Coatings - by curing applied powders formed by polymn of - olefins and epoxy resins - to give powders useful as coatings

    公开(公告)号:DE2207910A1

    公开(公告)日:1973-08-23

    申请号:DE2207910

    申请日:1972-02-19

    Applicant: BASF AG

    Abstract: Process for prepg. coating by heating at 130-200 degrees C an (e.g. electrostatically) applied powder coating comprising a copolymer formed from (in wt.%) (1) 15-80 meth(acrylic)esters of 1-8C alkanols; (2) 10-80 alkenylbenzenes of 8-10C (3) 5-40 ethers of unsatd carboxylic N-methylolamides the acid residue contg 3-5C and the ether gp 1-8C (4) 0-20 glycol mono-acrylate or methacrylate (5) 0-20 3-5C enoic acid (6) 0-20 other monoolefins. (1)-(6) are bulk, suspension or emulsion copolymerised using an initiator a water-dilutable protective colloid and 1-25% epoxide resin and opt. other additives. Powder produced requires milder curing conditions, is insensitive to impurities, gives high gloss finish, and has high resistance to solvents and abrasion.

    Magnetic recording vehicle - comprising a magnetic pigment dispersion in a copolymer forming a hard coating

    公开(公告)号:DE2060214A1

    公开(公告)日:1972-06-15

    申请号:DE2060214

    申请日:1970-12-08

    Applicant: BASF AG

    Abstract: A magnetic recording vehicle is mfd. by preparing a dispersion of a finely divided magnetic pigment (eg. gamma-Fe(III)-oxide) in a binder based on a copolymer of monoolefinically unsatd. monomers and an inert solvent (eg. toluene), with opt. admixture of usual additives; applying a layer of the dispersion onto a substrate (eg. a PVC or polyester film or tape) and drying or hardening. The copolymer used forms hard coatings and contains (A) 5-40 wt.% of units of formula R(CH2)C-X-Y-O-CO-CH2-Z (where X is COO or S; Y is divalent aliphatic 2-12 C (oxa)hydrocarbon; Z is COCH2 or CN; and R is R when X is S, or H or CH3 when X is COO; and (B) 60-95 wt.% of units of acrylates and/or methacrylates which may be replaced by up to 30% units of other comonomer units. Good abrasion resistance hence long service life.

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