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公开(公告)号：DE10041345A1
公开(公告)日：2002-03-07
申请号：DE10041345
申请日：2000-08-23
Applicant: BASF AG
Inventor： RATH HANS PETER , MACH HELMUT , ROEPER MICHAEL , STEPHAN JUERGEN , KARL JOERN , BLACKBOROW RICHARD J
Abstract: The invention relates to a method for producing linear alpha olefins by means of an isomerising metathetical reaction and ensuing ethenolysis. The method comprises the following steps: i) a C4-C10 olefin fraction is introduced into an isomerising metathesis reaction; ii) the mixture obtained is separated into a) a C2-C3-olefin fraction, b) a fraction containing olefins having the desired carbon count, c) a light fraction containing olefins having a carbon count of C4 or above, but below the carbon count of the desired fraction b) and, d) a heavy fraction containing olefins having a carbon count which is above the carbon count of the desired fraction b); iii) the light fraction c) and optionally the heavy fraction d) are redirected into the isomerising metathesis reaction i); iv) the fraction b) and optionally the fraction d) are introduced into an ethenolysis reaction; and v) the alpha olefin fraction produced in iv) is isolated. Linear C8-C12 alpha olefins can be especially produced using said method.
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公开(公告)号：DE59705219D1
公开(公告)日：2001-12-06
申请号：DE59705219
申请日：1997-08-29
Applicant: BASF AG
Inventor： KANAND JUERGEN , ROEPER MICHAEL
Abstract: In a process for producing alkoxybutenes, 1,3-butadiene or a butadiene-containing hydrocarbon mixture is reacted with an alcohol of formula ROH (I) at an increased temperature and pressure in the presence of a Brönsted acid, yielding a mixture of addition products of formulas (II) and (III), in which the radical R is a C2-C20 alkyl, alkenyl, cycloalkyl or cycloalkenyl group substituted or not with 1 to 2 C1-C10 alkoxy or hydroxy groups, or is a C2-C10 aryl or C7-C11 aralkyl group or a methyl group. The disclosed improvement consists in that the reaction is carried out in the presence of water.
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公开(公告)号：DE59704682D1
公开(公告)日：2001-10-25
申请号：DE59704682
申请日：1997-07-23
Applicant: BASF AG
Inventor： FISCHER ROLF , PACIELLO ROCCO , ROEPER MICHAEL , SCHNURR WERNER
IPC: B01J23/44 , B01J23/46 , B01J23/75 , C07B61/00 , C07C209/48 , C07C209/60 , C07C211/12 , C07C253/30 , C07C255/24
Abstract: PCT No. PCT/EP97/03987 Sec. 371 Date Feb. 1, 1999 Sec. 102(e) Date Feb. 1, 1999 PCT Filed Jul. 23, 1997 PCT Pub. No. WO98/05631 PCT Pub. Date Feb. 12, 1998The invention concerns a process for the preparation of 6-aminocapronitrile or 6-aminocapronitrile-hexamethylene diamine mixtures by: a) reacting 5-formylvaleronitrile with ammonia and hydrogen in the presence of hydrogenation catalysts selected from the group consisting of metals or metal compounds rhenium, copper and elements of group VIII of the periodic table of elements, a hydrogenation discharge product being obtained; and b) extracting from the hydrogenation discharge product 6-aminocapronitrile and optionally hexamethylene diamine, provided that the hydrogenation catalyst does not contain copper, nickel or copper and nickel as it's only components.
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公开(公告)号：BR9916520A
公开(公告)日：2001-09-04
申请号：BR9916520
申请日：1999-12-21
Applicant: BASF AG
Inventor： MAAS HEIKO , ROEPER MICHAEL , WALTER MARC , SCHULZ RALF , TROPSCH JUERGEN , JOGER HANS-ULRICH , SCHWAB PETER , SCHULZ MICHAEL
IPC: C07B61/00 , C07C2/10 , C07C6/04 , C07C11/02 , C07C11/107 , C07C29/16 , C07C31/125 , C07C41/03 , C07C43/13 , C07C45/50 , C07F9/09 , C07F9/11
Abstract: The invention describes a process for the preparation of novel surfactant alcohols and surfactant alcohol ethers by derivatization of olefins having from about 10 to 20 carbon atoms or of mixtures of such olefins to give alkanols, and optional subsequent alkoxylation, which comprises subjecting a C 4 -olefin mixture to metathesis, dimerizing the resulting olefins, and then derivatizing them to give surfactant alcohols, and optionally alkoxylating said alcohols. The olefin mixture obtained in the dimerization has a high proportion of branched components and less than 10% by weight of compounds which contain a vinylidene group. invention further describes the use of the surfactant alcohols and surfactant alcohol ethers to give surfactants by glycosylation or polyglycosylation, sulfation or phosphation.
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公开(公告)号：DE59703510D1
公开(公告)日：2001-06-13
申请号：DE59703510
申请日：1997-05-28
Applicant: BASF AG
Inventor： BREIT BERNHARD , PACIELLO ROCCO , GEISSLER BERNHARD , ROEPER MICHAEL
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Patent Agency Ranking
公开(公告)号：DE19827232A1
公开(公告)日：1999-12-23
申请号：DE19827232
申请日：1998-06-18
Applicant: BASF AG
Inventor： MAAS HEIKO , PACIELLO ROCCO , ROEPER MICHAEL , FISCHER JAKOB
IPC: B01J31/22 , B01J31/18 , B01J31/28 , C07B61/00 , C07C45/50 , C07C47/02 , C07C253/10 , C07F9/6571 , C07F15/00
Abstract: The invention relates to a catalyst comprising at least one complex of a metal of subgroup VIII which comprises at least one monodentate, bidentate or multidentate phosphinite ligand. The phosphorus atom and the oxygen atom of the phosphinite group are part of a 5 to 8-member heterocyclic compound. The invention also relates to a method for the hydroformylation and the hydrocyanation of compounds, said compounds containing at least one ethylenically unsaturated double bond, in the presence of such a catalyst. The preferred phosphinite ligand has the following formula (Ia), wherein R and R , independent of one another, represent hydrogen or trifluoromethyl.
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公开(公告)号：RU2135456C1
公开(公告)日：1999-08-27
申请号：RU96116892
申请日：1995-01-12
Applicant: BASF AG
Inventor： KANAND JUERGEN , ROEPER MICHAEL , PINKOS ROLF , ROKKO PACHELLO , THOME ALFRED
IPC: B01J21/16 , B01J27/18 , B01J29/06 , C07B61/00 , C07C27/00 , C07C29/17 , C07C31/12 , C07C41/06 , C07C41/32 , C07C43/15 , C07C45/51 , C07C47/02
Abstract: FIELD: industrial organic synthesis. SUBSTANCE: 1,3-butadiene interacts with alcohol of formula ROH, wherein R is alkyl or alkenyl with 2-20 carbon atoms optionally substituted by one or two C 1 -C 10 -alkoxy or hydroxy-C 1 -C 10 -alkoxy groups; C 6 -C 10 -aryl; C 7 -C 11 -arylalkyl; or methyl at elevated temperatures and pressure in presence of Broensted acid or Ib, VIIb or VIIIb group element complex with phosphorus- or nitrogen-containing ligands to form adducts corresponding to structures C-C=C-C-OR (II) and C-C(OR)-C=C (III). Adduct III is isomerized into adduct II. The latter is subjected to isomerization in presence of transition metal-containing homogeneous or heterogeneous catalyst in liquid phase or in presence of transition metal-containing heterogeneous catalyst in gas phase to form enol ether with structure C-C- C=C-OR (IV). Enol ether IV is subjected to action of hydrogen and water or only water in presence of homogeneous or heterogeneous catalyst as indicated above to form n-butyraldehyde and/or n-butanol, from which alcohol ROH is further released and recycled into the first step of process. EFFECT: increased selectivity of process and yield of products. 7 cl, 1 dwg, 6 tbl, 15 ex
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公开(公告)号：BR9609881A
公开(公告)日：1999-03-23
申请号：BR9609881
申请日：1996-07-26
Applicant: BASF AG
Inventor： ACHHAMMER GUENTHER , ROEPER MICHAEL
IPC: C07C67/54 , C07C69/716
Abstract: PCT No. PCT/EP96/03290 Sec. 371 Date Jan. 27, 1998 Sec. 102(e) Date Jan. 27, 1998 PCT Filed Jul. 26, 1996 PCT Pub. No. WO97/06126 PCT Pub. Date Feb. 20, 19975-Formylvaleric esters are prepared in a yield of not less than 90% by distillation of a formylvaleric ester mixture of 5-formylvaleric ester and either 3- or 4-formylvaleric ester or a mixture of 3- and 4-formylvaleric esters, where the ester radicals of the respective formylvaleric esters are identical, wherein the 3- or 4-formylvaleric ester or a mixture thereof is separated from the 5-formylvaleric ester in a distillation column at a pressure in the range from 2 to 100 mbar and a temperature of not above 150 DEG C. (measured as the temperature at the bottom of the column) and the esters used are the corresponding methyl or ethyl esters, where the purity of the 5-formylvaleric ester is not less than 98% and, as impurity, 4-formylvaleric ester is present in an amount of not more than 100 ppm.
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公开(公告)号：NO991266A
公开(公告)日：1999-03-16
申请号：NO991266
申请日：1999-03-16
Applicant: BASF AG
Inventor： KANAND JUERGEN , ROEPER MICHAEL
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公开(公告)号：DE59504832D1
公开(公告)日：1999-02-25
申请号：DE59504832
申请日：1995-08-24
Applicant: BASF AG
Inventor： KANAND JUERGEN , ROEPER MICHAEL , PACIELLO ROCCO , THOME ALFRED
IPC: C07C27/00 , C07B61/00 , C07C29/00 , C07C29/09 , C07C29/17 , C07C31/12 , C07C45/51 , C07C45/56 , C07C47/02 , C07D295/023
Abstract: PCT No. PCT/EP95/03358 Sec. 371 Date Jul. 23, 1997 Sec. 102(e) Date Jul. 23, 1997 PCT Filed Aug. 24, 1995 PCT Pub. No. WO96/07630 PCT Pub. Date Mar. 14, 1996A process for the preparation of n-butyraldehyde and/or n-butanol, in which a) 1,3-butadiene is caused to react with an amine of the formula I R1R2NH, I in which R1 and R2 independently denote hydrogen, optionally substituted aliphatic or cycloaliphatic radicals, or aryl or aralkyl radicals or are linked to form a bridging member which can contain hetero atoms, at elevated temperature and under superatmospheric pressure in the presence of a compound of a Group VIIIb element and in the presence of an alkali metal amide or a basic metal oxide to form a mixture of the adducts of the formulas II II and III III b) the adduct III is isomerized to the adduct II, c) the adduct II is isomerized in the presence of a homogeneous or heterogeneous transition metal element catalyst in the liquid phase or in the presence of a heterogeneous catalyst containing a transition metal element in the gaseous phase to form the enamine of the formula IV IV and d) n-butyraldehyde and/or n-butanol is/are produced from this enamine.
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