19.
    发明专利
    未知

    公开(公告)号:DE4007312C2

    公开(公告)日:2000-04-27

    申请号:DE4007312

    申请日:1990-03-08

    Applicant: BASF AG

    Abstract: N-vinylformamide is polymerized with or without other water-soluble monoethylenically unsaturated monomers and with or without water-insoluble monoethylenically unsaturated monomers in not less than 30% strength by weight aqueous monomer solutions in the presence of a polymerization initiator at not more than 150 degrees C. in a kneader by a method in which the polymerization is carried out to such an extent that the initially formed water-containing polymer gel disintegrates into fine particles and the finely divided polymer obtainable in this manner is hydrolyzed, preferably in the kneader, so that not less than 0.1 mol % of the N-vinylformamide units present in the polymer are converted into vinylamine units. The polymers obtainable in this manner dissolve readily in water. The aqueous solutions are used, for example, in papermaking and tertiary oil production.

    20.
    发明专利
    未知

    公开(公告)号:DE59506644D1

    公开(公告)日:1999-09-23

    申请号:DE59506644

    申请日:1995-03-11

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP95/00912 Sec. 371 Date Oct. 24, 1996 Sec. 102(e) Date Oct. 24, 1996 PCT Filed Mar. 3, 1995 PCT Pub. No. WO95/25759 PCT Pub. Date Sep. 28, 1995Graft polymers which contain N-vinyl units and in which the grafting base is a polymer which contains in each case at least 5% by weight of units of the formulae (I) (II) where R1 and R2 are each H or C1-C6-alkyl, monoethylenically unsaturated monomers are grafted onto the grafting base in a weight ratio of from 100:1 to 1:100, and which have K values of at least 7 (determined according to H. Fikentscher in 5% strength by weight aqueous solution at 25 DEG C. and pH 7), are prepared by polymerization of monoethylenically unsaturated monomers in the presence of polymers which in each case contain at least 5% by weight of units of the formulae I and/or II as the grafting base in a weight ratio of from 100:1 to 1:100, and are used as dispersants for pigments, as additives for detergents and cleaning agents, and strength agents for paper and as soil stabilizers and for fertilizer compaction.

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