中科微点-全球专利检索

  1. Login
  2. Sign Up

Search Results

49 records (took 0.024 seconds)

    4.
    发明专利
    未知

    公开(公告)号：ES2217891T3

    公开(公告)日：2004-11-01

    申请号：ES99973824

    申请日：1999-11-26

    Applicant: BASF AG

    Inventor： THIL LUCIEN ,  BREITSCHEIDEL BORIS ,  DISTELDORF WALTER ,  ZELLER EDGAR ,  WALTER MARC ,  MORSBACH BERND

    IPC: C07B61/00 ,  C07C29/14 ,  C07C31/125 ,  C07C67/08 ,  C07C69/44 ,  C07C69/80 ,  C08K5/05 ,  C08K5/10 ,  C08K5/11 ,  C08K5/12 ,  C08L27/06

    Abstract: The mixture described is a mixture of isomeric nonanol diesters of a dicarboxylic acid, selected from the class consisting of a mixture of diesters of adipic acid in the 1H NMR spectrum of which, observed in CDCl3, the ratio of the area under the resonance signals at chemical shifts in the range from 1.0 to 2.0 ppm with respect to TMS to the area under the resonance signals at chemical shifts in the range from 0.5 to 1.0 ppm with respect to TMS is from 1.20 to 5.00 and a mixture of diesters of phthalic acid, in the 1H NMR spectrum of which, observed in CDCl3, the ratio of the area under the resonance signals at chemical shifts in the range from 1.1 to 3.0 ppm with respect to TMS to the area under the resonance signals at chemical shifts in the range from 0.5 to 1.1 ppm with respect to TMS is from 1.00 to 4.00.The diesters of adipic and phthalic acid are suitable as plasticizers for PVC-based molding compositions and have high compatibility, a low cold crack temperature, low torsional rigidity and/or high thermal stability.

    5.
    发明专利
    未知

    公开(公告)号：ES2199546T3

    公开(公告)日：2004-02-16

    申请号：ES99904776

    申请日：1999-01-14

    Applicant: BASF AG

    Inventor： GEISSLER BERNHARD ,  ROPER MICHAEL ,  ZELLER EDGAR ,  PACIELLO ROCCO ,  DECKER JURGEN ,  VOSS HARTWIG

    IPC: B01J31/22 ,  B01J31/16 ,  B01J31/18 ,  B01J31/20 ,  C07B61/00 ,  C07C27/20 ,  C07C29/16 ,  C07C31/125 ,  C07C45/50 ,  C07C47/02 ,  C08G73/02

    Abstract: The invention relates to a method for the production of aldehydes or aldehydes and alcohols by hydroformylation of olefins in the presence of a complexing catalyst homogeneously dissolved in a reaction mixture, containing a metal of Group VIIIa of the periodic table of the elements and a phosphorus-free, polydentate nitrogen compound suitable for complex formation as ligand at temperatures ranging from 50 to 100° C. and pressures from 20 to 1,000 bar and recirculating the catalyst complex in the hydroformylation reaction, wherein a) derivatized polyamines are used that are substantially non-water soluble and suitable for complex formation and have a mean molecular weight of more than 1,000 Dalton and at least 10 nitrogen atoms; b) the catalyst complex remaining in the bottom of the distillation column and the excess ligands obtained from the reaction mixture are recirculated totally or partially in the hydroformylation once the hydroformylation reaction and the separation or partial separation by distillation of the aldehydes and the alcohols has been completed; c) continues or at least batchwise evacuation of at least part of the high boiler from the bottom of the distillation of the reaction mixture is then carried out.

    6.
    发明专利
    未知

    公开(公告)号：DE59905443D1

    公开(公告)日：2003-06-12

    申请号：DE59905443

    申请日：1999-01-14

    Applicant: BASF AG

    Inventor： GEISSLER BERNHARD ,  ROEPER MICHAEL ,  ZELLER EDGAR ,  PACIELLO ROCCO ,  DECKER JUERGEN ,  VOSS HARTWIG ,  MAHR NORBERT

    IPC: B01J31/22 ,  B01J31/16 ,  B01J31/18 ,  B01J31/20 ,  C07B61/00 ,  C07C27/20 ,  C07C29/16 ,  C07C31/125 ,  C07C45/50 ,  C07C47/02 ,  C08G73/02

    Abstract: The invention relates to a method for the production of aldehydes or aldehydes and alcohols by hydroformylation of olefins in the presence of a complexing catalyst homogeneously dissolved in a reaction mixture, containing a metal of Group VIIIa of the periodic table of the elements and a phosphorus-free, polydentate nitrogen compound suitable for complex formation as ligand at temperatures ranging from 50 to 100° C. and pressures from 20 to 1,000 bar and recirculating the catalyst complex in the hydroformylation reaction, wherein a) derivatized polyamines are used that are substantially non-water soluble and suitable for complex formation and have a mean molecular weight of more than 1,000 Dalton and at least 10 nitrogen atoms; b) the catalyst complex remaining in the bottom of the distillation column and the excess ligands obtained from the reaction mixture are recirculated totally or partially in the hydroformylation once the hydroformylation reaction and the separation or partial separation by distillation of the aldehydes and the alcohols has been completed; c) continues or at least batchwise evacuation of at least part of the high boiler from the bottom of the distillation of the reaction mixture is then carried out.

    9.
    发明专利
    未知

    公开(公告)号：BR9917230A

    公开(公告)日：2002-01-08

    申请号：BR9917230

    申请日：1999-11-26

    Applicant: BASF AG

    Inventor： THIL LUCIEN ,  BREITSCHEIDEL BORIS ,  DISTELDORF WALTER ,  ZELLER EDGAR ,  WALTER MARC ,  MORSBACH BERND ,  DORNIK KNUT

    IPC: C07B61/00 ,  C07C29/14 ,  C07C31/125 ,  C07C67/08 ,  C07C69/44 ,  C07C69/80 ,  C08K5/05 ,  C08K5/10 ,  C08K5/11 ,  C08K5/12 ,  C08L27/06

    Abstract: The mixture described is a mixture of isomeric nonanol diesters of a dicarboxylic acid, selected from the class consisting of a mixture of diesters of adipic acid in the 1H NMR spectrum of which, observed in CDCl3, the ratio of the area under the resonance signals at chemical shifts in the range from 1.0 to 2.0 ppm with respect to TMS to the area under the resonance signals at chemical shifts in the range from 0.5 to 1.0 ppm with respect to TMS is from 1.20 to 5.00 and a mixture of diesters of phthalic acid, in the 1H NMR spectrum of which, observed in CDCl3, the ratio of the area under the resonance signals at chemical shifts in the range from 1.1 to 3.0 ppm with respect to TMS to the area under the resonance signals at chemical shifts in the range from 0.5 to 1.1 ppm with respect to TMS is from 1.00 to 4.00.The diesters of adipic and phthalic acid are suitable as plasticizers for PVC-based molding compositions and have high compatibility, a low cold crack temperature, low torsional rigidity and/or high thermal stability.

Patent Agency Ranking