公开(公告)号：DE19962155A1

公开(公告)日：2001-06-28

申请号：DE19962155

申请日：1999-12-22

Applicant: BASF AG

Inventor： MERK CLAUDIA ,  BOTZEM JOERG ,  HUBER GUENTHER ,  GRUND NORBERT

IPC: C09B67/28 ,  C02F1/461 ,  C02F1/467 ,  C25B3/25 ,  D06P1/22 ,  D06P1/28 ,  D06P1/30 ,  D06P3/60 ,  D06P5/20 ,  C25B3/04 ,  C25B11/04 ,  C09B67/00 ,  C09B7/02

Abstract: In electrochemical reduction of a vat dye (I) by contacting (I) with a cathode comprising a substrate of electroconductive material and an electroconductive, cathodically-polarized layer formed in situ by sedimentation, electrochemical reduction is carried out in the presence of a base.

公开(公告)号：DE19962102A1

公开(公告)日：2001-06-28

申请号：DE19962102

申请日：1999-12-22

Applicant: BASF AG

Inventor： MERK CLAUDIA ,  HUBER GUENTHER

IPC: C25B3/23 ,  C25B11/00 ,  C25B3/02 ,  C25B11/04

Abstract: A process for the electrochemical oxidation of organic compounds (I) other than phosphonomethyl-iminodiacetic acid involves contacting (I) with an anode consisting of an electrically conductive support coated with an anodically polarized layer (II) formed by deposition in situ.

公开(公告)号：CA2336800A1

公开(公告)日：2000-01-20

申请号：CA2336800

申请日：1999-07-02

Applicant: BASF AG

Inventor： MERK CLAUDIA ,  BASSLER PETER ,  FISCHER ROLF ,  VOIT GUIDO ,  LUYKEN HERMANN

IPC: C07D295/02 ,  C07C209/48 ,  C07C209/82 ,  C07C209/84 ,  C07C211/12 ,  C07D295/023 ,  C25B3/25

Abstract: The invention relates to a method for reducing the quantity of an unsaturate d cyclic imine (I) of formula (I) in a mixture containing hexamethylenediamine and an imine (I), R1 meaning an alkenyl radical with 3, 4, 5, 6, 7, 8, 9, 10 , 11 carbon atoms belonging to the ring system, by electrochemically convertin g the imine (I) into a saturated cyclic amine of formula (II) in the presence of solvated protons.

公开(公告)号：DE10324192A1

公开(公告)日：2004-12-23

申请号：DE10324192

申请日：2003-05-28

Applicant: BASF AG

Inventor： GRIESBACH ULRICH ,  MERK CLAUDIA ,  HERMELING DIETER ,  BOTTKE NILS ,  SCHUBERT MARKUS ,  URTEL HEIKO

IPC: C07C41/50 ,  C07C43/307 ,  C07D307/32 ,  C07D307/83 ,  C07D307/88 ,  C07D307/89

公开(公告)号：DE59907209D1

公开(公告)日：2003-11-06

申请号：DE59907209

申请日：1999-07-02

Applicant: BASF AG

Inventor： MERK CLAUDIA ,  BASSLER PETER ,  FISCHER ROLF ,  VOIT GUIDO ,  LUYKEN HERMANN

IPC: C07D295/02 ,  C07C209/48 ,  C07C209/82 ,  C07C209/84 ,  C07C211/12 ,  C07D295/023 ,  C25B3/25

Abstract: The level of an unsaturated cyclic imine (I) of the formula (I)where R1 is alkenyl having 3, 4, 5, 6, 7, 8, 9, 10, 11 carbon atoms belonging to the ring system, in a mixture comprising hexamethylenediamine and an imine (I) is reduced by electrochemical conversion of an imine (I) in a mixture comprising hexamethylenediamine and an imine (I) in the presence of solvated protons into a saturated cyclic amine of the formula (II)

公开(公告)号：AT251111T

公开(公告)日：2003-10-15

申请号：AT99932786

申请日：1999-07-02

Applicant: BASF AG

Inventor： MERK CLAUDIA ,  BASSLER PETER ,  FISCHER ROLF ,  VOIT GUIDO ,  LUYKEN HERMANN

IPC: C07D295/02 ,  C07C209/48 ,  C07C209/82 ,  C07C209/84 ,  C07C211/12 ,  C07D295/023 ,  C25B3/25

Abstract: The level of an unsaturated cyclic imine (I) of the formula (I)where R1 is alkenyl having 3, 4, 5, 6, 7, 8, 9, 10, 11 carbon atoms belonging to the ring system, in a mixture comprising hexamethylenediamine and an imine (I) is reduced by electrochemical conversion of an imine (I) in a mixture comprising hexamethylenediamine and an imine (I) in the presence of solvated protons into a saturated cyclic amine of the formula (II)

公开(公告)号：CA2458696A1

公开(公告)日：2003-03-13

申请号：CA2458696

申请日：2002-08-10

Applicant: BASF AG

Inventor： GRIMMER JOHANNES ,  MERK CLAUDIA ,  ERNST HANSGEORG ,  SAUERWALD MANFRED ,  BOTZEM JOERG ,  MUELLER THOMAS

IPC: C25B3/25 ,  C07C45/62 ,  C25B3/04 ,  C25B9/06 ,  C25B9/20

Abstract: The invention relates to a method for producing compounds of general formula (I), wherein Rl represents an oxocyclohexyl radical which is optionally substituted by a hydroxyl radical, an alkoxy radical, and/or alkyl radicals, or an oxocyclohexenyl radical which is optionally substituted by a hydroxyl radical, an alkoxy radical, and/or alkyl radicals, the oxo groups being in t he form of an acetal, a ketone, or an enol ether, and R2 represents a hydroxy group or a protective group which can be transformed into a hydroxy group by means of hydrolysis. A compound of general formula (II) is cathodically reduced in a divided or partially divided electrolysis cell at a pH value of between 2 and 9.

公开(公告)号：DE10054993A1

公开(公告)日：2001-05-17

申请号：DE10054993

申请日：2000-11-07

Applicant: BASF AG

Inventor： MERK CLAUDIA ,  BUTZ THOMAS ,  DROEGEMUELLER MICHAEL ,  FISCHER MARTIN

IPC: C07F9/38 ,  C25B3/23 ,  C25B3/02 ,  C25B11/04 ,  C07F9/09

Abstract: A process for the production of N-phosphonomethylglycine (PMG) or corresponding salt by electrochemical oxidation of phosphonomethyliminodiacetic acid or corresponding salt (PMIDA) using an anode comprising an electrically conductive support material and an electrically conductive anodically polarized layer formed by in situ deposition.

公开(公告)号：DE19911746A1

公开(公告)日：2000-09-21

申请号：DE19911746

申请日：1999-03-16

Applicant: BASF AG

Inventor： PUETTER HERMANN ,  WEIPER-IDELMANN ANDREAS ,  MERK CLAUDIA

IPC: B01J19/08 ,  C02F1/461 ,  C25B3/00 ,  C25B11/04 ,  C25B11/12 ,  H01M4/58 ,  C23C16/26

Abstract: An electrode, having an applied pore-free diamond layer, is new. Independent claims are also included for the following: (i) production of the above electrode by seeding a cleaned electrode body surface with a high diamond nuclei density prior to coating with diamond; and (ii) electrochemical conversion of organic compounds by contact with the above electrode.

公开(公告)号：DE19827321A1

公开(公告)日：1999-12-23

申请号：DE19827321

申请日：1998-06-19

Applicant: BASF AG

Inventor： MERK CLAUDIA ,  PUETTER HERMANN ,  STECKHAN EBERHARD ,  KROENER LARS ,  JOERISSEN JAKOB ,  HOORMANN DIRK

IPC: C25B3/23 ,  C25B3/02 ,  C07C43/30 ,  C07C43/205 ,  C07C47/52 ,  C07C49/76

Abstract: Production of aromatic aldehyde, ether, acetal and ester compounds (I) by electrochemical oxidation is carried out in an electrolytic cell with a solid state electrolyte, consisting of one or several superimposed layers of cation exchange membrane, a cathode and an anode in direct contact with this and an electrolysis liquid. Production of aromatic aldehyde, ether, acetal and ester compounds of formula (I) with an oxidation number of 1-9 from aromatic compounds of formula (II) with an oxidation number NOTLESS 1 lower by electrochemical oxidation is carried out in an electrolytic cell with a solid state electrolyte, consisting of one or several superimposed layers of cation exchange membrane, a cathode and an anode in direct contact with this and an electrolysis liquid. The liquid is an organic solution, free from conducting electrolyte, containing 10-90 wt. % methanol, 1-50 wt. % compounds selected from (I) and (II), including NOTLESS 1 mol. % (II), 1-50 wt. % optionally N-alkylated 1-15 carbon (C) carbonamide or 3-15 C N-alkylated urea and 0-30 wt. % other inert solvent. R = hydrogen (H), 2-4 C alkyl, 1-4 C alkoxy or halogen; A, X = methylene, carbonyl or methoxymethylene (-CH(OCH3)-); B, Y = H or methoxy (OCH3); m = 0-3; n = 1-3. The oxidation numbers of (I) and (II) are obtained by adding the oxidation number for each group A and B or X and Y, which is 0 if A is methylene, 1 if A is methoxymethylene and 2 if A is carbonyl, 0 if B is H and 1 if B is methoxy.