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公开(公告)号:BR0110451A
公开(公告)日:2003-03-11
申请号:BR0110451
申请日:2001-04-30
Applicant: BASF AG
Inventor: BASSLER PETER , BAUMANN DIETER , FISCHER ROLF-HARTMUTH , FUCHS EBERHARD , MELDER JOHANN-PETER , OHLBACH FRANK
IPC: C07D223/10 , C07B61/00 , C07D201/08 , C07D201/16
Abstract: A process for the preparation of caprolactam is provided, whereina) a mixture (I) containing 6-aminocapronitrile and water is reacted in the liquid phase, in the presence of a catalyst, to give a mixture (II) containing caprolactam, ammonia, water, high-boiling components and low-boiling components,b) ammonia is then removed from the mixture (II) to give a mixture (III) containing caprolactam, water, high-boiling components and low-boiling components,c) water is then removed from the mixture (III) to give a mixture (IV) containing caprolactam, high-boiling components and low-boiling components, andd) a solid (V) containing caprolactam is then obtained from the mixture (IV) by crystallization, the proportion by weight of caprolactam in the solid (V) being greater than in the mixture (IV).
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公开(公告)号:ES2175793T3
公开(公告)日:2002-11-16
申请号:ES98948912
申请日:1998-09-05
Applicant: BASF AG
Inventor: PUTTER HERMANN , BAUMANN DIETER , HANNEBAUM HEINZ
IPC: C25B3/25 , C07D307/88 , C25B3/04
Abstract: A process for preparing phthalides byI. reducing phthalic acid or phthalic acid derivatives, where the carboxyl groups may be replaced by units which can be derived from the carboxyl groups by a condensation reaction and where one or more of the hydrogens of the o-phenylene unit may be substituted by inert radicals, at a cathode in a undivided electrolytic cell and dissolved in an electrolyte,II. discharging the electrolyte from the electrolytic cell when the reaction has proceeded to the stage where the molar ratio (M), formed by the proportion of phthalide and the sum of the proportions of phthalide and phthalic acid of phthalic acid derivatives in the electrolyte, is from 0.8:1 to 0.995:1, andIII. crystallizing the phthalides from the electrolyte and removing them from the mother liquor, if appropriate after distillative work-up of the electrolyte is described.
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公开(公告)号:CA2407723A1
公开(公告)日:2002-10-29
申请号:CA2407723
申请日:2001-04-30
Applicant: BASF AG
Inventor: BAUMANN DIETER , BASSLER PETER , FUCHS EBERHARD , FISCHER ROLF-HARTMUTH , MELDER JOHANN-PETER , OHLBACH FRANK
IPC: C07D223/10 , C07B61/00 , C07D201/08 , C07D201/16
Abstract: The invention relates to a method for producing caprolactam, characterized i n that a) a mixture (I) containing 6-aminocapronitrile and water in the liquid phase is converted into a mixture (II) containing caprolactam, ammonia, wate r, high boilers and low boilers in the presence of a catalyst; b) ammonia is th en removed from mixture (II), leaving a mixture (III) containing caprolactam, water, high boilers and low boilers; c) water is then removed from mixture (III) leaving a mixture (IV) containing caprolactam, high boilers and low boilers, and d) a solid (V) containing caprolactam is obtained from mixture (IV) by crystallization, the proportion by weight of caprolactam in the soli d (V) being greater than that in the mixture (IV).
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公开(公告)号:BR0107847A
公开(公告)日:2002-10-22
申请号:BR0107847
申请日:2001-01-24
Applicant: BASF AG
Inventor: DECKER EMILE DE , BASTIAENSEN ERIK , BAUMANN DIETER , ECK BERND , HEILEK J RG
Abstract: Purification of (meth)acrylic acid by crystallisation is carried out using a combination of >=2 different dynamic crystallisation processes.
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公开(公告)号:AT219962T
公开(公告)日:2002-07-15
申请号:AT97115933
申请日:1997-09-12
Applicant: BASF AG
Inventor: WEYER HANS-JUERGEN DR , ECK BERND , BAUMANN DIETER , MALTRY BERNHARD
IPC: B01J2/00 , B01J2/02 , B01J2/26 , C07C67/52 , C07C69/675
Abstract: The production of neopentyl glycolhydroxypivalate (NPG-HP) granules (I) comprises pouring molten NPG-HP onto a cooling surface so that the melt solidifies, using a melt containing 3 wt.% NPG-HP crystals. Also claimed are: (i) NPG-HP granules (I) obtained by the above process, especially: (a) spherical granules with an average diameter of 3-16 mm; or (b) granules with an average diameter of 20-100 mm and at least two parallel faces 15-30 mm apart; and (ii) the use of a granulating system for the above process, with a precooler (2) for the NPG-HP melt, a precrystalliser (3), and a drop-forming system (4) or a flat spreader to bring the melt onto a cooling belt (6), with a crusher if a flat spreader is used.
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公开(公告)号:DE10122788A1
公开(公告)日:2002-06-06
申请号:DE10122788
申请日:2001-05-10
Applicant: BASF AG
Inventor: HAMMON ULRICH , ECK BERND , BAUMANN DIETER , HEILEK JOERG , MUELLER-ENGEL KLAUS JOACHIM
IPC: C07C51/43 , C07C51/47 , C07C57/07 , C07D207/26 , C07D207/267 , C07B63/00 , B01D9/00 , C07D207/27
Abstract: Preparation of a purified melt of monomer(s) involves forming a suspension, crystallizing, mechanically separating off the suspended monomer crystals and further crystallizing, followed by further mechanical separation.
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公开(公告)号:DE59802024D1
公开(公告)日:2001-12-13
申请号:DE59802024
申请日:1998-06-05
Applicant: BASF AG
Inventor: MELDER DR , BAUMANN DIETER , MALTRY BERNHARD
IPC: C07C69/675 , B01D9/00 , B01J2/26 , C07C67/52
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公开(公告)号:AU7238201A
公开(公告)日:2001-11-12
申请号:AU7238201
申请日:2001-04-30
Applicant: BASF AG
Inventor: BASSLER PETER , BAUMANN DIETER , FISCHER ROLF-HARTMUTH , FUCHS EBERHARD , MELDER JOHANN-PETER , OHLBACH FRANK
IPC: C07D223/10 , C07B61/00 , C07D201/08 , C07D201/16
Abstract: A process for the preparation of caprolactam is provided, whereina) a mixture (I) containing 6-aminocapronitrile and water is reacted in the liquid phase, in the presence of a catalyst, to give a mixture (II) containing caprolactam, ammonia, water, high-boiling components and low-boiling components,b) ammonia is then removed from the mixture (II) to give a mixture (III) containing caprolactam, water, high-boiling components and low-boiling components,c) water is then removed from the mixture (III) to give a mixture (IV) containing caprolactam, high-boiling components and low-boiling components, andd) a solid (V) containing caprolactam is then obtained from the mixture (IV) by crystallization, the proportion by weight of caprolactam in the solid (V) being greater than in the mixture (IV).
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公开(公告)号:HU0003490A2
公开(公告)日:2001-02-28
申请号:HU0003490
申请日:1998-09-18
Applicant: BASF AG
Inventor: BAUMANN DIETER , HANNEBAUM HEINZ , PUETTER HERMANN
IPC: C07D307/88 , C25B3/25
Abstract: Phthalides in as-obtained phthalide synthesis reaction mixtures are recovered in pure form by(a) distilling compounds having a boiling point below the boiling point of the phthalide from the reaction mixture, provided such compounds are present in the reaction mixture, to obtain a crude phthalide as bottom product,(b) crystallizing the phthalide from a melt of the crude phthalide.
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公开(公告)号:DE19724461A1
公开(公告)日:1998-12-17
申请号:DE19724461
申请日:1997-06-10
Applicant: BASF AG
Inventor: MELDER JOHANN-PETER DR , BAUMANN DIETER , MALTRY BERNHARD
IPC: C07C69/675 , B01D9/00 , B01J2/26 , C07C67/52
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