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公开(公告)号:DE50006775D1
公开(公告)日:2004-07-15
申请号:DE50006775
申请日:2000-11-27
Applicant: BASF AG
Inventor: GOETZ ROLAND , GOETZ NORBERT , KEIL MICHAEL , WOLF BERND , STEINMETZ ADRIAN , STAMM ARMIN , HENKELMANN JOCHEM
Abstract: The invention relates to a method for producing o-chloromethyl benzoic acid chlorides of formula (I), in which R 1 to R 4 can be the same or different and represent hydrogen C 1 -C 4 alkyl, halogen or trifluoromethyl, by reaction benzo condensed lactones of formula (II), in which R 1 to R 4 have the above-mentioned meaning, with thionyl chloride. The inventive method is characterized in that the reaction is carried out in the presence of catalytic quantities of a Lewis acid and in the presence of catalytic quantities of a phosphine derivative.
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公开(公告)号:CZ2004410A3
公开(公告)日:2004-06-16
申请号:CZ2004410
申请日:2002-10-17
Applicant: BASF AG
Inventor: ROHDE THORSTEN , STAMM ARMIN , HENKELMANN JOCHEM
IPC: C07C263/10 , C07C265/08 , C07C265/10 , C07C265/12 , C07C265/14
Abstract: In a process for preparing isocyanates by reacting the corresponding primary amines with phosgene in an inert solvent, use is made of from 0.01 to 50 mol % of a sulfoxide, a sulfone or a mixture thereof, based on the total amount of primary amine and isocyanate formed in the reaction solution.
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公开(公告)号:CZ20040409A3
公开(公告)日:2004-06-16
申请号:CZ20040409
申请日:2002-10-17
Applicant: BASF AG
Inventor: ROHDE THORSTEN , STAMM ARMIN , HENKELMANN JOCHEM
IPC: C07B61/00 , C07C263/10 , C07C265/10
CPC classification number: C07C263/10 , C07C2601/14 , C07C265/10
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公开(公告)号:AT265482T
公开(公告)日:2004-05-15
申请号:AT01925333
申请日:2001-02-16
Applicant: BASF AG
Inventor: HENKELMANN JOCHEM , MAAS HEIKO , SCHULZ GERHARD , STAMM ARMIN , RINK HEINZ-PETER , JUNG WERNER-ALFONS , SCHWAB PETER
IPC: C07C263/10 , C07C265/14 , C08G18/62 , C08G18/72 , C08G18/73 , C09D175/04 , C09J175/04
Abstract: A description is given of polyisocyanates of the formula I in which R and R' are identical or different and are alkyl groups having 1-4 carbon atoms and n is on average from 1.5 to 5 and also of a process for preparing these polyisocyanates in which a polyamine of the formula II in which R, R', and n are as defined above, is reacted with phosgene. The new polyisocyanates are suitable for producing crosslinked polyurethanes from reaction mixtures with low solvent content and for producing coating compositions or adhesives. Also described are the coating compositions and adhesives, and their use.
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公开(公告)号:HU0304002A2
公开(公告)日:2004-03-29
申请号:HU0304002
申请日:2002-04-17
Applicant: BASF AG
Inventor: DRANSFELD PETER , HEILIG MANFRED , KNEUPER HEINZ-JOSEF , RITTINGER STEFAN , SCHILDBERG HANS-PETER , STAMM ARMIN , WEBER THEODOR
Abstract: A method is provided for the intrinsically safe handling of 3-chloropropyne in the presence of a diluent with a boiling point ranging from -50° C. (223 K) to 200° C. (473 K) under atmospheric pressure, wherein the concentration of 3-chloropropyne in the liquid phase and in the gas phase is kept below the concentrations capable of deflagration by means of the type and amount of the diluent, the temperature and the total system pressure, together with the use of a 3-chloropropyne prepared, stored or transported in this way in the synthesis of dyestuffs, pharmaceutical and agricultural active ingredients, electroplating auxiliaries, disinfectants, steroids and growth hormones.
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公开(公告)号:DE59907811D1
公开(公告)日:2003-12-24
申请号:DE59907811
申请日:1999-07-06
Applicant: BASF AG
Inventor: STAMM ARMIN , HENKELMANN JOCHEM
IPC: C07D233/61 , C07D233/90 , C07D521/00
Abstract: In a process for preparing carbonyldiimidazole of the general formulae Ia, Ib, Ic or mixtures thereofwhere R1 is hydrogen or a C1-4-alkyl radical and R2 is hydrogen or a methyl radical, by reacting at least one imidazole of the general formulae IIa and IIbin which R1 and R2 have the abovementioned meaning, with phosgene in an inert solvent, stoichiometric amounts, based on the imidazoles, of an organic nitrogen base which has a lower pKb than imidazole are added to the reaction mixture.
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公开(公告)号:DE59907304D1
公开(公告)日:2003-11-13
申请号:DE59907304
申请日:1999-06-14
Applicant: BASF AG
Inventor: STAMM ARMIN , HENKELMANN JOCHEM
IPC: C07D233/56 , C07D233/60 , C07D233/95 , C07D521/00
Abstract: In a process for preparing carbonyldiimidazole from imidazole and phosgene in an inert solvent, the imidazole hydrochloride which results as coupled product is removed as melt from the resulting reaction mixture by phase separation.
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公开(公告)号:DE59906364D1
公开(公告)日:2003-08-28
申请号:DE59906364
申请日:1999-05-21
Applicant: BASF AG
Inventor: WEYER HANS-JUERGEN , STAMM ARMIN , WEBER THEODOR , HENKELMANN JOCHEM
Abstract: The present invention relates to a process for preparing alkyl, alkenyl and alkynyl chlorides from alcohols by reaction with a chlorinating agent in the presence of a catalyst, wherein the catalyst is a urea compound.
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公开(公告)号:DE59905751D1
公开(公告)日:2003-07-03
申请号:DE59905751
申请日:1999-03-08
Applicant: BASF AG
Inventor: STAMM ARMIN , HENKELMANN JOCHEM , WEYER HANS-JUERGEN
Abstract: The invention relates to a continuous method for producing propargyl chloride by reacting propargyl alcohol with a chlorinating agent in the presence of a catalyst. According to the invention, the chlorinating agent, propargyl alcohol and 0.1 to 10 mol.% of the catalyst with regard to the amount of propargyl alcohol is continuously dosed in a reaction zone and is reacted at a temperature ranging from 40 to 70 DEG C.
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公开(公告)号:AT240928T
公开(公告)日:2003-06-15
申请号:AT99959265
申请日:1999-10-29
Applicant: BASF AG
Inventor: STAMM ARMIN , HENKELMANN JOCHEM
Abstract: The invention relates to a process for the preparation of acid chlorides by reaction of carboxylic acids, carboxylic anhydrides, cyclic carboxylic esters or sulfonic acids with phosgene in the presence of a catalytic amount of a compound from the group consisting of N,N,N',N'-tetrasubstituted amidinium halides (I), N,N,N'-trisubstituted amidinium hydrohalides (II) and N,N,N'-trisubstituted amidines (III).
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