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1.发明授权Operation of diesel engines with reduced particulate emission by utilization of platinum group metal fuel additive and pass-through catalytic oxidizer 失效通过利用铂族金属燃料添加剂和直通催化氧化剂来操作具有减少的颗粒物排放的柴油发动机
公开(公告)号：US5501714A
公开(公告)日：1996-03-26
申请号：US403365
申请日：1995-03-14
Applicant: James M. Valentine , Jeremy D. Peter-Hoblyn
Inventor： James M. Valentine , Jeremy D. Peter-Hoblyn
IPC: F01N3/10 , B01D53/94 , B01J31/22 , C07F15/00 , C10L1/10 , C10L1/12 , C10L1/14 , C10L1/16 , C10L1/18 , C10L1/20 , C10L1/22 , C10L1/24 , C10L1/26 , C10L1/30 , C10L1/32 , C10L3/00 , C10L10/02 , C10L10/06 , F01N3/023 , F01N3/029 , F01N3/035 , F01N3/037 , F01N3/20 , F01N3/24 , F02B3/06 , F02B51/02 , F02D19/12 , F02D41/00
CPC classification number: B01D53/944 , B01J23/42 , B01J37/086 , C07F15/0033 , C07F15/006 , C07F15/0073 , C07F15/0086 , C10L1/10 , C10L1/12 , C10L1/14 , C10L1/1814 , C10L1/30 , C10L1/301 , C10L1/305 , C10L1/328 , C10L10/02 , C10L10/06 , C10L3/003 , F01N3/023 , F01N3/029 , F01N3/035 , F01N3/037 , F01N3/206 , F02B51/02 , F02D19/12 , B01D2255/102 , B01D2255/906 , B01D2258/012 , B01J2231/70 , B01J2531/72 , B01J2531/82 , B01J2531/822 , B01J2531/824 , B01J2531/828 , B01J2531/842 , B01J31/1805 , B01J31/20 , B01J31/2234 , B01J31/2295 , C10L1/1208 , C10L1/1225 , C10L1/1233 , C10L1/1241 , C10L1/125 , C10L1/1266 , C10L1/1275 , C10L1/1608 , C10L1/1616 , C10L1/1691 , C10L1/1802 , C10L1/1824 , C10L1/1828 , C10L1/1832 , C10L1/1852 , C10L1/1855 , C10L1/1857 , C10L1/188 , C10L1/1881 , C10L1/1883 , C10L1/1886 , C10L1/1888 , C10L1/189 , C10L1/19 , C10L1/191 , C10L1/198 , C10L1/1985 , C10L1/201 , C10L1/2222 , C10L1/2225 , C10L1/2227 , C10L1/224 , C10L1/2286 , C10L1/23 , C10L1/231 , C10L1/232 , C10L1/238 , C10L1/2437 , C10L1/2493 , C10L1/2641 , C10L1/2683 , C10L1/306 , F01N2430/04 , F02B3/06 , F05C2201/0427 , Y02T10/126
Abstract: The invention provides a method employing a fuel additive to improve the operation of a pass-through oxidation catalyst over long periods of time with continued catalytic activity and without the undesirable conversion of SO.sub.2 to SO.sub.3. A pass-through catalyst support is continuously, selectively catalyzed by the combustion of a fuel containing a platinum group metal composition which burns to release the catalyst metal in active form. The effectiveness of the process is attributed to improved combustion in the engine by the catalyst and the treatment of the catalytic oxidizer with active catalyst metal released during combustion such that, in the exhaust system, the soluble organic fraction of the particulates and the levels of gaseous unburned hydrocarbons and carbon monoxide are significantly reduced. The catalysts conditioned by the present invention cause minimal conversion of SO.sub.2 to SO.sub.3. The platinum group metal compositions soluble or dispersible in the diesel fuel and are added in amounts effective to provide concentrations of the metal in the fuel of less than 1 part per million (ppm).
Abstract translation: 本发明提供了一种使用燃料添加剂的方法，其长期持续催化活性并且不会不期望地将SO 2转化为SO 3来改善直通氧化催化剂的操作。 通过燃烧包含燃烧以释放活性形式的催化剂金属的铂族金属组合物的燃料来连续选择性催化直通催化剂载体。 该方法的有效性是由于催化剂在发动机中的燃烧改善以及在燃烧期间释放的活性催化剂金属对催化氧化剂的处理使得在排气系统中颗粒的可溶性有机部分和气态 未燃碳氢化合物和一氧化碳显着降低。 由本发明调理的催化剂导致SO 2转化为最少的SO 3。 铂族金属组合物可溶于或分散在柴油中，并以有效提供燃料中金属浓度小于百万分之一（ppm）的量加入。
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公开(公告)号：US5819529A
公开(公告)日：1998-10-13
申请号：US890145
申请日：1997-07-09
Applicant: Jeremy D. Peter-Hoblyn
Inventor： Jeremy D. Peter-Hoblyn
IPC: C10L1/14 , C10L1/16 , C10L1/18 , C10L1/20 , C10L1/24 , C10L1/26 , C10L1/28 , C10L1/30 , C10L10/00 , C10L10/02 , C10M159/18 , F01M3/00 , F02B1/04 , F02B47/00 , F02B51/02 , F02B75/02 , F01N3/00
CPC classification number: F02B47/00 , C10L1/143 , C10L1/1814 , C10L1/301 , C10L1/305 , C10L10/02 , C10M159/18 , F01M3/00 , F02B51/02 , C10L1/1616 , C10L1/1633 , C10L1/1641 , C10L1/1691 , C10L1/1832 , C10L1/1852 , C10L1/1883 , C10L1/1905 , C10L1/191 , C10L1/1985 , C10L1/201 , C10L1/207 , C10L1/2412 , C10L1/2633 , C10L1/28 , C10L1/306 , C10M2201/065 , C10M2227/08 , C10N2210/07 , C10N2240/105 , F02B1/04 , F02B2075/025 , F05C2201/0427 , Y02T10/121 , Y02T10/126
Abstract: The effectiveness is prolonged for catalytic oxidizers to reduce emissions of both HC and CO from two-stroke gasoline engines. A compound of a platinum group metal is added to the cylinder of the engine, to make it available as an active oxidation catalyst by combustion of the fuel. Preferably, the platinum group metal compound is added with the lubricating oil, but can be added to the fuel or through a separate injection.
Abstract translation: 催化氧化剂可以延长二氧化碳汽油发动机HC和CO排放的效果。 将铂族金属的化合物加入到发动机的气缸中，通过燃料的燃烧使其作为活性氧化催化剂得到。 优选地，铂族金属化合物加入润滑油，但可以加入到燃料中或通过单独的注入。
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公开(公告)号：US08863720B2
公开(公告)日：2014-10-21
申请号：US13664778
申请日：2012-10-31
Applicant: Federal-Mogul Corporation
Inventor： Warran Boyd Lineton
CPC classification number: F02F3/14 , B05D5/00 , C25D7/00 , F02B23/0603 , F02B2023/0612 , F02F3/12 , F05C2201/0403 , F05C2201/0418 , F05C2201/0421 , F05C2201/0424 , F05C2201/0427 , Y02T10/125
Abstract: A piston for a diesel internal combustion engine including a crown portion at least partially formed of steel and having a combustion surface with a combustion bowl formed therein is provided. The combustion bowl presents a combustion bowl rim area, and a coating including at least one of a noble metal and a refractory metal is applied to substantially only the combustion bowl rim area. The coating is preferably applied in the areas of the combustion bowl rim area that are in line with the sprays of diesel fuel when the piston is in a top dead center position during operation of the engine.
Abstract translation: 一种柴油机内燃机的活塞，其特征在于，具备至少部分由钢制成的具有形成有燃烧碗的燃烧面的冠部的冠部。 燃烧碗具有燃烧碗边缘区域，并且包括贵金属和难熔金属中的至少一种的涂层仅基本上施加于燃烧碗边缘区域。 当在发动机操作期间活塞处于上止点位置时，该涂层优选地应用于燃烧碗边缘区域与柴油燃料喷雾一致的区域中。
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Patent Agency Ranking
公开(公告)号：US5732548A
公开(公告)日：1998-03-31
申请号：US319620
申请日：1994-10-07
Applicant: Jeremy D. Peter-Hoblyn
Inventor： Jeremy D. Peter-Hoblyn
IPC: C10L1/14 , C10L1/16 , C10L1/18 , C10L1/20 , C10L1/24 , C10L1/26 , C10L1/28 , C10L1/30 , C10L10/00 , C10L10/02 , C10M159/18 , F01M3/00 , F02B1/04 , F02B47/00 , F02B51/02 , F02B75/02 , F01N3/20
CPC classification number: F02B47/00 , C10L1/143 , C10L1/1814 , C10L1/301 , C10L1/305 , C10L10/02 , C10M159/18 , F01M3/00 , F02B51/02 , C10L1/1616 , C10L1/1633 , C10L1/1641 , C10L1/1691 , C10L1/1832 , C10L1/1852 , C10L1/1883 , C10L1/1905 , C10L1/191 , C10L1/1985 , C10L1/201 , C10L1/207 , C10L1/2412 , C10L1/2633 , C10L1/28 , C10L1/306 , C10M2201/065 , C10M2227/08 , C10N2210/07 , C10N2240/105 , F02B1/04 , F02B2075/025 , F05C2201/0427 , Y02T10/121 , Y02T10/126
Abstract: The effectiveness is prolonged for catalytic oxidizers to reduce emissions of both HC and CO from two-stroke gasoline engines. A compound of a platinum group metal is added to the cylinder of the engine, to make it available as an active oxidation catalyst by combustion of the fuel. Preferably, the platinum group metal compound is added with the lubricating oil, but can be added to the fuel or through a separate injection.
Abstract translation: 催化氧化剂可以延长二氧化碳汽油发动机HC和CO排放的效果。 将铂族金属的化合物加入到发动机的气缸中，通过燃料的燃烧使其作为活性氧化催化剂得到。 优选地，铂族金属化合物加入润滑油，但可以加入到燃料中或通过单独的注入。
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公开(公告)号：US20130118438A1
公开(公告)日：2013-05-16
申请号：US13664778
申请日：2012-10-31
Applicant: Federal-Mogul Corporation
Inventor： Warran Boyd Lineton
CPC classification number: F02F3/14 , B05D5/00 , C25D7/00 , F02B23/0603 , F02B2023/0612 , F02F3/12 , F05C2201/0403 , F05C2201/0418 , F05C2201/0421 , F05C2201/0424 , F05C2201/0427 , Y02T10/125
Abstract: A piston for a diesel internal combustion engine including a crown portion at least partially formed of steel and having a combustion surface with a combustion bowl formed therein is provided. The combustion bowl presents a combustion bowl rim area, and a coating including at least one of a noble metal and a refractory metal is applied to substantially only the combustion bowl rim area. The coating is preferably applied in the areas of the combustion bowl rim area that are in line with the sprays of diesel fuel when the piston is in a top dead center position during operation of the engine.
Abstract translation: 一种柴油机内燃机的活塞，其特征在于，具备至少部分由钢制成的具有形成有燃烧碗的燃烧面的冠部的冠部。 燃烧碗具有燃烧碗边缘区域，并且包括贵金属和难熔金属中的至少一种的涂层仅基本上施加于燃烧碗边缘区域。 当在发动机操作期间活塞处于上止点位置时，该涂层优选地应用于燃烧碗边缘区域与柴油燃料喷雾一致的区域中。
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公开(公告)号：US6003303A
公开(公告)日：1999-12-21
申请号：US514978
申请日：1995-08-14
Applicant: Jeremy D. Peter-Hoblyn , James M. Valentine , Barry N. Sprague , W. Robert Epperly
Inventor： Jeremy D. Peter-Hoblyn , James M. Valentine , Barry N. Sprague , W. Robert Epperly
IPC: B01D53/94 , C10L1/10 , C10L1/12 , C10L1/14 , C10L1/16 , C10L1/18 , C10L1/22 , C10L1/24 , C10L1/26 , C10L1/30 , C10L10/02 , C10L10/06 , F01N3/029 , F01N3/037 , F01N3/20 , F02B3/06 , F02B51/02 , F02D41/00 , F02M25/00 , F02M25/07 , F01N3/00
CPC classification number: F02M25/00 , B01D53/944 , C10L1/10 , C10L10/02 , C10L10/06 , F01N3/029 , F01N3/037 , F01N3/206 , F02B51/02 , F02M26/15 , B01D2255/1021 , B01D2255/2065 , B01D2255/20761 , B01D2255/906 , C10L1/1208 , C10L1/1225 , C10L1/1233 , C10L1/1241 , C10L1/125 , C10L1/1266 , C10L1/1275 , C10L1/14 , C10L1/1608 , C10L1/1616 , C10L1/1691 , C10L1/1814 , C10L1/1824 , C10L1/1828 , C10L1/1852 , C10L1/1855 , C10L1/1857 , C10L1/188 , C10L1/1881 , C10L1/1883 , C10L1/1886 , C10L1/1888 , C10L1/191 , C10L1/198 , C10L1/1985 , C10L1/2222 , C10L1/2225 , C10L1/2227 , C10L1/224 , C10L1/2286 , C10L1/23 , C10L1/231 , C10L1/232 , C10L1/238 , C10L1/2437 , C10L1/26 , C10L1/2608 , C10L1/301 , C10L1/305 , F01N2430/04 , F01N2610/02 , F01N3/023 , F01N3/035 , F02B3/06 , F02D41/0047 , F05C2201/0427 , Y02T10/126
Abstract: Emissions of pollutants from diesel engines are reduced by a combination of mechanical devices and fuel additives. In one series of embodiments, diesel emissions of NO.sub.x and particulates are reduced, simultaneously with gaseous hydrocarbons and carbon monoxide, by the combined use of exhaust gas recirculation or engine timing modification, with a particulate trap and a platinum group metal catalyst composition. In another embodiment, a multi-metal catalyst composition, comprising a combination of a platinum metal catalyst composition and at least one auxiliary catalyst metal composition, especially cerium or copper, is employed to provide catalyst metal to the exhaust system including a diesel trap to lower the balance point of the particulate trap (the temperature at which the rate of trap loading equals the rate of regeneration) while also lowering the emissions of carbon monoxide and unburned hydrocarbons. Data for platinum, copper and cerium catalysts establishes effective amounts. Tests also show selective maintenance of low oxidation of SO.sub.2 to SO.sub.3.
Abstract translation: 通过机械装置和燃料添加剂的组合来减少来自柴油发动机的污染物的排放。 在一系列实施例中，通过与颗粒捕集器和铂族金属催化剂组合物的组合使用废气再循环或发动机正时修改，与气态烃和一氧化碳同时地减少NOx和颗粒的柴油排放。 在另一个实施方案中，使用包含铂金属催化剂组合物和至少一种辅助催化剂金属组合物，特别是铈或铜的组合的多金属催化剂组合物，以向排气系统提供催化剂金属，该排气系统包括柴油收集器以降低 颗粒捕集器的平衡点（捕集装载速率等于再生速率的温度）同时也降低一氧化碳和未燃碳氢化合物的排放。 铂，铜和铈催化剂的数据建立有效量。 测试还显示选择性维持SO2的低氧化为SO3。
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7.发明授权Method for reducing emissions of NO.sub.x and particulates from a diesel engine 失效减少柴油发动机NOx和颗粒物排放的方法
公开(公告)号：US6051040A
公开(公告)日：2000-04-18
申请号：US978687
申请日：1997-11-26
Applicant: Jeremy D. Peter-Hoblyn
Inventor： Jeremy D. Peter-Hoblyn
IPC: B01D53/94 , C10L1/10 , C10L1/12 , C10L1/14 , C10L1/16 , C10L1/18 , C10L1/22 , C10L1/24 , C10L1/30 , C10L10/02 , C10L10/06 , F01N3/023 , F01N3/035 , F01N3/037 , F01N3/20 , F02B3/06 , F02B51/02 , F02D19/12 , F02D41/00
CPC classification number: F02D19/12 , B01D53/9418 , B01D53/944 , B01D53/9477 , C10L1/10 , C10L10/02 , C10L10/06 , F01N3/023 , F01N3/029 , F01N3/035 , F01N3/206 , F01N3/2066 , F02B51/02 , B01D2251/206 , B01D2255/1021 , B01D2255/202 , B01D2255/2065 , B01D2255/2073 , B01D2255/20738 , B01D2255/20761 , B01D2258/012 , C10L1/1233 , C10L1/1241 , C10L1/125 , C10L1/1266 , C10L1/14 , C10L1/1608 , C10L1/1616 , C10L1/1814 , C10L1/1824 , C10L1/1828 , C10L1/1852 , C10L1/1855 , C10L1/1857 , C10L1/188 , C10L1/1881 , C10L1/1886 , C10L1/1888 , C10L1/189 , C10L1/2227 , C10L1/224 , C10L1/2286 , C10L1/231 , C10L1/2437 , C10L1/30 , C10L1/301 , C10L1/305 , F01N2240/20 , F01N2430/04 , F01N2610/01 , F01N2610/02 , F02B3/06 , F02D41/0047 , F05C2201/0427 , Y02T10/126 , Y02T10/24
Abstract: A method improves the operation of a diesel engine through the use of a fuel additive, a diesel particulate trap and a NO.sub.x -reducing catalyst. The operation of the NO.sub.x -reducing catalyst is enhanced by the introduction of urea or like compound upstream of the catalyst at temperatures effective for non-catalytic NO.sub.x reduction and the generation of ammonia. The additive comprises fuel-soluble compositions of platinum group metal in effective amounts to lower the emissions of unburned hydrocarbons and carbon monoxide from the trap. The catalytic activity provided to the exhaust system by the fuel additive is selective and preferably reduces the oxidation of SO.sub.2 to SO.sub.3. The platinum group metal compositions are preferably added in amounts effective to provide concentrations of the metal in the fuel of less than 1 part per million (ppm). Lithium and/or sodium compositions can be used in amounts effective to reduce the trap regeneration temperature, e.g. concentrations to provide about 1 to 100 ppm lithium metal, and/or 1 to 30 ppm sodium metal.
Abstract translation: 一种方法通过使用燃料添加剂，柴油颗粒捕集器和NOx还原催化剂来改善柴油发动机的操作。 通过在有效用于非催化NOx还原和产生氨的温度下，在催化剂上游引入尿素等化合物来提高NOx还原催化剂的操作。 添加剂包含有效量的铂族金属的燃料可溶性组合物，以降低来自捕集器的未燃碳氢化合物和一氧化碳的排放。 通过燃料添加剂提供给排气系统的催化活性是选择性的，并且优选地将SO 2氧化成SO 3。 铂族金属组合物优选以有效提供小于1ppm（ppm）的燃料中的金属浓度的量加入。 锂和/或钠组合物可以以有效降低陷阱再生温度的量使用，例如 浓度提供约1至100ppm的锂金属和/或1至30ppm的金属钠。
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公开(公告)号：US2926649A
公开(公告)日：1960-03-01
申请号：US46140754
申请日：1954-10-11
Applicant: BYRON HICKS J
Inventor： BYRON HICKS J
CPC classification number: F02B77/04 , F02B51/02 , F02B77/02 , F05C2201/0421 , F05C2201/0424 , F05C2201/0427 , F05C2201/0466 , Y02T10/126
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