14.
    发明专利
    未知

    公开(公告)号:AT270134T

    公开(公告)日:2004-07-15

    申请号:AT01969739

    申请日:2001-09-19

    Applicant: BASF AG

    Abstract: A process is proposed for the separation of C 5+ cuts by distillation into a low-boiler (A), a medium-boiler (B) and a high-boiler fraction (C) in one or more dividing-wall columns (TK), in which a dividing wall (T) is arranged in the longitudinal direction of the column with formation of an upper, common column region ( 1 ), a lower, common column region ( 6 ), a feed part ( 2, 4 ) with rectifying section ( 2 ) and stripping section ( 4 ), and a withdrawal part ( 3, 5 ) with rectifying section ( 5 ) and stripping section ( 3 ), with feed of the C 5+ cut (A, B, C) into the central region of the feed part ( 2, 4 ), discharge of the high-boiler fraction (C) from the bottom of the column, discharge of the low-boiler fraction (A) via the top of the column, and discharge of the medium-boiler fraction (B) from the central region of the withdrawal part ( 3, 5 ), wherein the dividing ratio of the liquid reflux at the upper end of the dividing wall (T) is set in such a way that the proportion of high-boiling key components in the liquid reflux over the stripping section ( 3 ) of the withdrawal part at the upper end of the dividing wall (T) is from 10 to 80%, preferably from 30 to 50%, of the limit value allowed in the medium-boiler fraction (B), and wherein the heating power in the evaporator at the bottom of the dividing-wall column (TK) is set in such a way that the concentration of the low-boiling key components in the liquid at the lower end of the dividing wall (T) is from 10 to 80%, preferably from 30 to 50%, of the limit value allowed in the medium-boiler fraction (B).

    16.
    发明专利
    未知

    公开(公告)号:ES2175520T3

    公开(公告)日:2002-11-16

    申请号:ES97954375

    申请日:1997-12-10

    Applicant: BASF AG

    Abstract: The disclosure is a process for preparing mixtures of monoolefinic C5 mononitriles having nonconjugated C=C- and C=N bonding by catalytic hydrocyanation of a hydrocarbon mixture containing 1,3-butadiene, by first diminishing the proportion of those components in the hydrocarbon mixture which impair the catalytic hydrocyanation and then subjecting the resulting mixture to catalytic hydrocyanation.

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