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    Production of beta-alkoxynitrile or gamma-alkoxyamine
    2.
    发明专利
    Production of beta-alkoxynitrile or gamma-alkoxyamine 审中-公开
    β-烷氧基硅烷或γ-羟基烷基胺的生产

    公开(公告)号：JPH11279135A

    公开(公告)日：1999-10-12

    申请号：JP1752499

    申请日：1999-01-26

    Applicant: Basf Ag ,  ビーエーエスエフ アクチェンゲゼルシャフト

    Inventor： FRIEDRICH WOLFGANG ,  KNEUPER HEINZ-JOSEF DR ,  ELLER KARSTEN DR ,  HENNE ANDREAS DR ,  LEBKUECHER ROLF DR

    IPC: B01J31/02 ,  C07B61/00 ,  C07C213/02 ,  C07C217/08 ,  C07C217/48 ,  C07C253/30 ,  C07C255/13 ,  C07C255/37

    CPC classification number: C07C213/02 ,  C07C253/30 ,  C07C217/08 ,  C07C217/48 ,  C07C255/13 ,  C07C255/37

    Abstract: PROBLEM TO BE SOLVED: To obtain the subject compound by reaction between an α,β-unsaturated nitrile and an alcohol using a specific diazabicycloalkene as basic catalyst without the need of any prior separation or neutralization of the catalyst for the addition reaction.
    SOLUTION: This compound is obtained by reaction between an α,β-unsaturated nitrile (e.g. acrylonitrile) and a monohydric, dihydric or trihydric alcohol (e.g. methanol, ethanol, 2-ethylhexanol, 2-methoxyethanol, benzyl alcohol) at -20 to 200°C using a diazabicycloalkene of the formula (H may be substituted with a 1-20C alkyl, 6-20C aryl or 7-20C arylalkyl; (n) and (m) are each 1-6) as basic catalyst {e.g. 1,5-diazabicyclo[4.3.0]nonene-5(DBN), 1,8- diazabicyclo[5.4.0]undecene-7(DBU)}; wherein the amount of the catalyst to be used is pref. 0.05-5 wt.% based on the alcohol.
    COPYRIGHT: (C)1999,JPO

    Abstract translation: 要解决的问题：通过使用特定的二氮杂双环链烯烃作为碱性催化剂，通过α，β-不饱和腈和醇之间的反应获得目标化合物，而不需要任何预先分离或中和加成反应的催化剂。 溶液：该化合物通过α-β-不饱和腈（如丙烯腈）与一元二元或三元醇（如甲醇，乙醇，2-乙基己醇，2-甲氧基乙醇，苄醇）在-20〜200 （H可以被1-20C烷基，6-20C芳基或7-20C芳基烷基取代;（n）和（m）各自为1-6）作为碱性催化剂，例如 1,5-二氮杂双环[4.3.0]壬烯-5（DBN），1,8-二氮杂双环[5.4.0]十一碳烯-7（DBU）}; 其中所用的催化剂的量是优选的。 基于醇为0.05-5重量％。

    PRODUCTION OF ALKYLAMINE
    3.
    发明专利
    PRODUCTION OF ALKYLAMINE 失效

    公开(公告)号：JPH11100374A

    公开(公告)日：1999-04-13

    申请号：JP20740698

    申请日：1998-07-23

    Applicant: BASF AG

    Inventor： KNEUPER HEINZ-JOSEF DR ,  LEBKUECHER ROLF DR ,  NEUHAUSER HORST DR ,  HENNE ANDREAS DR ,  BECKER RAINER

    IPC: C07D295/02 ,  B01J23/75 ,  C07B37/04 ,  C07B61/00 ,  C07C209/26 ,  C07D295/023

    Abstract: PROBLEM TO BE SOLVED: To economically and continuously obtain an alkylamine in a simplified apparatus by preheating only an amine stream or only an aldehyde stream fed by separated stream during feed and reacting the amine with the aldehyde on a fixed bed catalyst in a reactor. SOLUTION: Only an aldehyde stream [e.g. formaldehyde aqueous solution having 50-90 wt.%, preferably 65-75 wt.% water content based on total weight of the solution] or only an amine stream (preferably 30-80 wt.% piperazine aqueous solution) fed by separated stream is preheated during a feed (a molar ratio of piperazine to formaldehyde is 1:1.0 to 1:5, preferably 1:2 to 1:2.7) is and the aldehyde is reacted with the amine in a reactor in which these compounds are mixed in a catalyst bed on a fixed bed catalyst in the presence of an isolated hydrogen to continuously provide the objective alkylamine.

    N-ALKYLATION OF AMINE
    4.
    发明专利
    N-ALKYLATION OF AMINE 失效

    公开(公告)号：JPH10279569A

    公开(公告)日：1998-10-20

    申请号：JP5196498

    申请日：1998-03-04

    Applicant: BASF AG

    Inventor： SIMON JOACHIM DIPL CHEM DR ,  BECKER RAINER ,  LEBKUECHER ROLF DR ,  NEUHAUSER HORST DR

    IPC: C07D295/02 ,  B01J23/72 ,  B01J23/78 ,  B01J23/86 ,  C07B61/00 ,  C07C209/16 ,  C07C211/03 ,  C07D295/023

    Abstract: PROBLEM TO BE SOLVED: To industrially and economically advantageously N-alkylate an amine by carrying out the reaction in the presence of a specific catalyst. SOLUTION: When (A) an alcohol (preferably an α,ω-diol) is reacted with (B) an alkylamine or a dialkylamine (preferably monomethylamine, etc.), the reaction is carried out in the presence of (C) a catalyst prepared by including 0-2 wt.% BaO, Cr2 O3 and/or ZnO in copper and magnesium silicate as a base regardless thereof for each time as the catalyst. The component C preferably contains 30-60 wt.% CuO and has preferably at least 100 m /g BET specific surface area. The reaction is preferably conducted in the liquid phase under 50-300 bars pressure.

    6.
    发明专利
    未知

    公开(公告)号：AT221903T

    公开(公告)日：2002-08-15

    申请号：AT95116222

    申请日：1995-10-14

    Applicant: BASF AG

    Inventor： HORN PETER DR ,  JUNG LUDWIG ,  LARBIG HARALD DR ,  LEBKUECHER ROLF DR ,  LEHR GERHARD

    IPC: C08G18/50 ,  C08G65/26 ,  C08G101/00

    Abstract: The prodn. of polyurethane (PU) foam comprises reacting (a) polyisocyanate(s); with (b) high-mol. wt. polyol(s) with at least two reactive H atoms, comprising (B1) polyoxyalkylene-polyol(s) with an OH no. of 30-500, obtd. by alkoxylating N,N'-bis(3-aminopropyl)-ethylenediamine, tripropylene-tetramine and/or tetrapropylene-pentamine with alkene oxide(s); and opt. (c) low-mol wt. chain extenders and/or crosslinkers; in the presence of (d) blowing agents. Also claimed are polyols (b1) obtd. as above.

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