103.
    发明专利
    未知

    公开(公告)号:BR9707635A

    公开(公告)日:1999-07-27

    申请号:BR9707635

    申请日:1997-02-20

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP97/00803 Sec. 371 Date Aug. 24, 1998 Sec. 102(e) Date Aug. 24, 1998 PCT Filed Feb. 20, 1997 PCT Pub. No. WO97/30993 PCT Pub. Date Aug. 28, 1997Pyrazolylhetaroyl derivatives of the formula I where the substituents have the following meanings: L and M are hydrogen, C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C1-C4-alkoxy, it being possible for these groups to be unsubstituted or substituted by one to five halogen atoms or C1-C4-alkoxy; halogen, cyano, nitro; X is oxygen or sulfur which can be substituted by one or two oxygens; n is zero, one or two; and Q, R1, R2, R3 and R4 have the meanings given in claim 1, processes for the preparation of the pyrazol-4-yl-hetaroyl derivatives, compositions comprising them, and the use of these derivatives or of the compositions comprising them for controlling weeds.

    PROCESS AND INTERMEDIATE PRODUCTS FOR PREPARING SUBSTANTIALLY ISOMER-PURE E-2-(2-ARYLOXYMETHYLENE PHENYL)-CROTONIC ACID METHYL ESTERS

    公开(公告)号:NZ307541A

    公开(公告)日:1999-04-29

    申请号:NZ30754196

    申请日:1996-04-23

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP96/01689 Sec. 371 Date Oct. 9, 1997 Sec. 102(e) Date Oct. 9, 1997 PCT Filed Apr. 23, 1996 PCT Pub. No. WO96/34847 PCT Pub. Date Nov. 7, 1996A process for the preparation of essentially isomerically pure methyl E-2-(2-aryloxymethylenephenyl)crotonates of the formula Ia Ia where R is an aromatic radical and R' is a C1-C3-alkyl group, which comprises first converting a suitable methyl 2-(2-aryloxymethylenephenyl)- alpha -ketoacetate with an alkyl metal compound of the formula IIIM-CH2-R'IIIwhere M is a metal ion equivalent into the corresponding methyl 2-(2-aryloxymethylenephenyl)- alpha -hydroxybutyrate of the formula IV, subsequently dehydrating IV in the presence of an acid to give a mixture of methyl E- and Z-2-(2-aryloxymethylenephenyl)crotonates and, subsequently, converting this mixture in the presence of a base in an inert polar solvent into the essentially isomerically pure methyl E-2-(2-aryloxymethylenephenyl)crotonate Ia.

    DERIVADOS DE ACIDO IMINOOXIFENILACETICO, SU PREPARACION, PRODUCTOS INTERMEDIOS PARA SU PREPARACION, Y SU USO.

    公开(公告)号:MX9804622A

    公开(公告)日:1998-10-31

    申请号:MX9804622

    申请日:1998-06-09

    Applicant: BASF AG

    Abstract: Se presentan derivados de ácido 2-iminooxifenilacético (Ver Formula) donde los sustituyentes y el índice tienen los siguientes significados: R1 es C(CO2CH3)-NOCH3 (Ia), C(CONHCH3)=NOCH3 (Ib), C(CONH2)=NOCH3 (Ic), C(CO2CH3)=CHOCH3 (Id) o bien C(CO2Ch3)=CHCH3 (Ie); R2 es ciano, nitro, halogeno, alquilo, haloalquilo o bien alcoxi; m es 0, 1 o bien 2; R3 es hidrogeno, ciano, hidroxilo, halogeno, alquilo, haloalquilo, alcoxialquilo, alcoxi, haloalcoxi, alquiltio, ciclopropilo, alquenilo, ariloxialquilo, bencilo o benciloxi no sustituidos o sustituidos; R4 es hidrogeno, ciano, alquilo, alquenilo, alquinilo, cicloalquilo, heterocíclilo, arilo y hetarilo no sustituidos o bien sustituidos; alcoxi, alqueniloxi, alquiniloxi, cicloalcoxi, heterocicliloxi, ariloxi y hetariloxi no sustituidos o sustituidos ariltio y hetariltio no sustituidos o bien sustituidos; -Q-C(R5)-N-Y1-R6 o bien -Q-O-N-CR7R8, R3 y R4 juntos con el átomo de carbono sobre el cual están unidos con un anillo de cuatro a ocho miembros no sustituidos o bien sustituido que, además de átomos de carbono, puede contener uno o dos átomos de oxígeno y/o azufre y/o grupos NH y/o N(alquilo C1-C4); R3 y R4 no están simultáneamente enlazados al átomo de carbono por medio de heteroátomos; sus sales, procesos y productos intermedios para su preparacion, y su uso.

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