公开(公告)号：WO0107392A9

公开(公告)日：2003-04-03

申请号：PCT/EP0007199

申请日：2000-07-26

Applicant: BASF AG ,  AUER HEINZ ,  DAHLHAUS JUERGEN ,  FISCHER KARL ,  HAMMER HANS ,  KELLENBENZ JOCHEN ,  SCHULZ MICHAEL ,  THIEL JOACHIM ,  VICARI MAXIMILIAN

Inventor： AUER HEINZ ,  DAHLHAUS JUERGEN ,  FISCHER KARL ,  HAMMER HANS ,  KELLENBENZ JOCHEN ,  SCHULZ MICHAEL ,  THIEL JOACHIM ,  VICARI MAXIMILIAN

IPC: B01D3/00 ,  B01J3/00 ,  B01J3/02 ,  B01J19/00 ,  C07B61/00 ,  C07C29/80 ,  C07C31/04 ,  C07C67/36 ,  C07C69/06

CPC classification number: C07C67/36 ,  C07C69/06

Abstract: The invention relates to a method of producing methyl formiate by reacting excess methanol with carbon monoxide under increased pressure and increased temperature in the presence of an alkalimethylate or alkaline earth methylate as the catalyst in a pressure-proof reactor. The inventive method uses at least two reactor elements, preferably countercurrent reactors, at a temperature of approximately 100 DEG C and a pressure of approximately 100 bar in combination with a solid-matter free desalination of the reactor product. The inventive method provides a means for producing methyl formiate of any quality desired and with an excellent production capacity in a very economical and complication-free manner. The invention further relates to a method of solid-matter free desalination and to devices for carrying out the inventive method.

Abstract translation: 公开了一种用于由过量的甲醇与下在碱金属或碱土金属甲醇盐如在耐压反应器催化剂的存在超大气压力和升高的温度下一氧化碳反应，制备甲酸甲酯的方法，其中操作通过使用至少两个，优选在逆流反应器元件 温度至100℃，并在组合100巴的以任何所需质量非常经济的，无故障的主要生产甲酸甲酯和具有很好的生产能力成为可能的反应器的无固体的脱盐的压力。 此外，描述了用于执行该方法的无固体的脱盐和装置的过程。

公开(公告)号：WO02053520A2

公开(公告)日：2002-07-11

申请号：PCT/EP0200054

申请日：2002-01-05

Applicant: BASF AG ,  VANOPPEN DOMINIC ,  SCHWAB EKKEHARD ,  BASSET JEAN-MARIE ,  THIVOLLE-CAZAT JEAN ,  TAOUFIK MOSTAPHA ,  SCHULZ MICHAEL ,  HOEHN ARTHUR

Inventor： VANOPPEN DOMINIC ,  SCHWAB EKKEHARD ,  BASSET JEAN-MARIE ,  THIVOLLE-CAZAT JEAN ,  TAOUFIK MOSTAPHA ,  SCHULZ MICHAEL ,  HOEHN ARTHUR

IPC: C07C6/08 ,  C07C6/10

CPC classification number: C07C6/10 ,  C07C6/08 ,  C07C2531/12

Abstract: The invention relates to a method for producing hydrocarbons having a modified carbon skeleton by reacting aliphatic hydrocarbons a) with themselves, b) with another aliphatic hydrocarbon or c) with aromatic alkyl substituted hydrocarbons, in the presence of a metal organic catalyst or the hybrid thereof, at a temperature of between 20 - 400 DEG C and a pressure of between 0.2 - 100 bars, wherein the reaction takes place in the presence of hydrogen.

Abstract translation: 通过脂族烃反应制备具有改性碳骨架的烃的方法：a）与其本身; b）与另一种脂族烃或c）与芳族烷基取代的烃在有机金属催化剂或其杂化物存在下，在20-400℃的温度和0.2-100巴的压力下，通过在氢存在下 执行。

公开(公告)号：WO0014055A3

公开(公告)日：2002-10-03

申请号：PCT/EP9906463

申请日：1999-09-02

Applicant: BASF AG ,  SLANY MICHAEL ,  SCHAEFER MARTIN ,  SCHULZ MICHAEL

Inventor： SLANY MICHAEL ,  SCHAEFER MARTIN ,  SCHULZ MICHAEL

IPC: B01J31/24 ,  C07B61/00 ,  C07C253/30 ,  C07C255/19 ,  C07F9/6568 ,  C07F15/00 ,  B01J31/28 ,  C07F9/50

CPC classification number: C07C253/30 ,  C07F15/0053 ,  C07C255/19

Abstract: The invention relates to a method for producing cyanovaleric acid or esters thereof by reacting 2-, 3- or 4-pentene nitrile or mixtures thereof with carbon monoxide and with a compound containing hydroxyl groups in the presence of a catalyst system. Said catalyst system comprises: (i) a palladium (II) compound, (ii) a bidentate diphosphine ligand and (iii) an anion source. The invention also relates to novel catalyst systems with diphosphine ligands of the bis(phosphinomethyl)amine type.

Abstract translation: 公开了用于由2-，3-或4-戊烯腈或与一氧化碳及其混合物中和在催化剂系统，包括存在一个含羟基的化合物反应来制备氰基戊酸或酯的方法：（ⅰ）钯（II） 化合物，（ii）双齿二膦配体，和（iii）阴离子源。 描述也与双（膦）胺型的二膦配体的新型催化剂体系。

公开(公告)号：ES2261484T3

公开(公告)日：2006-11-16

申请号：ES01978386

申请日：2001-09-25

Applicant: BASF AG

Inventor： SCHAFER MARTIN ,  SLANY MICHAEL ,  ZELLER EDGAR ,  ROPER MICHAEL ,  SCHULZ MICHAEL ,  GRIMM GUNTHER

IPC: B01J31/24 ,  B01J31/16 ,  B01J31/28 ,  B01J35/00 ,  C07B61/00 ,  C07C51/14 ,  C07C53/122 ,  C07C67/38

Abstract: Sistema catalizador para el carbonilado de compuestos con insaturación olefínica o acetilénica con monóxido de carbono y un compuesto nucleófilo, que contiene (a) paladio; (b) una fosfina; y (c) una polietilenimina acilada disuelta de manera homogénea o al menos en distribución coloidal en la mezcla de reacción, que presenta unidades de la fórmula general (I) o isómeros ramificados de las mismas (Ver fórmula) en la que la suma de m+n asciende al menos a 10, y R, independientemente entre sí, significa hidrógeno, restos alquilo, cicloalquilo, arilo, aralquilo, acilo con hasta 30 átomos de carbono o restos hidroxialquil(poli)oxialquileno con hasta 500 unidades alquilenoxi, presentando la polietilenimina (I) los siguientes elementos estructurales (II) o isómeros ramificados de los mismos (Ver fórmulas) en las que R¿ significa, independientemente entre sí, alquilo con 1 a 29 átomos de carbono, y cuyo grado de amidación asciende a un 1 hasta casi un 100%, referido a los grupos amino amidables.

公开(公告)号：DE50109455D1

公开(公告)日：2006-05-18

申请号：DE50109455

申请日：2001-09-25

Applicant: BASF AG

Inventor： SCHAEFER MARTIN ,  SLANY MICHAEL ,  ZELLER EDGAR ,  ROEPER MICHAEL ,  SCHULZ MICHAEL ,  GRIMM GUENTHER

IPC: B01J31/16 ,  B01J31/24 ,  B01J31/28 ,  B01J35/00 ,  C07B61/00 ,  C07C51/14 ,  C07C53/122 ,  C07C67/38

Abstract: The invention relates to a catalyst system for carbonylating olefinically or acetylenically unsaturated compounds with carbon monoxide and a nucleophile compound, containing (a) palladium; (b) a phosphine and (c) a polymer containing nitrogen which is soluble in the reaction mixture, with the exception of polyvinyl polymers with aromatic radicals containing nitrogen on the polymer chain. The invention also relates to a method for carbonylation in the presence of one such catalyst system.

公开(公告)号：DE59910915D1

公开(公告)日：2004-11-25

申请号：DE59910915

申请日：1999-12-23

Applicant: BASF AG

Inventor： DAHLHAUS JUERGEN ,  KARL JOERN ,  SCHULZ MICHAEL ,  WENZEL ANNE ,  HARDER WOLFGANG ,  HOEHN ARTHUR

IPC: B01J23/04 ,  B01J31/40 ,  C07B61/00 ,  C07C231/10 ,  C07C233/03

Abstract: In the process for preparing formamide by reaction of ammonia and carbon monoxide in the presence of at least one catalyst, sodium diformylamide is used as catalyst. If sodium methoxide is used as further active component, sodium diformylamide can be formed from this. In this process, sodium diformylamide is a particularly active and stable catalyst which can be recycled.

公开(公告)号：DE59909056D1

公开(公告)日：2004-05-06

申请号：DE59909056

申请日：1999-12-21

Applicant: BASF AG

Inventor： MAAS HEIKO ,  ROEPER MICHAEL ,  WALTER MARC ,  SCHULZ RALF ,  TROPSCH JUERGEN ,  JAEGER HANS-ULRICH ,  SCHWAB PETER ,  SCHULZ MICHAEL

IPC: C07B61/00 ,  C07C2/10 ,  C07C6/04 ,  C07C11/02 ,  C07C11/107 ,  C07C29/16 ,  C07C31/125 ,  C07C41/03 ,  C07C43/13 ,  C07C45/50 ,  C07F9/09 ,  C07F9/11

Abstract: The invention describes a process for the preparation of novel surfactant alcohols and surfactant alcohol ethers by derivatization of olefins having from about 10 to 20 carbon atoms or of mixtures of such olefins to give alkanols, and optional subsequent alkoxylation, which comprises subjecting a C 4 -olefin mixture to metathesis, dimerizing the resulting olefins, and then derivatizing them to give surfactant alcohols, and optionally alkoxylating said alcohols. The olefin mixture obtained in the dimerization has a high proportion of branched components and less than 10% by weight of compounds which contain a vinylidene group. invention further describes the use of the surfactant alcohols and surfactant alcohol ethers to give surfactants by glycosylation or polyglycosylation, sulfation or phosphation.

公开(公告)号：AT263131T

公开(公告)日：2004-04-15

申请号：AT99962263

申请日：1999-12-21

Applicant: BASF AG

Inventor： MAAS HEIKO ,  ROEPER MICHAEL ,  WALTER MARC ,  SCHULZ RALF ,  TROPSCH JUERGEN ,  JAEGER HANS-ULRICH ,  SCHWAB PETER ,  SCHULZ MICHAEL

IPC: C07B61/00 ,  C07C2/10 ,  C07C6/04 ,  C07C11/02 ,  C07C11/107 ,  C07C29/16 ,  C07C31/125 ,  C07C41/03 ,  C07C43/13 ,  C07C45/50 ,  C07F9/09 ,  C07F9/11

Abstract: The invention describes a process for the preparation of novel surfactant alcohols and surfactant alcohol ethers by derivatization of olefins having from about 10 to 20 carbon atoms or of mixtures of such olefins to give alkanols, and optional subsequent alkoxylation, which comprises subjecting a C 4 -olefin mixture to metathesis, dimerizing the resulting olefins, and then derivatizing them to give surfactant alcohols, and optionally alkoxylating said alcohols. The olefin mixture obtained in the dimerization has a high proportion of branched components and less than 10% by weight of compounds which contain a vinylidene group. invention further describes the use of the surfactant alcohols and surfactant alcohol ethers to give surfactants by glycosylation or polyglycosylation, sulfation or phosphation.

公开(公告)号：NO20033029D0

公开(公告)日：2003-07-02

申请号：NO20033029

申请日：2003-07-02

Applicant: BASF AG

Inventor： VANOPPEN DOMINIC ,  SCHWAB EKKEHARD ,  BASSET JEAN-MARIE ,  THIVOLLE-CAZAT JEAN ,  TAOUFIK MOSTAPHA ,  SCHULZ MICHAEL ,  HOEHN ARTHUR

IPC: C07C6/08 ,  C07C6/10

公开(公告)号：DE59903982D1

公开(公告)日：2003-02-13

申请号：DE59903982

申请日：1999-09-02

Applicant: BASF AG

Inventor： SLANY MICHAEL ,  SCHAEFER MARTIN ,  SCHULZ MICHAEL

IPC: B01J31/24 ,  C07B61/00 ,  C07C253/30 ,  C07C255/19 ,  C07F9/6568 ,  C07F15/00

Abstract: The process comprises reacting 2-, 3- or 4-pentenenitrile or mixtures thereof with carbon monoxide and a hydroxyl compound in the presence of a catalyst system comprising (i) a palladium(II) compound, (ii) a bidentate diphosphine ligand and (iii) an anion source. Novel catalyst systems containing diphosphine ligands of the bis(phosphinomethyl)amine type are also described.