghalit ,  Gennadii Dimitrievich Bukatov ,  Sergei Andreevich Sergeev ,  Vladimir Aleksandrovich Zakharov ,  Jaiprakash Brijlal Sainani ,  Aurora Alexandra Batinas-Geurts

    IPC: C08F110/06

    CPC classification number: C08F110/06 ,  C08F10/00 ,  C08F4/651 ,  C08F4/6565

    Abstract: The present invention relates to a catalyst component for polymerization of an olefin comprising a compound represented by the Fischer projection of: wherein R5 is substituted or unsubstituted hydrocarbyl having 1 to 20 carbon atoms; R6 and R7 are different and independently selected from the group consisting of hydrogen, halogen and substituted or unsubstituted hydrocarbyl having 1 to 20 carbon atoms; R5-R7 optionally containing one or more hetero-atoms replacing one or more carbon atoms, one or more hydrogen atom or both, wherein said hetero-atom is selected from the group consisting of nitrogen, oxygen, sulfur, silicon, phosphorus and halogen; and wherein the compound of Formula (I) is the only internal electron donor in the catalyst component. The present invention also relates to a process for preparing a polymerization catalyst component comprising the steps of i) contacting a compound R4zMgX2-z wherein R4 is aromatic, aliphatic or cyclo-aliphatic group containing 1 to 20 carbon atoms, X is a halide, and z is in a range of larger than 0 and smaller than 2, with an alkoxy- or aryloxy-containing silane compound to give a first intermediate reaction product; ii) contacting the first intermediate reaction product with at least one activating compound selected from the group formed by internal electron donors and compounds of formula M(OR2)v-w(R3)w, wherein M can be Ti, Zr, Hf, Al or Si, each R2 and R3, independently, represent an alkyl, alkenyl or aryl group, v is the valency of M and w is smaller than v and iii) contacting the second intermediate reaction product with a halogen-containing Ti-compound and an internal electron donor represented by the Fischer projection of formula (I); and optionally with at least one compound selected from a group comprising a monoester, a diester and a 1,3-diether.

    Abstract translation: 本发明涉及一种用于聚合烯烃的催化剂组分，其包含由Fischer投影表示的化合物：其中R5是取代或未取代的具有1至20个碳原子的烃基; R6和R7不同且独立地选自氢，卤素和具有1至20个碳原子的取代或未取代的烃基; 任选地含有一个或多个取代一个或多个碳原子的杂原子，一个或多个氢原子或两者的R 5 -R 7，其中所述杂原子选自氮，氧，硫，硅，磷和卤素; 并且其中式（I）的化合物是催化剂组分中唯一的内电子给体。 本发明还涉及一种制备聚合催化剂组分的方法，包括以下步骤：i）使化合物R4zMgX2-z与其中R4是芳族的，含有1至20个碳原子的脂族或环脂族基团，X是卤化物，和 z在大于0且小于2的范围内，与含烷氧基或芳氧基的硅烷化合物反应得到第一中间反应产物; ii）使第一中间反应产物与至少一种选自由内电子给体形成的基团和式M（OR 2）vw（R 3）w）的化合物接触，其中M可以是Ti，Zr，Hf，Al或Si ，每个R 2和R 3独立地表示烷基，烯基或芳基，v是M的化合价，w小于v，和iii）使第二中间体反应产物与含卤素的Ti化合物和内部电子 由式（I）的费舍尔投影表示的供体; 和任选地与至少一种选自包含单酯，二酯和1,3-二醚的化合物。

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