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    11.
    发明专利
    未知

    公开(公告)号：DE59102591D1

    公开(公告)日：1994-09-29

    申请号：DE59102591

    申请日：1991-02-14

    Applicant: BASF AG

    Inventor： RIEGER BERNHARD DR ,  BRINTZINGER HANS PROF DR ,  ROELL WERNER DR ,  REINMUTH ANNETTE ,  BARSTIES ELKE

    IPC: C07F17/00 ,  C08F4/60 ,  C08F4/626 ,  C08F4/639 ,  C08F4/6392 ,  C08F4/64 ,  C08F4/642 ,  C08F4/646 ,  C08F4/6592 ,  C08F4/68 ,  C08F10/00 ,  C08F10/06 ,  C08F110/06

    Abstract: The present invention relates to soluble catalyst systems for the polymerization of C2- to C10-alk-l-enes, containing, as active constituents, a) a metallocene complex of the general formula I (I) where R1 and R2 are branched C4- to C10-alkyl, 5- to 7-membered cycloalkyl, which may itself be substituted by C1- to C6-alkyl, or are C6- to C15-aryl or aralkyl; R3 to R6 are C1- to C8-alkyl, M is titanium, zirconium, hafnium or vanadium, Y is silicon or germanium, and X is halogen or C1- to C8-alkyl, b) and an open-chain or cyclic aluminoxane compound of the general formula II or III where R7 is C1-C4-alkyl, and m is from 5 to 30. These catalyst systems are particularly suitable for the preparation of polypropylene and copolymers of propylene with lesser amounts of other C2- to C10-alky-l-enes.

    12.
    发明专利
    未知

    公开(公告)号：DE4120009A1

    公开(公告)日：1992-12-24

    申请号：DE4120009

    申请日：1991-06-18

    Applicant: BASF AG

    Inventor： KARL EBERHARD ,  ROELL WERNER DR ,  BRINTZINGER HANS PROF DR ,  RIEGER BERNHARD DR ,  STEHLING UDO

    IPC: C07F17/00 ,  C08F4/60 ,  C08F4/622 ,  C08F4/639 ,  C08F4/642 ,  C08F4/6392 ,  C08F4/646 ,  C08F4/649 ,  C08F4/6592 ,  C08F4/68 ,  C08F10/00 ,  C08F10/06 ,  C08F110/06

    Abstract: Polymers of 2-10C alk-1-ene are obtd. by polymerisation at 0.1-3000 bar and -20 to 300 degrees C in the presence of a catalyst system contg.: (a) a bis-cyclopentadienyl complex of formula (I), and (b) an open-chain or cyclic aluminoxane of formulae (II) or (III). (R )2Al-Ä-O-Al(R )-Üm-R (II) M = Ti, Zr, Hf, V, Nb or Ta; X = halo or 1-8C alkyl; Y = C, P, S, Si or Ge; Z = 1-8C alkyl, 3-10C cycloalkyl or 6-10C aryl; R , R = 1-4C alkyl; R -R = H or 1-4C alkyl; or R +R or R +R may form a 4-15C hydrocarbon ring system; n = 0, 1 or 2; R = 1-4C alkyl; and m = 5-30. The following cpds. are excluded: dimethylsilyl- bis-(2-methyl indenyl)-, phenyl(methyl)silyl- bis-(2-methyl indenyl)-, diphenylsilyl- bis-(2-methyl indenyl)-, dimethylsilyl- bis-(2-ethyl indenyl)- and isopropylidene- bis-(2-methyl indenyl)- zirconium dichloride, and dimethylsilyl- and phenyl(methyl)silyl- bis-(2-methyl indenyl)- zirconium-dimethyl.

    13.
    发明专利
    未知

    公开(公告)号：ES2116027T3

    公开(公告)日：1998-07-01

    申请号：ES95115772

    申请日：1992-05-27

    Applicant: BASF AG

    Inventor： KARL EBERHARD ,  ROELL WERNER DR ,  BRINTZINGER HANS-HERBERT PROF ,  RIEGER BERNHARD DR ,  STEHLING UDO

    IPC: C07F17/00 ,  C08F4/60 ,  C08F4/622 ,  C08F4/642 ,  C08F4/639 ,  C08F4/6392 ,  C08F4/646 ,  C08F4/649 ,  C08F4/6592 ,  C08F4/68 ,  C08F10/00 ,  C08F10/06 ,  C08F110/06

    Abstract: Polymers of 2-10C alk-1-ene are obtd. by polymerisation at 0.1-3000 bar and -20 to 300 degrees C in the presence of a catalyst system contg.: (a) a bis-cyclopentadienyl complex of formula (I), and (b) an open-chain or cyclic aluminoxane of formulae (II) or (III). (R )2Al-Ä-O-Al(R )-Üm-R (II) M = Ti, Zr, Hf, V, Nb or Ta; X = halo or 1-8C alkyl; Y = C, P, S, Si or Ge; Z = 1-8C alkyl, 3-10C cycloalkyl or 6-10C aryl; R , R = 1-4C alkyl; R -R = H or 1-4C alkyl; or R +R or R +R may form a 4-15C hydrocarbon ring system; n = 0, 1 or 2; R = 1-4C alkyl; and m = 5-30. The following cpds. are excluded: dimethylsilyl- bis-(2-methyl indenyl)-, phenyl(methyl)silyl- bis-(2-methyl indenyl)-, diphenylsilyl- bis-(2-methyl indenyl)-, dimethylsilyl- bis-(2-ethyl indenyl)- and isopropylidene- bis-(2-methyl indenyl)- zirconium dichloride, and dimethylsilyl- and phenyl(methyl)silyl- bis-(2-methyl indenyl)- zirconium-dimethyl.

    15.
    发明专利
    未知

    公开(公告)号：DE4406964A1

    公开(公告)日：1995-09-07

    申请号：DE4406964

    申请日：1994-03-03

    Applicant: BASF AG

    Inventor： LANGHAUSER FRANZ DR ,  FISCHER DAVID DR ,  KERTH JUERGEN DR ,  SCHWEIER GUENTHER DR ,  BARSTIES ELKE ,  BRINTZINGER HANS-HERBERT PROF ,  SCHAIBLE STEFAN ,  ROELL WERNER DR

    IPC: C08F4/622 ,  C08F4/02 ,  C08F4/60 ,  C08F4/602 ,  C08F4/616 ,  C08F4/628 ,  C08F4/639 ,  C08F4/6392 ,  C08F4/642 ,  C08F4/656 ,  C08F4/6592 ,  C08F4/68 ,  C08F10/00

    Abstract: New supported catalyst systems prepd. by the following method: (a) reaction of a fine particled carrier with an alpha -tris-alkoxysilyl- OMEGA -haloalkyl cpd.; (b) addn. of a metallocene complex of formula (I); (c) reaction with a quaternising agent of formula (V); and (d) opt. addn. of an open chain or cyclic alumoxane cpd. of formula (VI) or (VII). M = Ti, Zr, Hf,V, Nb or Ta; X = F, Cl, Br, I, H 1-10C alkyl, 6-15C aryl or -OR ; R = 1-10C alkyl, 6-15C aryl, 1-10C alkyl, 6-20C aryl, 6-20C aryl - 1-10C alkyl, 1-10C fluoroalkyl or 6-20C fluoroaryl; R -R and R -R = H, 1-10C alkyl, opt.1-10C alkyl substd. 5-7 membered cycloalkyl or 6-15C aryl(alkyl),with which two neighbouring gps. may opt. form 4-15C cyclic gps., or Si(R )3; R = 1-10C alkyl, 6-15C aryl or 3-10C cycloalkyl; R = : Q = N,P, As, Sb or Bi; R , R = 1-10C alkyl, 3-15C cycloalkyl, 6-15C aryl, 1-10C alkyl- 6-20C aryl, 6-20C aryl -1-10C alkyl, 1-10C fluoroalkyl or 5-20C fluoroaryl, or R and R may form a 2-15C heterocyclic gp. contg. 1-8 heteroatoms from main gps. III-VI of the periodic table; R = H, 1-10C alkyl, opt.1-10C alkyl substd. 5-7 membered cycloalkyl, 6-15C aryl(alkyl) in which two neighbouring gps. may opt. form 4-15C cyclic gps. Si(R )3 or a gp. of formula R = 1-10C alkyl, 6-15C aryl or 3-10C cycloalkyl; Q = N, P, As, Sb, or Bi; R , R = 1-10C alkyl, 3-15C cycloalkyl, 6-15C aryl, 1-10C alkyl 6-20C aryl, 6-20C aryl -1-10C alkyl, 1-10C fluoroalkyl, 6-20C fluoroaryl or R14 and R15 may form a 2-15C heterocyclic gp.contg. 1-8 heteroatoms from main gps. III-VI of the periodic table; Y = a gp. of formula Z = Si,Ge, Sn or C; R -R = H, 1-10C alkyl, 3-10C cycloalkyl or 6-15C aryl, with two neighbouring gps. opt. forming a 4-15C cyclic gp.; A = 1-10C alkyl, 3-15C cycloalkyl, 6-15C aryl, 1-10C alkyl-6-20C aryl, 6-20C aryl-1-10C alkyl, 1-10C fluoroalkyl or 6-20C fluoroaryl; X = F, Cl, Br, I, SO3 , SO4 or NO3 ; a = 1-2; R = 1-4C alky; and m = 5-30. Also claimed are (i) the prepn. of the supported catalyst systems, and (ii) use of the catalyst systems for the prepn. of 2-10C alk-1-enes at -50 to 300 degrees C. 0.5-3000 bar.

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