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公开(公告)号：CZ205699A3
公开(公告)日：1999-09-15
申请号：CZ205699
申请日：1997-12-12
Applicant: BASF AG
Inventor： HORN PETER , SCHERZER DIETRICH , HABERLE KARL , TREULING ULRICH , PARTUSCH GEORG , TANNY GUNTER , KISTENMACHER AXEL
Abstract: In a process for producing self-releasing, compact or cellular moldings which comprise polyisocyanate polyaddition products and may contain reinforcing material by reactinga) organic and/or modified organic polyisocyanates withb) at least one compound containing at least two reactive hydrogen atoms and having a molecular weight of from 62 to 10,000 and, if desired,c) chain extenders and/or crosslinkers in the presence ofd) internal mold release agents and in the presence of or absence ofe) catalysts,f) blowing agents,g) reinforcing materials andh) auxiliariesin an open or closed mold, the internal mold release agents (d) used are diesters and/or monoesters of alkylsuccinic acids and/or diesters and/or monoesters of alkenylsuccinic acids.
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公开(公告)号：AT184032T
公开(公告)日：1999-09-15
申请号：AT96941636
申请日：1996-12-02
Applicant: BASF AG
Inventor： HORN PETER , HESSE ANTON , RATH HANS PETER , GREIF NORBERT , PARTUSCH GEORG , BAUMANN EDWIN , LARBIG HARALD , HECKMANN WALTER , BECKER JOHANNES
IPC: C08J5/04 , C08G18/06 , C08G18/28 , C08G18/66 , C08G101/00 , C08J5/24 , C08J9/00 , C08J9/04 , C08K5/3415 , C08L75/04
Abstract: The invention relates to a process for preparing self-releasing, compact or cellular moulded bodies optionally containing reinforcing agents and made of polyisocyanate polyaddition products by reacting a) organic and/or modified organic polyisocyanates with b) at least one compound with at least two reactive hydrogen atoms and a molecular weight of 500 to 9,000 and optionally c) chain extension and/or cross-linking agents in the presence of d) alkyl and/or alkenyl succinic acid monoamides, -monoamides, poly(alkyl succinic acid)- and/or poly(alkenyl succinic acid)-polyamides, -polyimides, -monoamide monoimides, -polyamide imides, -amide polyimides and- polyamide polyimides or mixtures thereof as internal mould release agents, and also in the presence or absence of e) catalysts, f) blowing agents, g) reinforcing agents, h) auxiliary agents, in an open or closed moulding tool, optionally under compression. The invention also relates to the use of alkyl- and/or alkenyl succinic acid amides and/or imides (d) as internal mould release agents for the preparation of moulded bodies made of polyisocyanate polyaddition products.
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公开(公告)号：CA2219846A1
公开(公告)日：1998-05-21
申请号：CA2219846
申请日：1997-11-20
Applicant: BASF AG
Inventor： PRISSOK FRANK , LEHR GERHARD , GENZ MANFRED , KING HORST , KRECH RUEDIGER , HORN PETER
Abstract: Thermoplastic polyurethanes are prepared by reacting (a) isocyanates with (b) compounds reactive toward isocyanates, in the presence or absence of (c) chain extenders, (d) catalysts and (e) customary auxiliaries and additives and adding crosslinked polyurethanes in comminuted form before, during and/or after the reaction.
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公开(公告)号：CA2054170C
公开(公告)日：1996-12-03
申请号：CA2054170
申请日：1991-10-24
Applicant: BASF AG
Inventor： HORN PETER , HOELDERICH WOLFGANG , TADDEY RUDOLF , TINTELNOT DIETER
IPC: B29C45/00 , B29C44/00 , B29K75/00 , B29L31/56 , C08G18/00 , C08G18/08 , C08G101/00 , C08J9/00 , C08J9/02 , C08J9/34 , C08K7/26 , C08L75/00 , B29C67/20
Abstract: Chlorofluorocarbon-free urethane-containing, soft-elastic moldings having a cellular core, a compacted peripheral zone and an essentially pore-free smooth surface are produced by reacting a) an organic and/or modified organic polyisocyanate with b) at least one relatively high-molecular-weight compound containing at least two reactive hydrogen atoms and, if desired, c) a low-molecular-weight chain extender and/or crosslinking agent, in the presence of d) a blowing agent, e) a catalyst, f) a crystalline, microporous molecular sieve having a cavity diameter of less than 1.3 nm and comprising metal oxides or metal phosphates, and, if desired, further additives and g) assistants, in a closed mold with compaction, expediently by RIN.
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公开(公告)号：MX169980B
公开(公告)日：1993-08-03
申请号：MX1644189
申请日：1989-06-13
Applicant: BASF AG
Inventor： HORN PETER , REICH ERHARD , HENNING RAINER
Abstract: The invention relates to polyurethane mouldings which are provided with a contoured, multilayer film and comprise a) a top layer of paint, b) a middle layer of a urethane- and/or urea-containing film, produced from a thermocurable mixture which has a long shelf life at room temperature, and c) a rear layer of a compact or cellular polyurethane, which may optionally contain inserts and/or reinforcing material, and to a process for the production of the polyurethane mouldings according to the invention and to their use.
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Patent Agency Ranking
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公开(公告)号：CA1270738A
公开(公告)日：1990-06-26
申请号：CA493840
申请日：1985-10-25
Applicant: BASF AG
Inventor： HORN PETER , BAUMANN EDWIN , MARX MATTHIAS , GERARTS PETER
IPC: B32B5/28 , B32B5/24 , B32B37/10 , B32B38/00 , C08G69/16 , C08J5/24 , C08J9/40 , B29C69/00 , B32B31/20 , B32B27/42
Abstract: Sheet-like reinforced materials consisting of A. a core layer comprising a sheet-Like textile structure, preferably a glass fiber mat, B. a plastic matrix composed of a nylon which has been polymerized under alkaline conditions and penetrates both the core layer and the surface layer or layers, are produced batchwise by the RIM method or continuously on a double-belt press by impregnating the sheet-line textile structure and the foam sheets with a lactam melt and polymerizing the latter. The reinforced material can be used for the production of finished articles having a satisfactory surface, for example for the automotive or aircraft industry.
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公开(公告)号：CA2002400A1
公开(公告)日：1990-05-09
申请号：CA2002400
申请日：1989-11-07
Applicant: BASF AG
Inventor： HORN PETER , REHMER GERD , LUTTER HEINZ-DIETER , RAMLOW GERHARD , HINZ WERNER , SCHMIDT HANS U
IPC: C08F216/14 , C08F218/10 , C08F220/28 , C08F220/58 , C08F222/20 , C08F226/00 , C08F226/06 , C08F290/06 , C08F299/02 , C08G18/40 , C08G18/62 , C08L75/04 , C09K23/52
Abstract: The novel copolymers having K values of from 5 to 80 are prepared by free-radical polymerisation of A) 20 to 80% by weight, based on the total weight of (A) and (B), of at least one olefinically unsaturated polyoxyalkylene alcohol or polyester alcohol adduct, (B) 80 to 20% by weight, based on the total weight of (A) and (B), of at least one vinyl monomer from the group comprising N-vinylformamide, -2-pyrrolidone, -2-piperidone, -2-caprolactam, -imidazole, -2-ethyleneurea and -2-propyleneurea, C) 0.05 to 40 parts by weight of glycidyl acrylate and/or glycidyl methacrylate, D) 0 to 10 parts by weight of at least one alpha , beta -monoolefinically unsaturated acid and E) 0 to 30 parts by weight of at least one olefinically unsaturated carboxamide and/or carboxylate and/or styrene, the parts by weight of (C), (D) and (E) in each case being based on 100 parts by weight of the monomers (A) and (B). The copolymers are used as assistants and/or additives, for example as dispersion and/or emulsification assistants, or as additives for improving the mechanical properties, in formulations for the preparation of polyisocyanate polyaddition products.
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公开(公告)号：CA1225187A
公开(公告)日：1987-08-04
申请号：CA468826
申请日：1984-11-28
Applicant: BASF AG
Inventor： BLUM RAINER , WERNER FRANK , HORN PETER , OSTERLOH ROLF , WELZ MARTIN
Abstract: HEAT-CURABLE COMPOSITIONS WHICH ARE STORAGE-STABLE AT ROOM TEMPERATURE AND ARE BASED ON COMPOUNDS HAVING REACTIVE-HYDROGEN ATOMS AND POLYISOCYANATES _ of the Invention The invention relates to compositions which are storage-stable at room temperature and which can be heat--cured to form molded parts having polyurethane, polyurea, and polyisocyanurate groups, said composition containing (a) one or more polyols having a molecular weight of from 400 to 10,000 and a functionality of from 2 to 8, (b) at least one polyfunctional compound having a molecular weight of 62 to 400 and being selected from the group consisting of aliphatic hydroxyl compound, cycloaliphatic hydroxyl compounds, aromatic amino compounds, or mixtures thereof, and (c) an organic polyisocyanate which is present in the form of discreet particles, which are deactivated on their surfaces and are dispersed in the liquid component, and depending on the product needs, (d) catalysts, (e) blowing agents, (f) reinforcing materials, and (g) auxiliaries and additives. The single-component systems are used for the preparation of cellular or noncellular, optionally reinforced polyurethane, polyurea, and/or polyisocyanurate group-containing molded parts.
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公开(公告)号：CA1193399A
公开(公告)日：1985-09-10
申请号：CA432865
申请日：1983-07-21
Applicant: BASF AG
Inventor： HORN PETER , GEHM ROBERT , MARX MATTHIAS , ROEBER ARTUR
IPC: C01B33/32 , C08G18/00 , C08G18/18 , C08G18/32 , C08G18/38 , C08G18/50 , C08G18/83 , C08G77/02 , C08K3/34 , C08G18/14 , C08G18/40 , C08J9/04
Abstract: Stable water glass solutions are obtained (A) by mixing a solution of an aqueous alkali silicate solution and alkali hydroxide with a tertiary amine and subsequently oxyalkylating the resultant two-phase reaction mixture with at least one alkylene oxide in such an amount that a uniform solution forms or (B) by oxyalkylating a tertiary amine with at least one alkylene oxide and mixing the resultant reaction mixture with a solution of an aqueous alkali silicate solution and alkali hydroxide. The stable water glass solutions are suitable for the preparation of organo silicate foams. For the preparation of the organo silicate foams, a mixture of the stable water glass solutions and tertiary amino group-containing polyether polyols is reacted with organic polyisocyanates in the presence of catalysts, blowing agents and optionally auxiliaries and additives.
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