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    MANUFACTURING OF 1,2-DICHLOROETHANE
    11.
    发明专利
    MANUFACTURING OF 1,2-DICHLOROETHANE 失效

    公开(公告)号：JP2001348347A

    公开(公告)日：2001-12-18

    申请号：JP2001013946

    申请日：2001-01-23

    Applicant: BASF AG

    Inventor： MEISSNER RUPRECHT ,  HESSE MICHAEL DR ,  WALSDORFF CHRISTIAN

    IPC: C07C17/02 ,  B01J23/72 ,  B01J27/122 ,  B01J35/02 ,  B01J37/00 ,  C07B61/00 ,  C07C17/156 ,  C07C19/045

    Abstract: PROBLEM TO BE SOLVED: To provide a method for oxychlorination of ethyene on a fixed bed catalyst in which the oxychlorination can be carried out without additional particles of an inert diluting material even at a high space velocity in a reactor. SOLUTION: This method is to produce 1,2-dichloroethane by the oxychlorination of ethene in the presence of a copper-containing fixed bed catalyst comprising a bed essentially consisting of catalyst particles comprising, at least partially, a support material impregnated with an active component and, if desired, a promoter and the method is characterized in that the catalyst bed comprises essentially no separate inert material for dilution.

    PRODUCTION OF AMINE
    13.
    发明专利
    PRODUCTION OF AMINE 失效

    公开(公告)号：JPH10130209A

    公开(公告)日：1998-05-19

    申请号：JP15828097

    申请日：1997-06-16

    Applicant: BASF AG

    Inventor： ELLER KARSTEN DR ,  KUMMER RUDOLF DR ,  HESSE MICHAEL DR

    IPC: B01J21/08 ,  B01J23/24 ,  B01J23/30 ,  B01J35/10 ,  C07B61/00 ,  C07C209/02 ,  C07C209/60 ,  C07C211/03 ,  C07C211/16 ,  C07C211/21 ,  C07C211/33 ,  C07C211/43

    Abstract: PROBLEM TO BE SOLVED: To simply obtain the subject compound by reacting ammonia or a primary or secondary amine with an olefin in the presence of a specific condition catalyst. SOLUTION: This amine of formula I (R -R are each H, a 1-20C alkyl, a 2-20C alkenyl, etc.) is obtained by reacting an olefin of formula II, such as isobutene, diisobutene or cyclopentene, with ammonia, a primary amine or secondary amine of formula III at 200-350 deg.C at a pressure of 100-300 bars in the presence of a heterogeneous catalyst. A catalyst suitable for the amination of the olefin is effectively one or more of the oxides of group IVB or VIB elements in the periodic table, especially advantageously 5-20wt.% of a heterogeneous catalyst containing 5-15wt.% of tungsten and 8-25wt.% of zirconium on a carrier. The reaction exhibits a high selectivity and a high yield. The catalyst is further simply and easily recycled.

    Verfahren zur Herstellung von Aminen aus Olefinen an Oxiden der Gruppen IVB, VIB oder deren Gemischen auf Trägern
    14.
    发明公开
    Verfahren zur Herstellung von Aminen aus Olefinen an Oxiden der Gruppen IVB, VIB oder deren Gemischen auf Trägern 失效
    一种用于从基IVB，VIB族的氧化物或它们的在载体上的混合物的烯烃制备胺的方法

    公开(公告)号：EP0814075A1

    公开(公告)日：1997-12-29

    申请号：EP97109361

    申请日：1997-06-10

    Applicant: BASF AG

    Inventor： ELLER KARSTEN DR ,  KUMMER RUDOLF DR ,  HESSE MICHAEL DR

    IPC: B01J21/08 ,  B01J23/24 ,  B01J23/30 ,  B01J35/10 ,  C07B61/00 ,  C07C209/02 ,  C07C209/60 ,  C07C211/03 ,  C07C211/16 ,  C07C211/21 ,  C07C211/33 ,  C07C211/43

    CPC classification number: C07C209/60 ,  B01J23/24 ,  Y02P20/582

    Abstract: Verfahren zur Herstellung von Aminen der allgemeinen Formel I in der R ,R ,R ,R ,R ,R : Wasserstoff, C1- bis C20-Alkyl, C2- bis C20-Alkenyl, C2- bis C20-Alkinyl, C3- bis C20-Cycloalkyl, C4- bis C20-Alkyl-cycloalkyl, C4- bis C20-Cycloalkyl-alkyl, Aryl, C7- bis C20-Alkylaryl oder C7- bis C20-Aralkyl, R und R : gemeinsam eine gesättigte oder ungesättigte C3- bis C9-Alkylendikette und; R oder R : C21- bis C200-Alkyl, C21- bis C200-Alkenyl oder gemeinsam eine C2- bis C12-Alkylendikette bedeuten, durch Umsetzung von Olefinen der allgemeinen Formel II in der R , R , R und R die oben genannten Bedeutungen haben, mit Ammoniak oder primären oder sekundären Aminen der allgemeinen Formel III in der R und R die oben genannten Bedeutungen haben, bei Temperaturen von 200 bis 350°C und einem Druck von 100 bis 300 bar in Gegenwart eines Heterogenkatalysators, indem man Oxide der Gruppen IVB, VIB oder deren Gemische auf Trägern als Heterogenkatalysatoren einsetzt.

    Abstract translation: 在通过在200-350度起反应用氨（NH 3）式（II）的烯烃或式伯或仲cardamines C中的制备式（I）的cardamines的（III）和从100到在非均相的存在300巴 催化剂，IVB族和/或VIB氧化物（S）上的支撑被用作催化剂。 [R <5> - [R <6> CH-CR <3> [R <4> -NR <3> [R <4>（I）R <5> - [R <6> C = CR <3> [R <4>（II ）H-NR <1> [R <2>（III）中，R <1-6> =氢（H），1-20烷基碳（C），C 2-20烯基，C 2-20炔基，3-20个 ç环烷基，C 4-20烷基 - 环烷基，C 4-20环烷基 - 烷基，芳基，C 7-20烷芳基或C 7-20芳烷基; 或R <1> [R <2> =一个（未）饱和的C 3-9亚烷基二链; 且R <3>或R <5> = 21-200Ç烷（烯）基或R <3> [R <5> = A C 12亚烷基二链。

    CATALYST AND METHOD FOR THE HYDRATION OF CARBONYL COMPOUNDS
    15.
    发明专利
    CATALYST AND METHOD FOR THE HYDRATION OF CARBONYL COMPOUNDS 未知

    公开(公告)号：MY150679A

    公开(公告)日：2014-02-28

    申请号：MYPI20040679

    申请日：2004-02-27

    Applicant: BASF AG

    Inventor： HUBER-DIRR SYLVIA DR ,  HESSE MICHAEL DR ,  HAUNERT ANDREA DR ,  JUNICKE HENRIK DR

    IPC: B01J23/70 ,  B01J23/83 ,  C07C29/149

    Abstract: A PROCESS FOR HYDROGENATING AN ORGANIC COMPOUND WHICH HAS AT LEAST ONE CARBONYL GROUP, IN WHICH THE ORGANIC COMPOUND IS BROUGHT INTO CONTACT IN THE PRESENCE OF HYDROGEN WITH A SHAPED ARTICLE WHICH CAN BE PRODUCED IN A PROCESS IN WHICH (i) AN OXIDIC MATERIAL COMPRISING COPPER OXIDE, ALUMINUM OXIDE AND AT LEAST ONE OF THE OXIDES OF LANTHANUM, TUNGSTEN, MOLYBDENUM, TITANIUM OR ZIRCONIUM IS PREPARED, (ii) POWDERED METALLIC COPPER, COPPER FLAKES, POWDERED CEMENT, GRAPHITE OR A MIXTURE THEREOF IS ADDED TO THE OXIDIC MATERIAL, AND (iii) THE MIXTURE RESULTING FROM (ii) IS SHAPED TO A SHAPED ARTICLE.

    20.
    发明专利
    未知

    公开(公告)号：DE19803368A1

    公开(公告)日：1999-08-05

    申请号：DE19803368

    申请日：1998-01-29

    Applicant: BASF AG

    Inventor： GROENING CARSTEN DR ,  HESSE MICHAEL DR ,  HEINEKE DANIEL DR ,  KNEUPER HEINZ-JOSEF DR ,  FRITZ GERHARD DR

    IPC: B01J23/89 ,  B01J27/043 ,  B01J27/045 ,  C07D307/28 ,  C07D309/18 ,  C07D507/02 ,  C07D315/00 ,  C07D319/12 ,  C07D321/00

    Abstract: Unsaturated cyclic ethers are produced from diols in high yield and with low hydrogenated byproduct formation, by use of a supported cobalt-noble metal catalyst that has been doped with sulfur. A process for the production of unsaturated cyclic ethers (I) of formula (1) comprises reaction of a diol (II) of formula: OH-CH(R )-Y-CH(R )-CH(R )-OH (2), in the liquid phase at 150-300 degrees C, in the presence of a supported cobalt- containing catalyst (III) that has not been activated by reduction prior to use. The cobalt containing catalyst (III) is impregnated with a noble metal consisting of platinum, palladium, rhodium, iridium, ruthenium, osmium and/or rhenium on an inert carrier that is doped with sulfur. Y = -(CHR )q- or -(CHR )q-O-; R - R = H or 1-4C alkyl; q = 0-3. An Independent claim is also included for the supported cobalt catalyst (III).

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