Ultrasensitive spectrophotometer
    81.
    发明申请
    Ultrasensitive spectrophotometer 有权
    超声分光光度计

    公开(公告)号:US20060152726A1

    公开(公告)日:2006-07-13

    申请号:US11035034

    申请日:2005-01-13

    Inventor: David Larsen Zhi Xu

    Abstract: The invention concerns measurements in which light interacts with matter giving rise to changes in light intensity, and preferred embodiment spectrophotometer devices of the invention provide for ultrasensitive measurements through a reflection interaction with matter. The level of light source noise in these measurements can be reduced in accordance with the invention. Preferred embodiments of the invention use sealed housings lacking an internal light source, and reflection based sample and reference cells. In some embodiments a substantially solid thermally conductive housing is used. Other features of preferred embodiments include particular reflection based sample and reference cells. A total internal reflection embodiment includes, for example, a prism including an interaction surface, a detector, a lens that focuses a beam output from the prism onto the detector, and a closed interaction volume having an inlet and an outlet for delivering gas or liquid to the interaction surface. In a specular reflection embodiment, a reflective surface is used instead of a prism. In a diffuse reflection embodiment a matte surface is used instead of a prism and the matte surface produces scattering. Aspects of the invention include identification of noise-contributing components in spectrophotometry and the select set of preferred features in a given embodiment, and noise levels very near the shot noise limit may be realized with application of preferred embodiment devices.

    Abstract translation: 本发明涉及测量光,其中光与引起光强变化的物质相互作用,并且本发明的优选实施方式的分光光度计装置通过与物质的反射相互作用来提供超灵敏测量。 根据本发明,可以减少这些测量中的光源噪声的水平。 本发明的优选实施例使用缺少内部光源的密封壳体,以及基于反射的样品和参考单元。 在一些实施例中,使用基本上固体的导热壳体。 优选实施方案的其它特征包括特定的基于反射的样品和参考细胞。 全内反射实施例包括例如包括相互作用表面的棱镜,检测器,将从棱镜输出的光束聚焦到检测器上的透镜以及具有用于输送气体或液体的入口和出口的封闭相互作用体积 到相互作用的表面。 在镜面反射实施例中,使用反射表面代替棱镜。 在漫反射实施例中,使用无光泽表面代替棱镜,并且无光泽表面产生散射。 本发明的方面包括在给定实施例中识别分光光度法中的噪声贡献成分以及在一特定实施例中选择的一组优选特征,并且通过应用优选实施例装置可以实现非常接近散粒噪声极限的噪声水平。

    Refractive-diffractive spectrometer
    83.
    发明申请
    Refractive-diffractive spectrometer 失效
    折射衍射光谱仪

    公开(公告)号:US20050219525A1

    公开(公告)日:2005-10-06

    申请号:US11083895

    申请日:2005-03-17

    Applicant: Edward Granger

    Inventor: Edward Granger

    Abstract: A diffraction grating and a prism with the appropriate characteristics are employed to provide a combined dispersive characteristic that is substantially linear over the visible spectrum. Radiation from the grating and prism is collimated by a lens towards a detector array. The grating or a telecentric stop between the grating and prism is placed at a focal point of the lens in a telecentric arrangement so that equal magnification is achieved at the detector array. If the detector array is replaced by a plurality of optical channels, a multiplexer/demultiplexer is obtained.

    Abstract translation: 使用衍射光栅和具有适当特性的棱镜来提供在可见光谱上基本上线性的组合色散特性。 来自光栅和棱镜的辐射由透镜朝向检测器阵列准直。 光栅或光栅和棱镜之间的远心光阑以远心布置放置在透镜的焦点处,使得在检测器阵列处实现相等的放大倍率。 如果检测器阵列被多个光通道替代,则获得多路复用器/解复用器。

    Optical system and method for optically analyzing light from a sample
    84.
    发明授权
    Optical system and method for optically analyzing light from a sample 失效
    用于光学分析来自样品的光的光学系统和方法

    公开(公告)号:US06927852B2

    公开(公告)日:2005-08-09

    申请号:US10773712

    申请日:2004-02-05

    Inventor: Richard T. Reel

    Abstract: An optical system for analyzing light from a plurality of samples is provided. The optical system includes a plurality of holders adapted to have samples located therein, a collection lens, a transmission grating, and a reimaging lens. The collection lens is configured to receive and substantially collimate light from the samples. The transmission grating is configured to spectrally disperse the substantially collimated light from the collection lens. The reimaging lens is configured to receive the light from the light dispersing element and direct the light onto a light detection device. A method of optically analyzing at least one sample is also provided.

    Abstract translation: 提供了一种用于分析来自多个样品的光的光学系统。 光学系统包括多个保持器,其适于使样本位于其中,收集透镜,透射光栅和再成像透镜。 收集透镜被配置为接收并基本上准直来自样品的光。 透射光栅被配置为光谱地分散来自收集透镜的基本上准直的光。 该成像透镜被配置为接收来自光分散元件的光并将光引导到光检测装置上。 还提供了一种光学分析至少一个样品的方法。

    Light spectrum detecting apparatus
    85.
    发明授权
    Light spectrum detecting apparatus 失效
    光谱检测装置

    公开(公告)号:US06859274B2

    公开(公告)日:2005-02-22

    申请号:US10333991

    申请日:2001-07-05

    Applicant: Naoki Inamoto

    Inventor: Naoki Inamoto

    CPC classification number: G01J3/02 G01J3/0262 G01J3/2803

    Abstract: A light spectrum detecting apparatus according to the present invention comprises a photodetector (13) and a light transmitting plate (13b) covering a light receiving surface (13a) of the photodetector (13), and in the apparatus, a front surface S of the light transmitting plate 13b is inclined and, among incidents lights, any light once reflected by a back surface T of the light transmitting plate (13b) travels thereafter, with being totally reflected by the front surface S and the back surface T of the light transmitting plate (13b), to a side surface 13d of the light transmitting plate (13b). Any stray light can be prevented from entering the photodetector (13).

    Abstract translation: 根据本发明的光谱检测装置包括光电检测器(13)和覆盖光电检测器(13)的光接收表面(13a)的透光板(13b),并且在该装置中, 透光板13b是倾斜的,并且在事件发光中,一旦透光板(13b)的背面T反射的任何光在其之后行进,被透光板的前表面S和背面T完全反射 (13b)连接到透光板(13b)的侧表面13d。 可以防止任何杂散光进入光电检测器(13)。

    Photodetector and spectrometer using the same
    86.
    发明申请
    Photodetector and spectrometer using the same 有权
    光电检测器和光谱仪使用相同

    公开(公告)号:US20040239931A1

    公开(公告)日:2004-12-02

    申请号:US10854628

    申请日:2004-05-27

    CPC classification number: G01J3/2803 G01J3/0256 G01J3/0262 G01J3/0291

    Abstract: A spectrometer is configured by using a photodetector 1B which comprises a semiconductor substrate 10 having an upper surface 10a, a photodiode array 11 having a plurality of photodiodes 12 aligned on the upper surface 10a of the substrate 10, and a light input section 13 including an opening formed in a predetermined positional relationship to the photodiode array 11; and a main body 2 having a plate portion 20 and support portions 21 and 22 mounted on the substrate 10 of the photodetector 1B. The spectrometer is provided with a lens 23 protruded from a lower face 20b of the plate portion 20 and a planar aberration-reduced blazed reflection diffraction grating 24 provided on an upper face 20a of the plate portion 20 for separating incident light having entered through the light input section 13 and passed through the lens 23 into its spectral components, and configured to detect the spectral components with the photodiode array 11. Thus, a photodetector capable of improving the positioning accuracy of components when it is applied to a spectrometer and the spectrometer using the same are realized.

    Abstract translation: 通过使用光电检测器1B构成光谱仪,该光电检测器1B包括具有上表面10a的半导体衬底10,具有在衬底10的上表面10a上排列的多个光电二极管12的光电二极管阵列11和光输入部13, 开口以与光电二极管阵列11的预定位置关系形成; 以及主体2,其具有安装在光电检测器1B的基板10上的板部20和支撑部21和22。 光谱仪设置有从板部20的下表面20b突出的透镜23和设置在板部20的上表面20a上的平面像差减少的闪光反射衍射光栅24,用于分离通过光入射的入射光 输入部分13并通过透镜23进入其光谱分量,并且被配置为用光电二极管阵列11检测光谱分量。因此,一种光电检测器能够在将其应用于光谱仪时提高部件的定位精度,而光谱仪使用 同样实现。

    Detector assembly having reduced stray light ghosting sensitivity
    88.
    发明授权
    Detector assembly having reduced stray light ghosting sensitivity 失效
    检测器组件具有减少的杂散光重影灵敏度

    公开(公告)号:US06677588B1

    公开(公告)日:2004-01-13

    申请号:US07292023

    申请日:1988-12-13

    Abstract: An improved detector assembly 10 having decreased sensitivity both to Narcissism and to stray light ghosting is disclosed herein. The improved detector assembly 10 of the present invention includes a housing 70 having an input aperture 142 in communication with a chamber within said housing. A detector 130 for sensing electromagnetic energy passing through the input aperture 142 within a first field of view is mounted within the chamber. Also mounted within the chamber is a detector mirror 100 for reflecting energy passing through the input aperture 142 within a second field of view outside of the first field of view. The improved assembly 10 of the present invention further includes a second mirror 110 mounted within the chamber for reflecting energy reflected by the first mirror 100 through the input aperture 142.

    Abstract translation: 本文公开了一种改进的检测器组件10,其具有降低的自恋和偏光重影的灵敏度。 本发明的改进的检测器组件10包括壳体70,壳体70具有与所述壳体内的腔室连通的输入孔142。 用于感测通过第一视场内的输入孔142的电磁能的检测器130安装在腔室内。 还安装在腔室内的是用于在第一视场外的第二视野内反射通过输入孔142的能量的检测镜100。 本发明的改进的组件10还包括安装在室内的第二反射镜110,用于反射由第一反射镜100反射的能量通过输入孔142。

    Method and apparatus for a high resolution downhole spectrometer
    89.
    发明申请
    Method and apparatus for a high resolution downhole spectrometer 审中-公开
    高分辨率井下光谱仪的方法和装置

    公开(公告)号:US20030223068A1

    公开(公告)日:2003-12-04

    申请号:US10162023

    申请日:2002-06-04

    Abstract: The present invention provides a simple, robust, and versatile high-resolution spectrometer that is suitable for downhole use. The present invention provides a method and apparatus incorporating a spinning, oscillating or stepping optical interference filter to change the angle at which light passes through the filters after passing through a sample under analysis downhole. As each filter is tilted, the color or wavelength of light passed by the filter changes. Black plates are placed between the filters to isolate each filter's photodiode. The spectrometer of the present invention is suitable for use with a wire line formation tester, such as the Baker Atlas Reservation Characterization Instrument to provide supplemental analysis and monitoring of sample clean up. The present invention is also suitable for deployment in a monitoring while drilling environment. The present invention provides a high resolution spectometer which enables quantification of a crude oil's percentage of aromatics, olefins, and saturates to estimate a sample's gas oil ratio (GOR). Gases such as CO2 are also detectable. The percentage of oil-based mud filtrate contamination in a crude oil sample can be estimated with the present invention by using a suitable training set and chemometrics, a neural network, or other type of correlation method.

    Abstract translation: 本发明提供了一种适用于井下使用的简单,坚固且通用的高分辨率光谱仪。 本发明提供了一种包括旋转,振荡或步进光学干涉滤光器的方法和装置,以改变在通过井下分析的样品之后光通过滤光器的角度。 当每个滤光片倾斜时,由滤光片传出的光线的颜色或波长发生变化。 过滤器之间放置黑色板,以隔离每个过滤器的光电二极管。 本发明的光谱仪适合与线形成测试仪一起使用,例如Baker Atlas Reservation Characterization Instrument,以提供对样品清理的补充分析和监测。 本发明也适用于在钻井环境中进行监视。 本发明提供了一种高分辨率光谱仪,其能够定量原油的芳烃,烯烃和饱和物的百分比,以估计样品的瓦斯油比(GOR)。 气体如二氧化碳也是可以检测的。 通过使用合适的训练集和化学计量学,神经网络或其他类型的相关方法,可以用本发明估算原油样品中油基泥浆滤液污染物的百分比。

    Concentric spectrometer with mitigation of internal specular reflections
    90.
    发明授权
    Concentric spectrometer with mitigation of internal specular reflections 失效
    同心光谱仪,减轻内部镜面反射

    公开(公告)号:US06538736B1

    公开(公告)日:2003-03-25

    申请号:US09705990

    申请日:2000-11-03

    Inventor: Perry A. Palumbo

    CPC classification number: G01J3/04 G01J3/02 G01J3/0262 G01J3/18

    Abstract: Concentric spectrometers are plagued with internal reflections due to inherent nature of more than one optical surface possessing a common center of curvature. Reflections from optical surfaces arise when there is a difference or change in the refractive index of the media in which an optical beam or ray of a given wavelength is propagating. Internal reflections in concentric optical systems can produce a myriad of undesirable optical phenomenon at the image plane such as multiple images of an object, interference fringes, and stray light. As a result a loss in contrast or detection limit arise from such phenomenon in which light or detectable radiation that impinges on the image plane does not add to the formation of the intended image, (stray light). The present invention produces high quality images without the optical phenomenon(s) that arise from internal reflections by removing the reflected radiation from propagating through the optical system.

    Abstract translation: 由于具有共同的曲率中心的多于一个的光学表面的固有特性,同心光谱仪受到内部反射的困扰。 当光束或给定波长的光线正在传播的介质的折射率存在差异或变化时,会产生光学表面的反射。 同心光学系统中的内部反射可能在像平面上产生无数不希望的光学现象,例如物体的多个图像,干涉条纹和杂散光。 结果,造成对比度或检测限制的损失是由于这种现象,其中照射在图像平面上的光或可检测的辐射不会增加预期图像的形成(杂散光)。 本发明通过去除通过光学系统传播的反射辐射而产生高质量图像而没有由内部反射产生的光学现象。

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