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公开(公告)号：US3872134A
公开(公告)日：1975-03-18
申请号：US27067372
申请日：1972-07-11
Applicant: BASF AG
Inventor： WISTUBA HERMANN , SPRAGUE MICHAEL JOLYON , ENGELBACH HEINZ , ARMBRUST HERBERT , STURM HANS-JUERGEN
CPC classification number: C07C46/02 , B01J23/22 , C07C51/313 , C07C50/18 , C07C63/16
Abstract: Production of anthraquinone by catalytic oxidation of indans with oxygen in the presence of a vanadium (V) compound with one or more than one compound of thallium and antimony. Anthraquinone which can be prepared by the process according to this invention is a valuable starting material for the production of dyes and pesticides.
Abstract translation: 在钒（V）化合物与一种或多于一种铊和锑化合物的存在下，通过用氧催化氧化茚满来生产蒽醌。 可以通过根据本发明的方法制备的蒽醌是用于生产染料和农药的有价值的起始材料。
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公开(公告)号：WO0248128A3
公开(公告)日：2002-08-15
申请号：PCT/EP0114394
申请日：2001-12-07
Applicant: BASF AG , FISCHER ROLF-HARTMUTH , STEIN FRANK , PINKOS ROLF , HESSE MICHAEL , SPRAGUE MICHAEL JOLYON , ROESCH MARKUS , BORCHERT HOLGER , SCHLITTER STEPHAN , RAHN RALF-THOMAS , WECK ALEXANDER
Inventor： FISCHER ROLF-HARTMUTH , STEIN FRANK , PINKOS ROLF , HESSE MICHAEL , SPRAGUE MICHAEL JOLYON , ROESCH MARKUS , BORCHERT HOLGER , SCHLITTER STEPHAN , RAHN RALF-THOMAS , WECK ALEXANDER
IPC: B01J23/72 , B01J23/80 , C07D307/08 , C07C27/06
CPC classification number: B01J23/72 , B01J23/80 , C07D307/08
Abstract: The invention relates to a method for the production of optionally alkyl-substituted THF. The above is obtained by catalytic hydrogenation of C4-dicarboxylic acids and/or derivatives thereof, in the gas phase, using a catalyst containing 20 wt. %, preferably >30 wt %, in particular 35 to 90 wt. % of an oxidic support with acidic centres, whereby the method is carried out with a hot spot temperature of 240 to 280 DEG C and a catalytic loading of 0.01 to 1.0, preferably 0.02 to 1, in particular 0.05 to 0.5 kg reactant/l catalyst.hour.
Abstract translation: 本发明描述了任选烷基取代的THF的方法。 这是通过在C4二羧酸和/或它们的衍生物的气相催化加氢用催化剂，其包含<80重量％，优选<70重量％获得的（重量），特别是10至65重量％的CuO和> 20的 .-％，优选> 30重量％，特别是35至90重量具有在240热点Temoeratur至280℃的酸中心，与该过程中的氧化性载体的％，和0.01 Katalystorbelastungen 至1.0，优选0.02至1，特别是0.05至0.5千克原料/升Katalysator.Stunde。
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公开(公告)号：DE10111198A1
公开(公告)日：2002-09-19
申请号：DE10111198
申请日：2001-03-08
Applicant: BASF AG , XCELLSIS GMBH
Inventor： HOELZLE MARKUS , SPRAGUE MICHAEL JOLYON , HARTH KLAUS , SCHUESLER MARTIN , KARL MARTIN , BONEBERG STEFAN
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公开(公告)号：ES2231253T3
公开(公告)日：2005-05-16
申请号：ES00960507
申请日：2000-08-22
Applicant: BASF AG
Inventor： HUBER SYLVIA , SPRAGUE MICHAEL JOLYON , BREITSCHEIDEL BORIS , WULFF-DORING JOACHIM , HESSE MICHAEL , PINKOS ROLF
IPC: B01J23/80 , C07B61/00 , C07C29/149 , C07C31/04 , C07C31/20
Abstract: Procedimiento para el hidrogenado de un compuesto orgánico que presenta al menos un grupo carbonilo, en el que se pone en contacto el compuesto orgánico, en presencia de hidrógeno, con un cuerpo moldeado que es obtenible según un procedimiento en el que (i) se pone a disposición un material oxídico desecado y calcinado, que presenta material soporte y componente activo, que comprende óxido de cobre, óxido de cinc y óxido de aluminio, (ii) se añade al material oxídico polvo metálico pulverulento o cemento pulverulento, o una mezcla de los mismos, empleándose polvo de cobre y polvo de cemento con una distribución de tamaños de grano en la que al menos un 45 % de partículas de cobre o cemento poseen tamaños de grano en el intervalo de 10 a 100 m, y (iii) se moldea la mezcla resultante de (ii) para dar un cuerpo moldeado.
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公开(公告)号：ES2227309T3
公开(公告)日：2005-04-01
申请号：ES01985854
申请日：2001-12-07
Applicant: BASF AG
Inventor： FISCHER ROLF-HARTMUTH , STEIN FRANK , PINKOS ROLF , HESSE MICHAEL , SPRAGUE MICHAEL JOLYON , RISCH MARKUS
IPC: B01J23/72 , B01J23/80 , C07C27/06 , C07D307/08
Abstract: Procedimiento para la obtención de THF, en caso dado alquilsubstituido, mediante hidrogenado catalítico en la fase gaseosa de ácidos dicarboxílicos con 4 átomos de carbono y/o sus derivados, con un catalizador que contiene 20 % en peso, preferentemente > 30 % en peso, en especial un 35 a un 90 % en peso de un soporte oxídico con centros ácidos, llevándose a cabo el procedimiento a una temperatura Hot- Spot de 240 a 310ºC, preferentemente 240 a 280ºC, y cargas de catalizador de 0, 01 a 1, 0, preferentemente 0, 02 a 1, en especial 0, 05 a 0, 5 kg de educto / l de catalizador * hora.
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Patent Agency Ranking
公开(公告)号：DE10111197A1
公开(公告)日：2002-09-19
申请号：DE10111197
申请日：2001-03-08
Applicant: BASF AG
Inventor： HOELZLE MARKUS , SPRAGUE MICHAEL JOLYON , HARTH KLAUS , POEPEL WOLFGANG JUERGEN
Abstract: A process for producing catalysts that contain pacified copper and zinc oxide and/or aluminum oxide, comprises: (i) Precipitating a mixture of catalyst precursors which are dissolved in a solvent or in a sludge, using precipitating agents that contain anions. (ii) The mixture is washed and dried to form a solid catalyst precursor in powder or granulate form. (iii) The precursors are calcined until the anion content is 0.1-2.5wt%. (iv) The calcined precursors are then shaped and reduced and pacified, to form the catalyst. (v) Precipitation tales place by the addition of carbonates, and in the precipitation of zinc and aluminum salts the Zn:Al ration is 3:1-1:3, and the alkali carbonate solution has a pH of 5-12 and a temperature of 20-100 degrees C. (vi) The precipitate is separated and washed to remove the alkali ions. (vii) After drying, calcining takes place at 250-800 degrees C.
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公开(公告)号：DE10061556A1
公开(公告)日：2002-06-13
申请号：DE10061556
申请日：2000-12-11
Applicant: BASF AG
Inventor： FISCHER ROLF-HARTMUTH , STEIN FRANK , PINKOS ROLF , HESSE MICHAEL , SPRAGUE MICHAEL JOLYON , ROESCH MARKUS , BORCHERT HOLGER , SCHLITTER STEPHAN , RAHN RALF-THOMAS , WECK ALEXANDER
IPC: B01J23/72 , B01J23/80 , C07C27/06 , C07D307/08
Abstract: The invention relates to a method for the production of optionally alkyl-substituted THF. The above is obtained by catalytic hydrogenation of C4-dicarboxylic acids and/or derivatives thereof, in the gas phase, using a catalyst containing 20 wt. %, preferably >30 wt %, in particular 35 to 90 wt. % of an oxidic support with acidic centres, whereby the method is carried out with a hot spot temperature of 240 to 280 DEG C and a catalytic loading of 0.01 to 1.0, preferably 0.02 to 1, in particular 0.05 to 0.5 kg reactant/l catalyst.hour.
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公开(公告)号：DE19942895A1
公开(公告)日：2001-03-15
申请号：DE19942895
申请日：1999-09-08
Applicant: BASF AG
Inventor： HUBER SYLVIA , SPRAGUE MICHAEL JOLYON , BREITSCHEIDEL BORIS , WULFF-DOERING JOACHIM , HESSE MICHAEL , PINKOS ROLF , LIANG SHELUE , KUMBERGER OTTO , WALTER MARC
IPC: B01J23/80 , C07B61/00 , C07C29/149 , C07C31/04 , C07C31/20 , C07C29/136 , C07B31/00
Abstract: The invention relates to a method for hydrogenating an organic compound which has at least one carbonyl group. According to said method, the organic compound is brought into contact with a shaped body in the presence of hydrogen, said shaped body being produced according to a method in which: (i) an oxidic material containing copper oxide, zinc oxide and aluminium oxide is prepared; (ii) powder-form metallic copper or powder-form cement or a mixture thereof is added to said oxidic material; and (iii) the mixture resulting from (ii) is moulded into a shaped body.
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公开(公告)号：DK545989D0
公开(公告)日：1989-11-02
申请号：DK545989
申请日：1989-11-02
Applicant: BASF AG
Inventor： WANJEK HERBERT , WITTE CLAUS , SPRAGUE MICHAEL JOLYON , IRGANG MATTHIAS , HOELDERICH WOLFGANG , MROSS WOLF DIETER
Abstract: Copper-containing catalysts for low-temperature conversion at temperatures of from 150 to 300 DEG C and at from 10 to 40 bar which additionally contain aluminium, and zinc, if desired in the form of the compounds or oxides, and are prepared by joint precipitation, the copper-containing catalysts containing potassium and having a BET surface area matched to the potassium content, the potassium content being set to from 0.1 to 3.0% by weight at a BET surface area of from 30 to 160 m /g, and their use for the production of hydrogen and carbon dioxide from carbon monoxide and water.
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公开(公告)号：DE3520832A1
公开(公告)日：1986-12-11
申请号：DE3520832
申请日：1985-06-11
Applicant: BASF AG
Inventor： GRUENDLER KARL-HEINZ , IRGANG MATTHIAS , NETH NORBERT , SPRAGUE MICHAEL JOLYON , ZIRKER GUENTHER
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