Use of graft polymers for stuffing and fulling leathers and fur pelts

    公开(公告)号:AU662071B2

    公开(公告)日:1995-08-17

    申请号:AU4567993

    申请日:1993-07-13

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP93/01831 Sec. 371 Date Mar. 3, 1994 Sec. 102(e) Date Mar. 3, 1994 PCT Filed Jul. 13, 1993 PCT Pub. No. WO94/02650 PCT Pub. Date Feb. 3, 1994Soft leathers with a pleasant hand are obtained on fatliquoring and filling leather and fur skins with water-soluble or water-dispersible graft polymers of vegetable and animal oils, obtainable by radically initiated polymerization A) of a monomer or monomer mixture comprising (a) from 20 to 100% by weight of monoethylenically unsaturated carboxylic acids and/or monoethylenically unsaturated sulfonic acids and/or monoethylenically unsaturated phosphonic acids or their alkali metal, alkaline earth metal or ammonium salts, (b) from 0 to 80% by weight of other monoethylenically unsaturated monomers which are copolymerizable with the monomers (a), and (c) from 0 to 5% by weight of at least doubly ethylenically unconjugatedly unsaturated monomers in the presence of B) vegetable and/or animal oils in a weight ratio of A:B of (80-1):(20-99).

    Aqueous solutions or dispersions of copolymers

    公开(公告)号:AU1534295A

    公开(公告)日:1995-08-08

    申请号:AU1534295

    申请日:1995-01-16

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP95/00144 Sec. 371 Date Jul. 25, 1996 Sec. 102(e) Date Jul. 25, 1996 PCT Filed Jan. 16, 1995 PCT Pub. No. WO95/20056 PCT Pub. Date Jul. 27, 1995Aqueous solution or aqueous dispersion of copolymers suitable for the fatliquoring and filling of leather and fur skins are obtained by free-radical copolymerization of A1) C6-C40-monoolefins or C6-C40-alkyl vinyl ethers or mixtures thereof with B1) monoethylenically unsaturated C4-C8-dicarboxylic anhydrides or by free-radical copolymerization of A2) C6-C40-alkyl acrylates or methacrylates or vinyl esters of C6-C40-carboxylic acids or mixtures thereof with B2) monoethylenically unsaturated C3-C12-carboxylic acids, monoethylenically unsaturated C4-C12-dicarboxylic anhydrides, monoesters or monoamides of monoethylenically unsaturated C4-C12-dicarboxylic acids, amides of monoethylenically unsaturated C3-C12-carboxylic acids or mixtures thereof to give copolymers with molecular weights of 500 to 30,000, where the carboxyl groups which are present in aqueous medium are at least partially neutralized, and some of the carboxylic groups can be in amidated form, containing 0.5-40% by weight, based on the amount of copolymer, of defined emulsifiers.

    WATER-SOLUBLE COPOLYMERS AND THEIR PREPARATION

    公开(公告)号:CA1334041C

    公开(公告)日:1995-01-17

    申请号:CA563541

    申请日:1988-04-07

    Applicant: BASF AG

    Abstract: Water-soluble copolymers having a K value of from 15 to 120 (determined according to H. Fikentscher in an aqueous solution of their sodium salt at 25.degree.C, a pH of 7 and a polymer concentration of the Na salt of 1% by weight) contain, in polymerized form, a) not less than 80 mol % of one or more monoethylenically unsaturated C3-C6-monocarboxylic acids, b) from 0.5 to 20 mol % of a comonomer which possesses two or more ethylenically unsaturated, non-conjugated double bonds and one or more -CO-OX groups and/or their salt with an alkali metal, ammonium or alkaline earth metal base, and, if required, c) not more than 10 mol % of one or more comonomers which differ from b) and possess two or more ethylenically unsaturated, non-conjugated double bonds, and the said copolymers are prepared by copolymerization of the monomers a), b) and, if required, c) in aqueous solution and are used for coating seed.

    139.
    发明专利
    未知

    公开(公告)号:DK0486608T3

    公开(公告)日:1994-03-28

    申请号:DK90913137

    申请日:1990-08-06

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP90/01283 Sec. 371 Date Feb. 10, 1992 Sec. 102(e) Date Feb. 10, 1992 PCT Filed Aug. 6, 1990 PCT Pub. No. WO91/02094 PCT Pub. Date Feb. 21, 1991.Copolymers which are obtainable by free radical copolymerization of (a) C8-C40-alkyl vinyl ethers, if necessary as a mixture with not more than 50 mol % of C8-C40-monoolefins, with (b) ethylenically unsaturated C4-C8-dicarboxylic anhydrides at from 80 degrees to 300 degrees C. to give copolymers having molecular weights of from 500 to 20,000 g/mol, subsequent solvolysis of the anhydride groups of the copolymers and partial or complete neutralization of the carboxyl groups formed during the solvolysis, in an aqueous medium by means of a base, and which are present in the form of aqueous dispersions or solutions, are used as agents for imparting water repellency to leathers and skins.

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