-
公开(公告)号:ES2152706T3
公开(公告)日:2001-02-01
申请号:ES97944765
申请日:1997-08-18
Applicant: BASF AG
Inventor: LATSCH STEFAN , FISCHER WOLFGANG , GAUSEPOHL HERMANN , WARZELHAN VOLKER , SCHADE CHRISTIAN
IPC: C08F4/44 , C08F4/50 , C08F12/04 , C08F12/08 , C08F36/04 , C08F212/04 , C08F236/10 , C08F279/02 , C08F297/04
Abstract: The anionic polymerization of dienes or copolymers of dienes and vinylaromatic monomers in a vinylaromatic monomer or monomer mixture to give homopolydienes or copolymers or mixed homopolydienes and copolymers is carried out in the presence of a metal alkyl or aryl of an element having a valence of at least two without addition of Lewis bases.
-
公开(公告)号:DE19923579A1
公开(公告)日:2000-11-23
申请号:DE19923579
申请日:1999-05-21
Applicant: BASF AG
Inventor: JUENGLING STEPHAN , SCHADE CHRISTIAN , GAUSEPOHL HERMANN , WARZELHAN VOLKER , MOORS RAINER , SCHAECH HANSJOERG , QUEISSER JOACHIM , LUINSTRA GERRIT
IPC: C08F4/642 , C08F36/04 , C08F279/02 , C08F297/04 , C08L55/02 , C08F4/64 , C08F236/10 , C08F236/12
Abstract: A process for the polymerization of dienes in a solvent containing vinyl-aromatic monomers, which is carried out in presence of an organometallic compound of titanium, zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum or tungsten as catalyst and a Lewis acid as cocatalyst. Independent claims are also included for: (a) a process for the production of high-impact polystyrene, acrylonitrile-butadiene-styrene copolymers or methyl methacrylate-butadiene-styrene copolymers using a rubber solution produced by the above process; (b) a process for the continuous production of impact-modified thermoplastic molding materials containing a rubber-based soft phase dispersed in a hard vinyl-aromatic matrix, by: (1) polymerizing dienes in vinyl-aromatic monomer solution as above in a first reaction zone, (2) transferring the diene rubber to a second zone and subjecting it to anionic or radical polymerization, optionally in presence of further vinyl-aromatic monomer or other comonomers in amounts sufficient to achieve phase inversion and (3) completing the polymerization in a third zone with the amount of vinyl-aromatic monomer required for the impact-modified material; and (c) a process for the production of solutions of rubber in styrene solutions with sterically demanding chelate catalysts.
-
公开(公告)号:BR9908079A
公开(公告)日:2000-10-31
申请号:BR9908079
申请日:1999-02-05
Applicant: BASF AG
Inventor: SCHADE CHRISTIAN , FISCHER WOLFGANG , GAUSEPOHL HERMANN , KLOSTERMANN RAINER , WARZELHAN VOLKER , FONTANILLE MICHEL , DEFFIEUX ALAIN , DESBOIS PHILIPPE
IPC: C08F4/52 , C08F4/46 , C08F4/50 , C08F12/04 , C08F236/10 , C08F279/02 , C08F297/06
Abstract: In a process for the homopolymerization of vinylaromatic monomers or the copolymerization of vinylaromatic monomers and dienes, the monomers are polymerized in the presence of at least one alkali metal organyl, at least one magnesium organyl and at least one aluminum organyl. The invention also provides an initiator composition for carrying out the process.
-
公开(公告)号:BR9906753A
公开(公告)日:2000-10-17
申请号:BR9906753
申请日:1999-02-05
Applicant: BASF AG
Inventor: SCHADE CHRISTIAN , FISCHER WOLFGANG , GAUSEPOHL HERMANN , KNOLLL KONRAD , WARZELHAN VOLKER , FONTANILLE MICHEL , DEFFIEUX ALAIN , DESBOIS PHILIPPE
IPC: C08F4/54 , C08F4/46 , C08F12/04 , C08F36/04 , C08F236/10 , C08F297/06
Abstract: In a process for the homopolymerization of vinylaromatic monomers or the copolymerization of vinylaromatic monomers and dienes in the presence of at least one alkali metal compound and at least one compound of an element of group 3a of the Periodic Table of the elements, the compounds contain, based on the sum of molar equivalents of alkali metal and elements of group 3a, in each casea) from 0.1 to 3.9 molar equivalents of oxygen, sulfur, nitrogen or phosphorus andb) from 0.1 to 3.9 molar equivalents of an organyl ligand.
-
公开(公告)号:DE59701736D1
公开(公告)日:2000-06-21
申请号:DE59701736
申请日:1997-09-29
Applicant: BASF AG
Inventor: HORCHLER VON LOCQUENGHIEN KLAU , YAMAMOTO MOTONORI , ERHARDT KLAUS , NGUYEN KIM SON , WARZELHAN VOLKER
Abstract: A polyester dispersion comprising water and a biodegradable copolyester which contains structural units derived from both aliphatic and aromatic carboxylic acids or their derivatives, and the coated fertilizer granules prepared using this polyester dispersion, and a process for their preparation. A fertilization method in which the coated fertilizer granules according to the invention are used.
-
公开(公告)号:DE59605251D1
公开(公告)日:2000-06-21
申请号:DE59605251
申请日:1996-02-03
Applicant: BASF AG
Inventor: WARZELHAN VOLKER , PIPPER GUNTER , SEELIGER URSULA , BAUER PETER , PAGGA UDO , YAMAMOTO MOTONORI
IPC: C08J5/00 , A61L15/26 , A61L15/62 , C08G63/183 , C08G63/20 , C08G63/60 , C08G63/668 , C08G63/672 , C08G63/688 , C08G63/91 , C08J9/00 , C08J9/04 , C08L67/00 , C08L101/16 , C09J167/00 , D21H19/28
Abstract: PCT No. PCT/EP96/00457 Sec. 371 Date Aug. 14, 1997 Sec. 102(e) Date Aug. 14, 1997 PCT Filed Mar. 5, 1996 PCT Pub. No. WO96/25446 PCT Pub. Date Aug. 22, 1996Biodegradable polyesters having a molecular weight (Mn) of from 5000 to 50,000 g/mol (measured by gel permeation chromatography), a viscosity number of from 30 to 350 g/ml (measured in 50:50 by weight of o-dichlorobenzene/phenol at a concentration of 0.5% by weight of polyester at 25 DEG C.), and a melting point of from 50 to 170 DEG C., and having both hydroxyl and carboxyl end groups, the molar ratio of carboxyl end groups to hydroxyl end groups being greater than one, which is obtained by reacting a mixture consisting essentially of a1) a mixture consisting essentially of from 45 to 80 mol % of adipic acid or ester-forming derivatives thereof, or mixtures thereof, from 20 to 55 mol % of terephthalic acid or ester-forming derivatives thereof, or mixtures thereof, and from 0 to 5 mol % of a sulfonate compound, where the sum of the individual mole percentages is 100 mol %, and a2) a dihydroxy compound selected from the group consisting of C2-C6-alkanediols and C5-C10-cycloalkanediols, in the presence of from 0.01 to 5 mol %, per mol of component a1), of a compound D having at least three groups capable of ester formation, the molar ratio of a1) to a2) being from 0.4:1 to 1.5:1, polymers and biodegradable thermoplastic molding compositions, processes for their preparation and their use for producing biodegradable moldings, adhesives, foams and blends with starch obtained from the polymers or molding compositions.
-
公开(公告)号:DE19843687A1
公开(公告)日:2000-03-30
申请号:DE19843687
申请日:1998-09-24
Applicant: BASF AG
Inventor: JUENGLING STEPHAN , SCHADE CHRISTIAN , GAUSEPOHL HERMANN , WARZELHAN VOLKER , DESBOIS PHILIPPE , FONTANILLE MICHEL , DEFFIEUX ALAIN
Abstract: The invention relates to a method for the anionic polymerisation of dienes in a solvent in the form of an aliphatic, isocyclic or aromatic hydrocarbon or hydrocarbon mixture, in the presence of an organic lithium polymerisation initiator and a dialkylmagnesium compound which is soluble in the hydrocarbon, the molar ratio of Mg/Li being greater than 0.8.
-
公开(公告)号:DK0792311T3
公开(公告)日:1999-09-27
申请号:DK95937865
申请日:1995-11-04
Applicant: BASF AG
Inventor: KRONER MATTHIAS , SCHORNICK GUNNAR , WARZELHAN VOLKER , SEELIGER URSULA , YAMAMOTO MOTONORI , B SCHL RAINER
IPC: C08G63/183 , C08G63/60 , C08G63/688 , C08G63/91 , C08J5/00 , C08J9/04 , C08L67/00 , C08L101/16 , C09J167/00 , D21H19/28
Abstract: PCT No. PCT/EP95/04335 Sec. 371 Date May 12, 1997 Sec. 102(e) Date May 12, 1997 PCT Filed Nov. 4, 1995 PCT Pub. No. WO96/15175 PCT Pub. Date May 23, 1996A biodegradable polyester obtainable by reacting a mixture comprising (a1) from 95 to 99.9% by weight of a polyester P1 obtainable by reacting a mixture essentially comprising (b1) a mixture comprising 35-95 mol % of adipic acid or ester-forming derivatives thereof, 5-65 mol % of terephthalic acid or ester-forming derivatives thereof, and 0-5 mol % of a compound containing sulfonate groups, and (b2) a dihydroxy compound selected from the group consisting of C2-C6-alkanediols and C5-C10-cycloalkanediols, with the proviso that a compound D with at least three groups capable of ester formation is employed to prepare the polyester P1, (a2) from 0.1 to 5% by weight of a divinyl ether C1 and (a3) from 0 to 5 mol %, based on component (b1) from the preparation of P1, of compound D, and other biodegradable polymers and thermoplastic molding compositions, processes for the preparation thereof, the use thereof for producing biodegradable moldings and adhesives.
-
公开(公告)号:AU2927299A
公开(公告)日:1999-09-15
申请号:AU2927299
申请日:1999-02-19
Applicant: BASF AG
Inventor: MOHRSCHLADT RALF , HILDEBRANDT VOLKER , WARZELHAN VOLKER
Abstract: Polyamide particles, or polymer particles comprising polyamides, are extracted with aqueous solutions of aminonitiles and optionally further polyamide-forming monomers, polyamide-forming oligomers or mixtures thereof.
-
公开(公告)号:AU3140399A
公开(公告)日:1999-09-06
申请号:AU3140399
申请日:1999-02-05
Applicant: BASF AG
Inventor: KNOLL KONRAD , GAUSEPOHL HERMANN , WARZELHAN VOLKER , SCHADE CHRISTIAN , FISCHER WOLFGANG
IPC: C08F4/46 , C08F4/50 , C08F297/04
Abstract: In a process for the preparation of block copolymers from vinylaromatic monomers and dienes, the monomers are polymerized in the presence of at least one alkali metal organyl or alkali metal alkoxide and at least one magnesium, aluminum or zinc organyl.
-
-
-
-
-
-
-
-
-