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公开(公告)号:DE102006020847A1
公开(公告)日:2007-11-08
申请号:DE102006020847
申请日:2006-05-04
Applicant: BOSCH GMBH ROBERT , BASF AG
Inventor: GRAEHN JAN-MICHAEL , GRUENWALD WERNER , FAYE IAN , LEUTHNER STEPHAN , OERTEL KAI , ALLGEIER THORSTEN , MUELLER ULRICH , SCHUBERT MARKUS
IPC: F17C11/00
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公开(公告)号:DE102005009596A1
公开(公告)日:2006-08-31
申请号:DE102005009596
申请日:2005-02-28
Applicant: BASF AG
Inventor: SCHUBERT MARKUS , STEPHAN JUERGEN , POPLOW FRANK , HEIDEMANN THOMAS , DIEHLMANN UWE , MALTRY MICHAELA
Abstract: Preparation of non-aromatic carbon-carbon double/triple bond compound (A) or its mixtures from another non-aromatic carbon-carbon double/triple bond compound (B), comprises reacting pure (B) with an adsorption agent comprising an aluminum oxide (3 wt.%) and activating at 450-1000[deg]C; and contacting the pure compound (B) with a metathesis catalyst.
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公开(公告)号:AT328658T
公开(公告)日:2006-06-15
申请号:AT03810970
申请日:2003-11-06
Applicant: BASF AG
Inventor: SCHUBERT MARKUS , HESSE MICHAEL , FISCHER ROLF-HARTMUTH , CONSTANTINESCU TAKE
IPC: B01J21/18 , B01J23/00 , B01J23/656 , B01J23/68 , B01J23/84 , B01J23/889 , B01J35/00 , B01J37/02 , C07D307/08 , C07D307/33 , C07D315/00
Abstract: A supported rhenium containing catalyst (I) contains a further metal from Group 8 or 1b, preferably ruthenium (Ru), rhodium (Rh), palladium (Pd), osmium (Os,) iridium (Ir), platinum (Pt), copper (Cu), silver (Ag) or cobalt (Co) in the form of at least one bimetallic precursor compound applied to the support. An Independent claim is also included for a process for the production of mixtures of tetrahydrofuran and gamma-butyrolactone by catalytic hydrogenation of carbonyl compounds using the catalyst (I).
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公开(公告)号:DE102004009805A1
公开(公告)日:2005-09-15
申请号:DE102004009805
申请日:2004-02-28
Applicant: BASF AG
Inventor: SCHUBERT MARKUS , STEPHAN JUERGEN , BOEHM VOLKER , BRODHAGEN ANDREAS , POPLOW FRANK , WEICHERT CHRISTIAN , BORCHERT HOLGER
Abstract: Supported catalyst comprising a support (S) in which Al 2 O 3 is present in a proportion of at least 75% by weight and rhenium compounds as active component (A), wherein the maximum of the distribution function of the pore diameters in the mesopore range is at from 0.008 to 0.050 mum.
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公开(公告)号:AT287398T
公开(公告)日:2005-02-15
申请号:AT02758298
申请日:2002-07-03
Applicant: BASF AG
Inventor: SCHLITTER STEPHAN , BORCHERT HOLGER , HESSE MICHAEL , SCHUBERT MARKUS , BOTTKE NILS , FISCHER ROLF-HARTMUTH , ROESCH MARKUS , HEYDRICH GUNNAR , WECK ALEXANDER
IPC: B01J23/89 , B01J37/02 , B01J37/03 , C07D307/08 , C07D307/33 , C07D315/00
Abstract: A catalyst (I) for the gas phase hydrogenation of 4C-dicarboxylic acids and/or derivatives, preferably maleic acid anhydride, comprises copper oxide (20-94 wt.%), palladium and/or a palladium compound (0.005-5 wt.%) and an oxide support (2-79.995 wt.%) comprising oxides of Al, Si, Zn, La, Ce, Group IIIa-VIIIa elements and/or Group IA and II elements. Independent claims are also included for: (i) a process for the production of the catalyst (I) by impregnation of an oxide supported copper oxide catalyst with a solution of a soluble palladium compound, drying and optionally calcining; and (ii) a process for the gas phase hydrogenation of 4C-dicarboxylic acids and/or derivatives, preferably maleic acid anhydride in the presence of the catalyst (I).
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公开(公告)号:DE10225928A1
公开(公告)日:2003-12-24
申请号:DE10225928
申请日:2002-06-11
Applicant: BASF AG
Inventor: HESSE MICHAEL , SCHLITTER STEPHAN , BORCHERT HOLGER , SCHUBERT MARKUS , ROESCH MARKUS , BOTTKE NILS , FISCHER ROLF-HARTMUTH , WECK ALEXANDER , WINDECKER GUNTHER , HEYDRICH GUNNAR
IPC: C07C29/149 , C07D315/00 , C07C29/132 , C07C31/20 , C07D307/20 , C07D307/32
Abstract: The invention relates to a method for producing optionally akyl-substituted 1,4-butandiol by two-stage catalytic hydration in the gaseous phase of C4 dicarboxylic acids and/or the derivatives thereof with the steps of: a) introducing a gaseous flow of a C4 dicarboxylic acid or a derivative thereof at 200 to 300 °C and 2 to 60 bar in a first reactor and catalytic gas phase hydration to a mainly optionally alkyl-substituted gamma-butyrolactone containing product; b) introducing the product flow so obtained into a second reactor at a temperature of from 150 °C to 240 °C and a pressure of from 15 to 100 bar and catalytic gas phase hydration to optionally alkyl-substituted 1,4-butandiol; c) removing the desired product from the intermediates, byproducts and possibly not reacted educt; d) optionally returning non-reacted intermediates to one or both hydration stages, whereby in both hydration stages one catalyst each is used which comprises = 5 % by weight, preferably 5 to 95 % by weight, especially 20 to 90 % by weight of an oxidic carrier, the pressure prevailing in the second reactor is higher than in the first reactor, and the product mixture removed from the first reactor is introduced into the second reactor without further purifying it.
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17.
公开(公告)号:AU2003242665A1
公开(公告)日:2003-12-22
申请号:AU2003242665
申请日:2003-06-11
Applicant: BASF AG
Inventor: BORCHERT HOLGER , SCHUBERT MARKUS , ROSCH MARKUS , BOTTKE NILS , FISCHER ROLF-HARTMUTH , WECK ALEXANDER , WINDECKER GUNTHER , HEYDRICH GUNNAR , HESSE MICHAEL , SCHLITTER STEPHAN
IPC: C07B61/00 , C07C29/149 , C07C31/20
Abstract: Optionally alkyl-substituted 1,4-butanediol is prepared from C 4 -dicarboxylic acids and/or of derivatives thereof by: a) introducing a gas stream of the C 4 -dicarboxylic acid or the derivative thereof in a first reactor in the gas phase to obtain a product which contains mainly optionally alkyl-substituted gamma-butyro-lactone; b) removing succinic anhydride from the product of step a); c) catalytically hydrogenating the product of step b) in a second reactor in the gas phase to obtain optionally alkyl-substituted 1,4-butanediol; d) removing the desired product from intermediates, by-products and any unconverted reactants; and e) optionally recycling unconverted intermediates into one or both hydrogenation stages. The catalysts employed in each of the hydrogenation stages comprise
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公开(公告)号:AU2003238491A8
公开(公告)日:2003-12-22
申请号:AU2003238491
申请日:2003-06-10
Applicant: BASF AG
Inventor: ROSCH MARKUS , WECK ALEXANDER , HEYDRICH GUNNAR , SCHLITTER STEPHAN , FISCHER ROLF-HARTMUTH , BORCHERT HOLGER , SCHUBERT MARKUS , HESSE MICHAEL , BOTTKE NILS , WINDECKER GUNTHER
IPC: C07C29/149 , C07D315/00 , C07C31/20 , C07D307/20
Abstract: The invention relates to a method for producing optionally akyl-substituted 1,4-butandiol by two-stage catalytic hydration in the gaseous phase of C4 dicarboxylic acids and/or the derivatives thereof with the steps of: a) introducing a gaseous flow of a C4 dicarboxylic acid or a derivative thereof at 200 to 300 °C and 2 to 60 bar in a first reactor and catalytic gas phase hydration to a mainly optionally alkyl-substituted gamma-butyrolactone containing product; b) introducing the product flow so obtained into a second reactor at a temperature of from 150 °C to 240 °C and a pressure of from 15 to 100 bar and catalytic gas phase hydration to optionally alkyl-substituted 1,4-butandiol; c) removing the desired product from the intermediates, byproducts and possibly not reacted educt; d) optionally returning non-reacted intermediates to one or both hydration stages, whereby in both hydration stages one catalyst each is used which comprises = 5 % by weight, preferably 5 to 95 % by weight, especially 20 to 90 % by weight of an oxidic carrier, the pressure prevailing in the second reactor is higher than in the first reactor, and the product mixture removed from the first reactor is introduced into the second reactor without further purifying it.
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公开(公告)号:BRPI0711285A2
公开(公告)日:2012-04-10
申请号:BRPI0711285
申请日:2007-04-26
Applicant: BASF AG
Inventor: SCHUBERT MARKUS , MUELLER ULRICH , HESSE MICHAEL , SCHIERLE-ARNDT KERSTIN , OERTEL KAI , FAYE IAN , ALLGEIER THORSTEN , GRAEHN JAN-MICHAEL
IPC: F17C11/00
Abstract: Hydrogen or methane gas pressure container having a minimum volume of 1 m3 a prescribed maximum filling pressure, has a filter through which oxygen, methane respectively, can flow during uptake. The filter has an adsorbent for adsorbing impurities selected from the group consisting of a higher hydrocarbon, ammonia, an odorous substance, hydrogen sulfide and a mixture of two or more of these substances. The pressure container and the filter comprise porous metal organic frameworks as adsorbent.
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公开(公告)号:CA2640300A1
公开(公告)日:2007-08-16
申请号:CA2640300
申请日:2007-02-08
Applicant: BASF AG
Inventor: MULLER ULRICH , SCHUBERT MARKUS , MATTENHEIMER HENDRICK
Abstract: The present invention relates to a process for preparing porous organic frameworks by reaction of a reaction mixture in a liquid phase comprising the appropriate starting compounds in the presence of a nonaqueous organic solvent in the presence of and/or with liberation of water, wherein the latter is withdrawn from the liquid phase of the reaction mixture during the reaction. Here, frameworks having relatively high specific surface areas can be obtained in a reproducible way.
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