12.
    发明专利
    未知

    公开(公告)号:ES2077739T3

    公开(公告)日:1995-12-01

    申请号:ES91112468

    申请日:1991-07-25

    Applicant: BASF AG

    Abstract: The present invention relates to substituted sulphonylureas of the formula I … … in which n and m are 0 or 1 and the substituents have the following meanings: …… R is hydrogen, alkyl, alkenyl or alkynyl; … R is halogen or trifluoromethyl when m is 0 or, in the event that m is 1, alkyl, alkenyl or alkynyl, and when X is O or S and m is 1, trifluoro- or chlorodifluoromethyl; … X is O, s or N-R , where R is hydrogen or alkyl; … R is hydrogen, halogen, alkyl, haloalkyl or alkoxy; … A is haloalkyl, a halogen atom, cyano, nitro, alkoxy, alkylthio, alkylsulphinyl, alkylsulphonyl or a radical … … in which … B is an oxygen atom or an alkylimino group N-R ; … R is hydrogen, an optionally substituted alkyl group, an optionally substituted cycloalkyl group, an alkenyl group or an alkynyl group; … R is hydrogen, an alkyl group, or, together with R , a C4-C6-alkylene chain in which a methylene group can be replaced by an oxygen atom or by a C1-C4-alkylimino group, … and their environmentally compatible salts. … Process and intermediates for the preparation of the compounds I, and their use as herbicides and bioregulators.

    14.
    发明专利
    未知

    公开(公告)号:AT127122T

    公开(公告)日:1995-09-15

    申请号:AT91109440

    申请日:1991-06-08

    Applicant: BASF AG

    Abstract: Dicarboxylic acid imides of the formulae Ia, Ib and Ic … … in which the substituents have the following meaning:… X is oxygen or sulphur;… R is hydrogen; halogen; cyano; alkyl; cycloalkyl; alkenyl; alkynyl; alkoxy; alkenyloxy; alkynyloxy; alkylthio; halogenoalkoxy; halogenoalkylthio; alkylsulphonyl; halogenoalkylsulphonyl; phenyl; phenylalkyl; phenoxy or phenylthio, a 5- to 6-membered saturated or aromatic heterocyclic radical containing one or two hetero atoms selected from the group comprising oxygen, sulphur and nitrogen; it being possible for the said organic radicals to be further substituted;… R is hydrogen; hydroxyl; alkoxy; alkyl; cycloalkyl; alkenyl; alkynyl; di-C1-C4-alkylamino; a 5- to 6-membered heterocyclic saturated or aromatic radical with one or two hetero atoms selected from the group comprising oxygen, sulphur or nitrogen; phenyl; naphthyl; it being possible for the said organic radicals to be further substituted,… and plant-compatible salts of the dicarboxylic acid imides I excepting 3-methylisoxazole-4,5-dicarboximide and thiazole-4,5-dicarboximides in which R is phenyl when R is methyl or 2-thiazolyl, and herbicidal compositions containing these compounds.

    Derivatives of 3-hydroxycarboxylic acids, their preparation and use

    公开(公告)号:DE4335950A1

    公开(公告)日:1995-04-27

    申请号:DE4335950

    申请日:1993-10-21

    Applicant: BASF AG

    Abstract: Derivatives of 3-hydroxycarboxylic acids of the formula I in which the substituents have the following meaning: R is a CHO group, a CO2H group or a radical which can be hydrolysed to give CO2H, R is halogen, alkyl, haloalkyl, alkoxy, haloalkoxy or alkylthio; X is nitrogen or CR , R being hydrogen or together with R forming a 3- to 4-membered alkylene or alkenylene chain in which one methylene group in each case is replaced by oxygen; R is halogen, alkyl, haloalkyl, alkoxy, haloalkoxy or alkylthio, or R is linked with R as indicated above to give a 5- or 6-membered ring; R is an optionally substituted alkyl, alkenyl or alkynyl group; a cycloalkyl or cycloalkenyl group which can contain an oxygen or sulphur atom and is optionally substituted; optionally substituted phenyl or naphthyl or an optionally substituted heteroaromatic; or R and R , together with the adjacent carbon atom, form a 3- to 8-membered ring which can contain an oxygen or sulphur atom and can carry 1 to 3 radicals; R is hydrogen, alkyl, alkenyl, alkynyl, alkylcarbonyl, alkoxycarbonyl, haloalkyl, cycloalkyl, alkoxyalkyl, alkylthioalkyl or optionally substituted phenyl, or R is linked with R as indicated above to give a ring; Y is sulphur, oxygen or a single bond; R is the radicals mentioned for R and additionally an amino group -NR R or a radical ... Original abstract incomplete.

    New cyclohexene-1,2-di:carboxylic acid derivs.

    公开(公告)号:DE4238001A1

    公开(公告)日:1994-07-21

    申请号:DE4238001

    申请日:1992-11-11

    Applicant: BASF AG

    Abstract: Substd. cyclohexene-1,2-dicarboxylic acid derivs. of formula (I), and their salts are new. Where T = CONR1R2 or CN; R1, R2 = H; R, 3-6C alkenyl, or 3-6C alkynyl, all opt. substd. by 1-3 halo, CN, NH2, SH, OH, OR, RSO, RSO2, RCO, COOH, ROCO, RNH, (R)2N, RNHCO, (R)2NCO, (RO)(HO)PO, (RO)2PO, or Ar); or Ar' when R1 is H or R, R2 may also be OH, RO, 3-6C alkenyloxy, 3-6C alkynyloxy, 3-7C cycloalkoxy 5-7 cycloalkenyloxy, 1-6C haloalkoxy, 3-6C halo alkenyloxy, 3-7C cycloalkyl-1-6C alkoxy, RCOO, 1-6C cyanoalkoxy, etc.; NR1R2 = a 3-8 membered non-aromatic heterocycle contg. 1-3N atoms and/or one O or S atom and opt. 1-2 CO gps., the ring being opt. substd. by 1-3R; Ar = phenyl or a 3-8 membered heterocycle (contg. 1-4 heteroatoms selected from 1-4N, 1O or 1S) both opt. substd. on every substitutable atom by OH, halo, CN, NO2, CF3, R or RO; Ar' as Ar except that the heterocycle contains 1-4 heteroatoms selected from 1-4N, 1-20 and 1-2S, and only C-atoms may be substd. R = 1-6C alkyl; R3 = H or R; R4 = H or halo; R5 = H, halo, NO2, CN or CF3; R6 = a 3-8 membered heterocycle (contg. 1-4 heteroatoms selected from 1-4N, 1-2O and 1-2S, and in which 1-2 CH2 gps. are opt. replaced by CO), opt. C-substd. by R, 2-6C alkenyl, 2-6C alkynyl, RO, RS, 3-6C alkenyloxy, 3-6C alkynyloxy, 3-6C alkenylthio, 3-6C alkynylthio, ROCO, NO2, NH2, halo, 1-4C alkylamino, di(1-4C)alkylamino, CN, 1-6C cyanoalkyl, 1-6C haloalkyl or 1-6C haloalkyloxy; ACN, ACOB, OR9, C(O)R10, C(S)R10, C(NR16)R10, A = straight chain 2-4C alkenylene or 2-4C alkynylene, both opt. substd. by 1-2 halo, CN, R, 1-6C haloalkyl, OH, RO, RCOO, ROCO or RCO; B = H, R, 3-6C alkenyl, 3-6C alkynyl, 1-6C haloalkyl, 3-7C cycloalkyl, OR17, SR17, phenyl (opt. substd. by 1-3R, 2-6C alkenyl, halo, CN, NO2, 1-6C haloalkyl, RO or ROCO), 1-6C alkoxy-1-6C alkyl, di(1-6C alkoxy)-1-6C alkyl, 1-6C alkylthio-1-6C alkyl or NR18R19; R17 = H, R, 3-6C alkenyl, 3-6C alkynyl, 3-6C cycloalkyl, 1-6C haloalkyl, 1-6C cyanoalkyl, 3-6C haloalkenyl, ROCO, 1-6C alkoxy(1-6C)alkyl, 1-6C alkoxycarbonyl (1-6C) alkyl, 1-6C alkoxyimino(1-6C)alkyl, or phenyl (opt. substd. by 1-3 R, 2-6C alkenyl, halo, CN, NO2, 1-6C haloalkyl, RO or ROCO); R18, R19 = H, R, 3-6C alkenyl, 3-6C alkynyl, 3-6C cycloalkyl, 1-6C haloalkyl, RCO, ROCO, 1-6C alkoxy (1-6C)alkyl, or phenyl (opt. substd. by 1-3R, 3-6C alkenyl, halo, CN, NO2, RO or ROCO); R9 = 1-6C cyanoalkyl RQ, 1-6C haloalkyl, 3-6C haloalkenyl, 3-6C alkynyl, 3-6C haloalkynyl, 1-6 alkoxycarbonyl-2-6C alkyl, ROQOCOQ, 1-6C alkoxyimino (1-6C)alkyl, or phenyl, phenyl-Q, 3-8 membered heterocyclyl or heterocyclyl-Q (where the heterocycles contain 1-4 heteroatoms, etc.; R10 = H, CN, R, 3-6C alkenyl, 3-6C alkynyl, 1-6C haloalkyl, 3-7C cycloalkyl, ROCO, ROCOQ, or phenyl (opt. substd. by 1-3 halo, CN, NO2, R, 3-6C alkenyl, 1-6C haloalkyl, RO or ROCO); R16 = H, R, 3-6C alkenyl, 3-6C alkynyl, 3-7C cycloalkyl, 1-6C haloalkyl, phenyl (opt. substd. by 1-3R, halo, CN, 2-6C alkenyl, NO2, 1-6C haloalkyl, 1-6C alkoxy, or ROCO), ROQ, OH, RO, 3-6C alkenyloxy, 3-6C alkynyloxy, 5-7C cycloalkoxy, 5-7C cycloalkenyloxy, etc.; R5+R6 = an opt. unsatd. 3-5 membered carbon chain which opt. contains 1-2O, S, N, CO or 1-6C alkoximino gps. and which is opt. substd. by 1-2 CN, NO2, NH2, halo, R, 1-6C haloalkyl, 2-6C alkenyl, 2-6C alkynyl, 1-6C cyanoalkyl, RCOQ, phenyl-Q or 3-8 membered heterocyclyl-1-6C alkyl, where the heterocycle is opt. unsatd. and contains 1-4 heteroatoms selected from 1-4N, 1-20 and 1-2S; provided that when T is CONR1R2 then R9 is not 3-6C alkynyl and R16 is not 1-6C alkoxy, and when T is CN then R9 is not 1-6C haloalkoxy.

    19.
    发明专利
    未知

    公开(公告)号:DE4238175A1

    公开(公告)日:1994-05-19

    申请号:DE4238175

    申请日:1992-11-12

    Applicant: BASF AG

    Abstract: Described are sulphonyl urea compounds of the general formula I in which R is a methyl or ethyl group; R is C1-C3 alkoxycarbonyl, a C1-C2 alkyl group with 1 to 5 fluorine atoms, methylsulphonyl, dimethylaminosulphonyl, thiomethyl, methylsulphoxide, methylsulphonyloxy, trifluoromethoxy, difluoromethoxy, difluorochloromethoxy, difluorochloromethyl or nitro; R is hydrogen, methyl, methoxy, ethoxy, fluorine, chlorine or thiomethyl; W is hydrogen or chlorine and Z is CH or N, plus salts of these compounds suitable for use in agriculture.

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