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公开(公告)号：DE102005057198A1
公开(公告)日：2007-06-06
申请号：DE102005057198
申请日：2005-11-29
Applicant: BASF AG
Inventor： ERNST MARTIN , HAHN THILO , MELDER JOHANN-PETER
IPC: C07C209/48 , B01J23/00 , C07B43/04
Abstract: Hydrogenation of oligonitrile with at least two nitrile groups in the presence of a catalyst, which is pre-treated by contacting with a compound A, before the hydrogenation process; where the compound A is e.g. alkaline metal carbonates, alkaline-earth metal carbonates, ammonium carbonate, alkaline metal hydrogencarbonate, alkaline-earth metal hydrogencarbonate, ammonium hydrogencarbonate and alkaline-earth metal oxycarbonate. Hydrogenation of oligonitrile with at least two nitrile groups in the presence of a catalyst, which is pre-treated by contacting with a compound A, before the hydrogenation process; where the compound A is alkaline metal carbonates, alkaline-earth metal carbonates, ammonium carbonate, alkaline metal hydrogencarbonate, alkaline-earth metal hydrogencarbonate, ammonium hydrogencarbonate, alkaline-earth metal oxycarbonate, alkaline metal carboxylate, alkaline-earth metal carboxylate, ammonium carboxylate, alkaline metal dihydrogen phosphate, alkaline-earth metal dihydrogen phosphates, alkaline metal hydrogen phosphates, alkaline-earth metal hydrogen phosphates, alkaline metal phosphates, alkaline-earth metal phosphates, ammonium phosphate, alkaline metal acetates, alkaline-earth metal acetates, ammonium acetate, alkaline metal formate, alkaline-earth metal formate, ammonium formate, alkaline metal oxalates, alkaline-earth metal oxalates or ammonium oxalate. Independent claims are also included for: (1) an oligo amine or amino nitrile, obtained from an oligo nitrile; (2) a catalyst comprising a metal from group VIII to X, which are pretreated with the compound A, where the cobalt or nickel catalyst is pre-treated with compound A excluding alkali metal carbonate or alkali metal hydrogen carbonate; and (3) a method for preparing the catalyst comprising treating a metal form group VIII to X with the compound.
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公开(公告)号：DE50304141D1
公开(公告)日：2006-08-17
申请号：DE50304141
申请日：2003-04-08
Applicant: BASF AG
Inventor： WINTERLING HELMUT , BENISCH CHRISTOPH , HAHN THILO
Abstract: A process for preparing a polyamide by reacting a mixture which comprises a monomer which has a nitrile group and has at least one other functional group capable of forming a carboxamide group, and comprises water, in the presence of titanium dioxide as catalyst, which comprises using titanium dioxide whose BET surface area, determined to the German standard DIN 66 131 volumetrically by the multipoint method, is in the range from 5 to 35 m2/g.
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公开(公告)号：DE102005003315A1
公开(公告)日：2006-08-03
申请号：DE102005003315
申请日：2005-01-24
Applicant: BASF AG
Inventor： ERNST MARTIN , HAHN THILO , WENZ KIRSTEN , HUGO RANDOLF , MELDER JOHANN-PETER
IPC: C07C209/48 , B01J23/86 , C07C211/51
Abstract: A process for preparing a xylylenediamine by heterogeneously catalyzed hydrogenation of a phthalonitrile, wherein the hydrogenation is carried out in the presence of a cobalt skeletal catalyst, of an alkali metal hydroxide and of an alcohol and/or ether as the solvent, at an absolute pressure in the range from 1 to 100 bar and a temperature in the range from 40 to 150° C.
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公开(公告)号：DE10217439A1
公开(公告)日：2003-10-30
申请号：DE10217439
申请日：2002-04-18
Applicant: BASF AG
Inventor： WINTERLING HELMUT , BENISCH CHRISTOPH , HAHN THILO
Abstract: A process for preparing a polyamide by reacting a mixture which comprises a monomer which has a nitrile group and has at least one other functional group capable of forming a carboxamide group, and comprises water, in the presence of titanium dioxide as catalyst, which comprises using titanium dioxide whose BET surface area, determined to the German standard DIN 66 131 volumetrically by the multipoint method, is in the range from 5 to 35 m2/g.
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公开(公告)号：CA2481456A1
公开(公告)日：2003-10-30
申请号：CA2481456
申请日：2003-04-08
Applicant: BASF AG
Inventor： HAHN THILO , BENISCH CHRISTOPH , WINTERLING HELMUT
Abstract: The invention relates to a method for producing a polyamide by converting a mixture containing a monomer that comprises a nitrile group and at least one additional functional group that is capable of forming a carboxamide group, in addition to water in the presence of titanium dioxide, which acts as the catalyst. Said method is characterised in that the titanium dioxide has a BE T surface area ranging between 5 and 35 m2/g, determined by means of a volumetric process according to a multipoint method, as per the German standard DIN 66 131.
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Patent Agency Ranking
公开(公告)号：DE102004009311A1
公开(公告)日：2005-09-08
申请号：DE102004009311
申请日：2004-02-26
Applicant: BASF AG
Inventor： KLAS KATRIN , HAHN THILO , HENKELMANN JOCHEM
Abstract: Process for preparing a propargyl alcohol of the formula I in which R 1 is a C 130 -alkyl, C 3-8 -cycloalkyl, C 2-20 -alkoxyalkyl, C 6-14 -aryl, C 7-20 -alkoxyarl, C 7-20 -aralkyl, C 7-20 -alkylaryl radical or H, by reacting a corresponding aldehyde of the formula R 1 -CHO with acetylene in the presence of ammonia and a catalytic amount of an alkali metal hydroxide, alkaline earth metal hydroxide or alkali metal alkoxide in the range from 0.6 to 10 mol % based on the aldehyde used, and also processes for preparing an allyl alcohol of the formulae II and III starting from the propargyl alcohol I prepared in accordance with the invention.
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公开(公告)号：DE10231945A1
公开(公告)日：2004-01-29
申请号：DE10231945
申请日：2002-07-15
Applicant: BASF AG
Inventor： GOEBBEL HANS-GEORG , KAIBEL GERD , MILLER CHRISTIAN , DOBLER WALTER , DIRNSTEINER THOMAS , HAHN THILO , BREUER KLAUS , AQUILA WERNER
Abstract: A process is described for preparing tetrahydrogeranylacetone in which pseudoionone, geranylacetone and/or dihydrogeranylacetone in a liquid phase, in which particles of a catalyst which is capable of preferentially hydrogenating carbon-carbon double bonds over carbon-oxygen double bonds are suspended, is conducted through a device which inhibits the transport of the catalyst particles in the presence of a hydrogen-containing gas.
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公开(公告)号：AU2003224047A1
公开(公告)日：2003-11-03
申请号：AU2003224047
申请日：2003-04-08
Applicant: BASF AG
Inventor： WINTERLING HELMUT , BENISCH CHRISTOPH , HAHN THILO
Abstract: A process for preparing a polyamide by reacting a mixture which comprises a monomer which has a nitrile group and has at least one other functional group capable of forming a carboxamide group, and comprises water, in the presence of titanium dioxide as catalyst, which comprises using titanium dioxide whose BET surface area, determined to the German standard DIN 66 131 volumetrically by the multipoint method, is in the range from 5 to 35 m2/g.
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公开(公告)号：DE502005002040D1
公开(公告)日：2008-01-03
申请号：DE502005002040
申请日：2005-02-08
Applicant: BASF AG
Inventor： DEININGER JUERGEN , DEMETER JUERGEN , HAHN THILO , KORY GAD , SOETJE OLIVER , ZEHNER PETER
Abstract: A continuous process for producing polyamides, their oligomers or mixtures thereof, if appropriate with further reaction products, comprises reaction of aminonitriles or dinitriles and diamines or mixtures thereof, if appropriate together with further polyamide-forming monomers and/or oligomers, with an aqueous medium composed of aqueous monomer and oligomer extracts obtained from polyamide production by extraction of the polymer with water in a reactor which has a vertical longitudinal axis and through which there is a flow substantially in the longitudinal direction wherein water and/or the aqueous medium are introduced into the reactor at two or more different locations along the vertical longitudinal axis, wherein the aqueous medium is introduced at one or more locations.
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公开(公告)号：BRPI0507662A
公开(公告)日：2007-07-17
申请号：BRPI0507662
申请日：2005-02-08
Applicant: BASF AG
Inventor： DEININGER JUERGEN , DEMETER JUERGEN , HAHN THILO , KORY GAD , SOETJE OLIVER S , ZEHNER PETER
Abstract: A continuous process for producing polyamides, their oligomers or mixtures thereof, if appropriate with further reaction products, comprises reaction of aminonitriles or dinitriles and diamines or mixtures thereof, if appropriate together with further polyamide-forming monomers and/or oligomers, with an aqueous medium composed of aqueous monomer and oligomer extracts obtained from polyamide production by extraction of the polymer with water in a reactor which has a vertical longitudinal axis and through which there is a flow substantially in the longitudinal direction wherein water and/or the aqueous medium are introduced into the reactor at two or more different locations along the vertical longitudinal axis, wherein the aqueous medium is introduced at one or more locations.
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