Abstract:
PROBLEM TO BE SOLVED: To provide a process for catalytically hydrogenating a hydrocarbon stream by which the fewest possible undesired secondary components such as oligomers and/or polymers and/or cracking products are formed. SOLUTION: The hydrocarbon stream is catalytically hydrogenated by adding a basic compound to the starting material stream without using a different solvent from the hydrocarbon stream to be hydrogenated. Thereby, the formation of undesired secondary components on the catalyst is effectively prevented. COPYRIGHT: (C)2003,JPO
Abstract:
The invention relates to a method for the dealkylation of alkyl-substituted aromatic hydrocarbons, such as for example toluol or other monoalkyl- or polyalkyl-substituted benzols or higher aromatics, to obtain benzol with the aid of water vapour in the presence of a catalyst that contains a support comprising zirconium oxide and rhodium. The invention also relates to the aforementioned catalyst.
Abstract:
The invention relates to a method for catalytic hydrogenation of a carbonyl compound or a mixture of two or more carbonyl compounds in the presence of catalyst tablets which contain an inorganic support containing TiO>2 /g.
Abstract:
The invention relates to a method for catalytically hydrating a poly- or monomethylol alkanal of the general formula (I), wherein R is the same or different and may represent a substituted or unsubstituted aliphatic hydrocarbon with 6 to 22 carbon atoms, an aryl or arylalkyl group with 6 to 22 carbon atoms or a methylol group, in the presence of a copper-containing catalyst. The inventive method is characterized in that the poly- or monomethylol alkanal containing batch to be hydrated has a total content of up to 5 ppm of metal ions of the groups 3 to 14 of the periodic system.
Abstract:
The invention relates to a method, whereby the colour number of polyhydric alcohols, in particular, trihydroxymethylpropane, can be significantly improved by hydrogenation. The method is characterized in that an alcohol is used in the hydrogenation, which has been previously purified by distillation. The conventional catalysts for hydrogenation are used as catalysts, preferably copper, nickel, palladium or ruthenium.
Abstract:
The invention relates to a method for the aromatisation of non-aromatic hydrocarbons with 6 or more carbon atoms in the presence of water vapour and a catalyst that contains a support comprising zirconium oxide, in addition to tin and platinum in a ratio of at least 1. The invention also relates to the aforementioned catalyst.
Abstract:
The invention relates to a method for dealkylating alkyl-substituted aromatic hydrocarbons with the aid of water vapour in the presence of a dealkylation catalyst, by means of a gas containing oxygen.
Abstract:
The invention relates to a method for cleaning crude terephthalic acid by means of catalytic, hydrogenating aftertreatment using a catalyst material containing at least one hydrogenation metal applied to a carbon carrier consisting of carbon fibres. The invention also relates to a catalyst consisting of the at least one catalyst material containing the at least one hydrogenation metal applied to the carbon fibres, the BET surface of the carbon carrier being
Abstract:
The present invention provides a process for preparing 1,6-hexanediol by hydrogenating dialkyl adipates, alkyl 6-hydroxycaproates, 1,4-cyclohexanedione and 4-hydroxycyclohexan-1-one as ester mixtures comprising impurities, by a) freeing resulting the esterification mixture of excess alcohol and low boilers in a first distillation stage (alcohol removal), b) carrying out a separation of the bottom product in a second distillation stage into an ester fraction substantially free of 1,4-cyclohexanediols and a fraction comprising at least the majority of the 1,4-cyclohexanediols, c) catalytically hydrogenating the ester fraction substantially free of 1,4-cyclohexanediols (ester hydrogenation) and d) in a purifying distillation stage, obtaining 1,6-hexanediol from the hydrogenation effluent in a manner known per se, which comprises selectively hydrogenating the ester mixture before stage a) and/or before stage b) (purifying hydrogenation).
Abstract:
Un proceso para la hidrogenación catalítica de un polimetiloalcanal o un monometiloalcanal de la fórmula (I) En donde R puede ser idéntico o diferente y cada uno es hidrocarburo alifático sustituido o no sustituido que tiene 1 a 22 átomos de carbono, un grupo aril o ariloalquilo que tiene de 6 a 22 pares de átomos de carbono o un grupo metilol, en la presencia de un catalizador que contiene cobre, en donde la alimentación de hidrogenación que comprende el polimetiloalcanal o monometiloalcanal tiene un contenido total de iones de metal de grupos 3 a 14 de la tabla periódica de elementos de hasta 5 ppm.