公开(公告)号：CA2276463A1

公开(公告)日：1998-07-09

申请号：CA2276463

申请日：1997-12-19

Applicant: BASF AG

Inventor： MAYER GUIDO ,  BAUMANN ERNST ,  OTTEN MARTINA ,  VON DEYN WOLFGANG ,  WESTPHALEN KARL-OTTO ,  WALTER HELMUT ,  GOETZ NORBERT ,  RHEINHEIMER JOACHIM ,  HILL REGINA LUISE ,  KARDORFF UWE ,  RACK MICHAEL ,  WITSCHEL MATTHIAS ,  ENGEL STEFAN ,  MISSLITZ ULF

IPC: C07D231/20 ,  A01N20060101 ,  A01N43/56 ,  C07D20060101 ,  C07D231/14 ,  C07D231/22 ,  C07D231/24 ,  C07D409/10 ,  C07D409/12

Abstract: The invention concerns 4-benzoyl-pyrazoles of formula (I), in which the variables have the following meanings: R1, R2 stand for hydrogen, nitro, halogen, cyano, rhodano, alkyl, halogen alkyl, alkoxyalkyl, alkenyl, alkinyl, OR5, -OCOR6, -OSO2R6, -SH, -S(O)nR7, -SO2OR5, -SO2NR5R8, -NR8SO2R6 or NR8COR6; R3 stands for hydrogen, cyano, alkyl, halogen alkyl, -OR7, -SR7 or NR7R10; R4 stands for hydrogen, optionally substituted alkyl, cycloalkyl, alkenyl, cycloalkenyl, alkinyl, -COR9, -CO2R9, -COSR9 or -CONR8R9; X stands for oxygen or NR8; n equals 0, 1 or 2; R5 stands for hydrogen, alkyl, halogen alkyl, alkoxyalkyl, alkenyl or alkinyl; R6 stands for alkyl or halogen alkyl; R7 stands for alkyl, halogen alkyl, alkoxyalkyl, alkenyl or alkinyl; R8 stands for hydrogen or alkyl; R9 stands for alkyl, alkenyl, alkinyl, phenyl or benzyl; R10 stands for alkyl, halogen alkyl, alkenyl or alkinyl; Q stands for optionally substituted pyrazol linked in position 4. Also disclosed are the salts of these compounds useful in agriculture; processes and intermediate products for preparing the compounds of formula (I), agents containing the same and the use of these derivatives or agents containing the same for controlling undesirable plants.

公开(公告)号：AU4621997A

公开(公告)日：1998-04-14

申请号：AU4621997

申请日：1997-09-09

Applicant: BASF AG

Inventor： BAUMANN ERNST ,  ZAGAR CYRILL ,  KARDORFF UWE ,  MISSLITZ ULF ,  WESTPHALEN KARL-OTTO ,  WALTER HELMUT ,  HAMPRECHT GERHARD

IPC: C07D403/12 ,  A01N47/38 ,  C07D401/12 ,  C07D405/12 ,  C07D409/12 ,  C07D411/12 ,  C07D413/12 ,  C07D417/12 ,  C07D419/12

Abstract: Substituted carbamoyltriazoles of the formula I as defined in the specification and the agriculturally useful salts thereof, processes for their preparation and their use as herbicides.

公开(公告)号：NZ265624A

公开(公告)日：1997-12-19

申请号：NZ26562494

申请日：1994-04-14

Applicant: BASF AG

Inventor： BAUMANN ERNST ,  RHEINHEIMER JOACHIM ,  VOGELBACHER UWE JOSEF ,  BRATZ MATTHIAS ,  MEYER NORBERT ,  GERBER MATTHIAS ,  WESTPHALEN KARL-OTTO ,  WALTER HELMUT ,  RADEMACHER WILHELM

IPC: C07D251/34 ,  A01N43/54 ,  A01N43/60 ,  A01N43/66 ,  A01P13/00 ,  C07C69/22 ,  C07C69/712 ,  C07C69/734 ,  C07D239/26 ,  C07D239/30 ,  C07D239/34 ,  C07D239/38 ,  C07D239/52 ,  C07D239/60 ,  C07D251/30 ,  C07D307/46 ,  C07D307/54 ,  C07D333/24 ,  C07D405/12 ,  C07D409/12 ,  C07D491/048

Abstract: PCT No. PCT/EP94/01156 Sec. 371 Date Oct. 19, 1995 Sec. 102(e) Date Oct. 19, 1995 PCT Filed Apr. 14, 1994 PCT Pub. No. WO94/25443 PCT Pub. Date Nov. 10, 19943-(Het)aryloxy(thio)carboxylic acid derivatives of the formula I I where R1 is hydrogen, COOH or a radical which can be hydrolyzed to give COOH; R2 and R3 are each halogen, alkyl, haloalkyl, alkoxy, haloalkoxy or alkylthio; X is nitrogen or CR14, where R14 is hydrogen or, together with R3, forms a 3-membered or 4-membered alkylene or alkenylene chain, in each of which a methylene group is replaced by oxygen; R4 is alkyl, cycloalkyl, cycloalkenyl, alkenyl or alkynyl, each of which is unsubstituted or substituted; an unsubstituted or substituted five-membered or six-membered heteroaromatic structure containing one to three nitrogen atoms or one sulfur or oxygen atom; unsubstituted or substituted phenyl or naphthyl; R4 and R5, together with the neighboring carbon atom, form a 3-membered to 8-membered ring which may contain an oxygen or sulfur atom and which is unsubstituted or substituted; R5 is hydrogen, alkyl, alkenyl, alkynyl, cycloalkyl, haloalkyl, alkoxyalkyl, alkylthioalkyl or phenyl, each of which is unsubstituted or substituted; R6 is unsubstituted or substituted phenyl or naphthyl or an unsubstituted or substituted five-membered or six-membered heteroaromatic structure containing one to three nitrogen atoms or one sulfur or oxygen atom; Y is sulfur or oxygen or a single bond; and Z is sulfur or oxygen.

公开(公告)号：BR9509338A

公开(公告)日：1997-11-04

申请号：BR9509338

申请日：1995-10-07

Applicant: BASF AG

Inventor： RIECHERS HARTMUT ,  KLINGE DAGMAR ,  AMBERG WILHELM ,  KLING ANDREAS ,  MULLER STEFAN ,  RHEINHEIMER JOACHIM ,  BAUMANN ERNST ,  VOGELBACHER UWE JOSEF ,  WERNER WOLFGANG ,  UNGER LILIANE ,  RASCHACK MANFRED

IPC: C07D251/30 ,  A61K31/505 ,  A61P9/00 ,  A61P9/08 ,  A61P9/10 ,  A61P9/12 ,  A61P11/08 ,  A61P13/02 ,  A61P15/00 ,  A61P25/04 ,  C07D239/00 ,  C07D239/26 ,  C07D239/28 ,  C07D239/34 ,  C07D239/38 ,  C07D239/60 ,  C07D239/70 ,  C07D239/96 ,  C07D251/12 ,  C07D251/52 ,  C07D257/02 ,  C07D309/00 ,  C07D403/06 ,  C07D403/12 ,  C07D405/12 ,  C07D417/12 ,  C07D487/04 ,  C07D491/04 ,  C07D491/044 ,  C07D491/048

Abstract: Heterocyclyl-substd. propanoic acids and their derivs., of formula (I), are new. R = formyl, tetrazolyl, nitrile, COOH or a gp. that can be hydrolysed to COOH; X = N or CR14; R2 = H, OH, NH2, alkylamino, dialkylamino, halo, alkyl, haloalkyl, alkoxy, haloalkoxy or alkylthio; R14 = H or 1-5 C alkyl; R3 = R2 or alkoxyimino; or CR3 + CR14 = 5 or 6 membered alkylene or alkenyl ring (opt. substd. by 1-2 alkyl) in which a methylene can be replaced by O, S, NH or alkylamino; R4, R5 = phenyl or naphthyl (both opt. substd. by one or more halo, NO2, CN, OH, alkyl, haloalkyl, alkoxy, haloalkyloxy, phenoxy, alkylthio, NH2, alkylamine or dialkylamino) or 3-7 C cycloalkyl; or the phenyl or naphthyl gps. are opt. bonded at the O- position (by a bond, CH2, O, S, SO2, ethylene, ethenylene or opt. alkylated amino); R6 = H, 1-8 C alkyl, 2-6 C alkenyl, 3-6 C alkynyl, 3-8 C cycloalkyl (all opt. substd. by 1 or more halo, NO2, CN, alkoxy 3-6 C alkenyloxy, 3-6 C alkynyloxy, alkylthio, haloalkoxy, alkylcarbonyl, alkoxycarbonyl, 3-8 C alkylcarbonylalkyl, alkylamino, dialkylamino, phenyl, Ph or OPh), Ar or Het; Y = S, O or bond; Q = S, O, SO, SO2 or bond; Ph = substd. phenyl, where substits. are halo, NO2, CN, alkyl, haloalkyl, alkoxy, haloalkoxy or alkylthio; Ar = phenyl or naphthyl (both opt. substd. by 1 or more halo, NO2, CN, OH, NH2, alkylamino, dialkylamino or OCH2CH2O); Het = 5 or 6 membered heteroaromatic with 1-3 N atoms and/or one S or O (opt. substd. by 1-4 halo and/or 1 or 2 alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, phenyl, phenoxy or phenyl carbonyl (where the phenyl is opt. substd. by 1-5 halo and/or 1-3 alkyl, haloalkyl, alkoxy, haloalkoxy and/or alkylthio)); alkyl and alkoxy have 1-4 C unless otherwise stated; provided that R6 is not H when Q = bond.

公开(公告)号：HRP950517A2

公开(公告)日：1997-10-31

申请号：HRP950517

申请日：1995-10-13

Applicant: BASF AG

Inventor： RIECHERS HARTMUT ,  KLINGE DAGMAR ,  ALBERG WILHELM ,  KLING ANDREAS ,  MUELLER STEFAN ,  BAUMANN ERNST ,  RHEINHEIMER JOACHIM ,  VOGELBACHER UWE JOSEF ,  WERNET WOLFGANG ,  UNGER LILIANE ,  RASCHACK MANFRED

IPC: C07D251/30 ,  A61K31/505 ,  A61P9/00 ,  A61P9/08 ,  A61P9/10 ,  A61P9/12 ,  A61P11/08 ,  A61P13/02 ,  A61P15/00 ,  A61P25/04 ,  C07D239/00 ,  C07D239/26 ,  C07D239/28 ,  C07D239/34 ,  C07D239/38 ,  C07D239/60 ,  C07D239/70 ,  C07D239/96 ,  C07D251/12 ,  C07D251/52 ,  C07D257/02 ,  C07D309/00 ,  C07D403/06 ,  C07D403/12 ,  C07D405/12 ,  C07D417/12 ,  C07D487/04 ,  C07D491/04 ,  C07D491/044 ,  C07D491/048

Abstract: Heterocyclyl-substd. propanoic acids and their derivs., of formula (I), are new. R = formyl, tetrazolyl, nitrile, COOH or a gp. that can be hydrolysed to COOH; X = N or CR14; R2 = H, OH, NH2, alkylamino, dialkylamino, halo, alkyl, haloalkyl, alkoxy, haloalkoxy or alkylthio; R14 = H or 1-5 C alkyl; R3 = R2 or alkoxyimino; or CR3 + CR14 = 5 or 6 membered alkylene or alkenyl ring (opt. substd. by 1-2 alkyl) in which a methylene can be replaced by O, S, NH or alkylamino; R4, R5 = phenyl or naphthyl (both opt. substd. by one or more halo, NO2, CN, OH, alkyl, haloalkyl, alkoxy, haloalkyloxy, phenoxy, alkylthio, NH2, alkylamine or dialkylamino) or 3-7 C cycloalkyl; or the phenyl or naphthyl gps. are opt. bonded at the O- position (by a bond, CH2, O, S, SO2, ethylene, ethenylene or opt. alkylated amino); R6 = H, 1-8 C alkyl, 2-6 C alkenyl, 3-6 C alkynyl, 3-8 C cycloalkyl (all opt. substd. by 1 or more halo, NO2, CN, alkoxy 3-6 C alkenyloxy, 3-6 C alkynyloxy, alkylthio, haloalkoxy, alkylcarbonyl, alkoxycarbonyl, 3-8 C alkylcarbonylalkyl, alkylamino, dialkylamino, phenyl, Ph or OPh), Ar or Het; Y = S, O or bond; Q = S, O, SO, SO2 or bond; Ph = substd. phenyl, where substits. are halo, NO2, CN, alkyl, haloalkyl, alkoxy, haloalkoxy or alkylthio; Ar = phenyl or naphthyl (both opt. substd. by 1 or more halo, NO2, CN, OH, NH2, alkylamino, dialkylamino or OCH2CH2O); Het = 5 or 6 membered heteroaromatic with 1-3 N atoms and/or one S or O (opt. substd. by 1-4 halo and/or 1 or 2 alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, phenyl, phenoxy or phenyl carbonyl (where the phenyl is opt. substd. by 1-5 halo and/or 1-3 alkyl, haloalkyl, alkoxy, haloalkoxy and/or alkylthio)); alkyl and alkoxy have 1-4 C unless otherwise stated; provided that R6 is not H when Q = bond.

公开(公告)号：BR9507231A

公开(公告)日：1997-09-16

申请号：BR9507231

申请日：1995-03-23

Applicant: BASF AG

Inventor： BAUMANN ERNST ,  VOGELBACHER UWE JOSEF ,  RHEINHEIMER JOACHIM ,  KLINGE DAGMAR ,  REICHERS HARTMUT ,  KROGER BURKHARD ,  BIALOJAN SIEGFRIED ,  BOLLSCHWEILER CLAUS ,  WERNET WOLFGANG ,  UNGER LILIANE ,  RASCHACK MANFRED

IPC: C07D251/26 ,  A61K31/00 ,  A61K31/505 ,  A61K31/506 ,  A61K31/53 ,  A61P9/00 ,  A61P9/08 ,  A61P9/10 ,  A61P9/12 ,  A61P11/08 ,  A61P13/02 ,  A61P15/00 ,  A61P25/04 ,  A61P39/02 ,  C07D239/26 ,  C07D239/34 ,  C07D239/38 ,  C07D401/12 ,  C07D405/12 ,  C07D409/12 ,  C07D413/12 ,  C07D417/12

Abstract: PCT No. PCT/EP95/01099 Sec. 371 Date Sep. 30, 1996 Sec. 102(e) Date Sep. 30, 1996 PCT Filed Mar. 23, 1995 PCT Pub. No. WO95/26716 PCT Pub. Date Oct. 12, 1995A method of inhibiting endothelin receptors by administering to a patient a compound of the formula I I

公开(公告)号：AT156822T

公开(公告)日：1997-08-15

申请号：AT94913587

申请日：1994-04-13

Applicant: BASF AG

Inventor： BAUMANN ERNST ,  HARREUS ALBRECHT ,  BRATZ MATTHIAS ,  RHEINHEIMER JOACHIM ,  VOGELBACHER UWE JOSEF ,  THEOBALD HANS ,  GERBER MATTHIAS ,  WALTER HELMUT ,  WESTPHALEN KARL-OTTO ,  RADEMACHER WILHELM

IPC: C07D233/64 ,  A01N43/50 ,  A01N43/54 ,  A01N43/56 ,  A01N43/653 ,  A01N43/66 ,  A01N43/713 ,  A01N43/76 ,  A01N43/80 ,  A01P13/00 ,  C07D207/333 ,  C07D207/335 ,  C07D213/55 ,  C07D231/12 ,  C07D239/34 ,  C07D239/38 ,  C07D239/56 ,  C07D239/60 ,  C07D261/08 ,  C07D263/32 ,  C07D275/02 ,  C07D277/14 ,  C07D307/28 ,  C07D333/16 ,  C07D333/24 ,  C07D333/28 ,  C07D401/12 ,  C07D403/12 ,  C07D405/12 ,  C07D409/12 ,  C07D413/12 ,  C07D417/12 ,  C07D491/04 ,  C07D491/048

Abstract: PCT No. PCT/EP94/01140 Sec. 371 Date Dec. 1, 1995 Sec. 102(e) Date Dec. 1, 1995 PCT Filed Apr. 13, 1994 PCT Pub. No. WO94/25455 PCT Pub. Date Nov. 10, 19943-Halo-3-hetarylcarboxylic acid derivatives having the formula I I in which R is a formyl group, a group CO2H or a radical which can be hydrolyzed to COOH, and the remaining substituents have the following meanings: R2 and R3 are halogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-haloalkoxy or C1-C4-alkylthio; X is nitrogen or CR13, where R13 is hydrogen or together with R3 forms an alkylene or alkenylene chain in which in each case one methylene group is replaced by oxygen; R4 is an unsubstituted or substituted five- or six-membered heteroaromatic ring which contains one to three nitrogen atoms and/or one sulfur or oxygen atom; R5 is hydrogen, substituted or unsubstituted alkyl, alkenyl, alkynyl, cycloalkyl or phenyl; Y is sulfur, oxygen or a single bond; and Z is halogen. The derivatives I having herbicidal and plant-growth regulating properties.

公开(公告)号：NZ265275A

公开(公告)日：1997-07-27

申请号：NZ26527594

申请日：1994-04-13

Applicant: BASF AG

Inventor： BAUMANN ERNST ,  RHEINHEIMER JOACHIM ,  VOGELBACHER UWE JOSEF ,  BRATZ MATTHIAS ,  THEOBALD HANS ,  GERBER MATTHIAS ,  WESTPHALEN KARL-OTTO ,  WALTER HELMUT ,  RADEMACHER WILHELM

IPC: A01N43/54 ,  A01N43/64 ,  A01N43/66 ,  A01N43/72 ,  A01P13/00 ,  A01P21/00 ,  C07C45/58 ,  C07C47/198 ,  C07C47/277 ,  C07C59/125 ,  C07C67/31 ,  C07C69/708 ,  C07D251/22 ,  C07C69/734 ,  C07C205/28 ,  C07C323/22 ,  C07C323/50 ,  C07D239/26 ,  C07D239/30 ,  C07D239/34 ,  C07D239/38 ,  C07D239/60 ,  C07D251/24 ,  C07D251/30 ,  C07D251/34 ,  C07D401/12 ,  C07D403/12 ,  C07D405/12 ,  C07D409/12 ,  C07D411/12 ,  C07D413/12 ,  C07D477/12 ,  C07D491/048 ,  C07D417/12 ,  C07C69/66 ,  C07C309/65 ,  C07C309/73

Abstract: PCT No. PCT/EP94/01141 Sec. 371 Date Oct. 19, 1995 Sec. 102(e) Date Oct. 19, 1995 PCT Filed Apr. 13, 1994 PCT Pub. No. WO94/25442 PCT Pub. Date Nov. 10, 19943-(Het)arylcarboxylic acid derivatives of the formula I I where R is formyl, CO2H or a radical hydrolyzable to COOH and the other substituents have the following meanings: R2 and R3 are each halogen, alkyl, haloalkyl, alkoxy, haloalkoxy or alkylthio; X is nitrogen or CR14, where R14 is hydrogen or, together with R3, forms an alkylene or alkenylene chain, in each of which a methylene group is replaced by oxygen; R4 is phenyl or naphthyl, each of which is unsubstituted or substituted or an unsubstituted or substituted five-membered or six-membered heteroaromatic structure containing one to three nitrogen atoms or one sulfur or oxygen atom; R5 is hydrogen, alkyl, alkenyl, alkynyl, cycloalkyl, haloalkyl, alkoxyalkyl, alkylthioalkyl or phenyl; R6 is C1-C8-alkyl, C3-C6-alkenyl, C3-C6-alkynyl or C3-C4-cyclo-alkyl, each of which may be mono- or polysubstituted; Y is sulfur, oxygen or a single bond; and Z is sulfur or oxygen; with the proviso that R6 is not unsubstituted C1-C4-alkyl when R4 is unsubstituted phenyl, Z is oxygen and simultaneously R5 is methyl or hydrogen.

公开(公告)号：AU678236B2

公开(公告)日：1997-05-22

申请号：AU6568194

申请日：1994-04-13

Applicant: BASF AG

Inventor： BAUMANN ERNST ,  RHEINHEIMER JOACHIM ,  VOGELBACHER UWE JOSEF ,  BRATZ MATTHIAS ,  THEOBALD HANS ,  GERBER MATTHIAS ,  WESTPHALEN KARL-OTTO ,  WALTER HELMUT ,  RADEMACHER WILHELM

IPC: C07D251/22 ,  A01N43/54 ,  A01N43/64 ,  A01N43/66 ,  A01N43/72 ,  A01P13/00 ,  A01P21/00 ,  C07C45/58 ,  C07C47/198 ,  C07C47/277 ,  C07C59/125 ,  C07C67/31 ,  C07C69/708 ,  C07C69/734 ,  C07C205/28 ,  C07C323/22 ,  C07C323/50 ,  C07D239/26 ,  C07D239/30 ,  C07D239/34 ,  C07D239/38 ,  C07D239/60 ,  C07D251/24 ,  C07D251/30 ,  C07D251/34 ,  C07D401/12 ,  C07D403/12 ,  C07D405/12 ,  C07D409/12 ,  C07D411/12 ,  C07D413/12 ,  C07D477/12 ,  C07D491/048 ,  C07D213/55 ,  C07D231/12 ,  C07D233/64 ,  C07D275/02 ,  C07D277/30 ,  C07D333/48 ,  C07D307/54 ,  C07D417/12 ,  C07C205/56

Abstract: PCT No. PCT/EP94/01141 Sec. 371 Date Oct. 19, 1995 Sec. 102(e) Date Oct. 19, 1995 PCT Filed Apr. 13, 1994 PCT Pub. No. WO94/25442 PCT Pub. Date Nov. 10, 19943-(Het)arylcarboxylic acid derivatives of the formula I I where R is formyl, CO2H or a radical hydrolyzable to COOH and the other substituents have the following meanings: R2 and R3 are each halogen, alkyl, haloalkyl, alkoxy, haloalkoxy or alkylthio; X is nitrogen or CR14, where R14 is hydrogen or, together with R3, forms an alkylene or alkenylene chain, in each of which a methylene group is replaced by oxygen; R4 is phenyl or naphthyl, each of which is unsubstituted or substituted or an unsubstituted or substituted five-membered or six-membered heteroaromatic structure containing one to three nitrogen atoms or one sulfur or oxygen atom; R5 is hydrogen, alkyl, alkenyl, alkynyl, cycloalkyl, haloalkyl, alkoxyalkyl, alkylthioalkyl or phenyl; R6 is C1-C8-alkyl, C3-C6-alkenyl, C3-C6-alkynyl or C3-C4-cyclo-alkyl, each of which may be mono- or polysubstituted; Y is sulfur, oxygen or a single bond; and Z is sulfur or oxygen; with the proviso that R6 is not unsubstituted C1-C4-alkyl when R4 is unsubstituted phenyl, Z is oxygen and simultaneously R5 is methyl or hydrogen.

公开(公告)号：NO971675D0

公开(公告)日：1997-04-11

申请号：NO971675

申请日：1997-04-11

Applicant: BASF AG

Inventor： RIECHERS HARTMUT ,  KLINGE DAGMAR ,  AMBERG WILHELM ,  KLING ANDREAS ,  MUELLER STEFAN ,  BAUMANN ERNST ,  RHEINHEIMER JOACHIM ,  VOGELBACHER UWE JOSEF ,  WERNET WOLFGANG ,  UNGER LILIANE ,  RASCHACK MANFRED

IPC: C07D251/30 ,  A61K31/505 ,  A61P9/00 ,  A61P9/08 ,  A61P9/10 ,  A61P9/12 ,  A61P11/08 ,  A61P13/02 ,  A61P15/00 ,  A61P25/04 ,  C07D239/00 ,  C07D239/26 ,  C07D239/28 ,  C07D239/34 ,  C07D239/38 ,  C07D239/60 ,  C07D239/70 ,  C07D239/96 ,  C07D251/12 ,  C07D251/52 ,  C07D257/02 ,  C07D309/00 ,  C07D403/06 ,  C07D403/12 ,  C07D405/12 ,  C07D417/12 ,  C07D487/04 ,  C07D491/04 ,  C07D491/044 ,  C07D491/048

Abstract: Heterocyclyl-substd. propanoic acids and their derivs., of formula (I), are new. R = formyl, tetrazolyl, nitrile, COOH or a gp. that can be hydrolysed to COOH; X = N or CR14; R2 = H, OH, NH2, alkylamino, dialkylamino, halo, alkyl, haloalkyl, alkoxy, haloalkoxy or alkylthio; R14 = H or 1-5 C alkyl; R3 = R2 or alkoxyimino; or CR3 + CR14 = 5 or 6 membered alkylene or alkenyl ring (opt. substd. by 1-2 alkyl) in which a methylene can be replaced by O, S, NH or alkylamino; R4, R5 = phenyl or naphthyl (both opt. substd. by one or more halo, NO2, CN, OH, alkyl, haloalkyl, alkoxy, haloalkyloxy, phenoxy, alkylthio, NH2, alkylamine or dialkylamino) or 3-7 C cycloalkyl; or the phenyl or naphthyl gps. are opt. bonded at the O- position (by a bond, CH2, O, S, SO2, ethylene, ethenylene or opt. alkylated amino); R6 = H, 1-8 C alkyl, 2-6 C alkenyl, 3-6 C alkynyl, 3-8 C cycloalkyl (all opt. substd. by 1 or more halo, NO2, CN, alkoxy 3-6 C alkenyloxy, 3-6 C alkynyloxy, alkylthio, haloalkoxy, alkylcarbonyl, alkoxycarbonyl, 3-8 C alkylcarbonylalkyl, alkylamino, dialkylamino, phenyl, Ph or OPh), Ar or Het; Y = S, O or bond; Q = S, O, SO, SO2 or bond; Ph = substd. phenyl, where substits. are halo, NO2, CN, alkyl, haloalkyl, alkoxy, haloalkoxy or alkylthio; Ar = phenyl or naphthyl (both opt. substd. by 1 or more halo, NO2, CN, OH, NH2, alkylamino, dialkylamino or OCH2CH2O); Het = 5 or 6 membered heteroaromatic with 1-3 N atoms and/or one S or O (opt. substd. by 1-4 halo and/or 1 or 2 alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, phenyl, phenoxy or phenyl carbonyl (where the phenyl is opt. substd. by 1-5 halo and/or 1-3 alkyl, haloalkyl, alkoxy, haloalkoxy and/or alkylthio)); alkyl and alkoxy have 1-4 C unless otherwise stated; provided that R6 is not H when Q = bond.