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公开(公告)号:SK6132003A3
公开(公告)日:2004-02-03
申请号:SK6132003
申请日:2001-11-22
Applicant: BASF AG
Inventor: WINTERLING HELMUT , FISCHER MICHAEL
Abstract: A process for preparing polyamides comprises polymerizing starting monomers in the presence of from 2.3 to 10 mmol, based on 1 mol of carboxamide group of the polyamide, of a chain regulator containing a nitrile group and a functional group capable of forming a carboxamide group.
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公开(公告)号:DE10217433A1
公开(公告)日:2003-10-30
申请号:DE10217433
申请日:2002-04-18
Applicant: BASF AG
Inventor: WINTERLING HELMUT , DEININGER JUERGEN , KREMPEL KURT
Abstract: A polyamide which contains a monoolefinically unsaturated compound chemically bonded at the end of the polymer chain, a process for preparing this polyamide, a polyamide obtainable by crosslinking this polyamide, and also fibers, films, and moldings, comprising at least one such polyamide.
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公开(公告)号:AR029914A1
公开(公告)日:2003-07-23
申请号:ARP010101992
申请日:2001-04-27
Applicant: BASF AG
Inventor: OHLBACH FRANK , ANSMANN ANDREAS , FISCHER ROLF-HARTMUTH , MELDER JOHANN-PETER , MAIXNER STEFAN , BASSLER PETER , WINTERLING HELMUT , LUYKEN HERMANN
Abstract: Procedimientos para la obtencion de caprolactama, así como procedimientos para la obtencion de polímeros usando caprolactama son generalmente conocidos. Los procedimientos de purificacion del producto citado obtenido tienen la desventaja, que son técnicamente complicados y requieren mucha energía, especialmente, por las numerosas etapas de separacion. Se provee un procedimiento que permite obtener polímeros a base de caprolactama de manera técnicamente sencilla y con ahorro de energía, obteniéndose polímeros con índices característicos de producto comparables con polímeros a base de caprolactama purificados mediante procedimientos técnicamente más complicados y con mayor consumo de energía. Procedimiento para la obtencion de un polímero usando caprolactama en donde: a) se hace reaccionar una mezcla (I) que contiene 6-aminocapronitrilo y agua, dando una mezcla (II) que contiene caprolactama, amoníaco, agua componentes de alto punto de ebullicion y componentes de bajo punto de ebullicion, en presencia de un solido que fomenta catalíticamente la reaccion, luego b) se elimina el amoníaco de la mezcla (II), obteniéndose una mezcla (III) que contienen caprolactama, agua, componentes de alto punto de ebullicion y componentes de bajo punto de ebullicion, luego c) se elimina el agua parcial o completamente de la mezcla (III), obteniéndose una mezcla (IV) que contienen caprolactama, componentes de alto punto de ebullicion y componentes de bajo punto de ebullicion, y luego d) se polimeriza la mezcla (IV), así como un polímero obtenido segun este procedimiento, a su uso para la fabricacion de fibras, materiales de estructura plana y cuerpos moldeados, así como a fibras, materiales de estructura plana y cuerpos moldeados obtenidos usando tal polímero.
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公开(公告)号:CA2407814A1
公开(公告)日:2002-10-31
申请号:CA2407814
申请日:2001-04-30
Applicant: BASF AG
Inventor: MAIXNER STEFAN , ANSMANN ANDREAS , FISCHER ROLF-HARMUTH , BASSLER PETER , WINTERLING HELMUT , OHLBACH FRANK , LUYKEN HERMANN , MELDER JOHANN-PETER
Abstract: The invention relates to a method for producing a polymer. Said method is characterized as follows: a) a mixture (I) containing 6-aminocapronitrile an d water is converted into a mixture (II) containing caprolactam, ammonia, wate r, high boilers and low boilers in the presence of a catalyst; then b) the ammonia is removed from mixture (II) to obtain a mixture (III) containing caprolactam, water, high boilers and low boilers; subsequently c) the water is completely or partially eliminated from mixture (III) to obtain a mixture (I V) containing caprolactam, high boilers and low boilers; and finally d) mixture (IV) is subjected to a polymerization reaction. The invention also relates t o a polymer obtained according to said method, to its use in the production of fibres, flat material and moulded bodies that are obtained using a polymer o f this type.
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公开(公告)号:DE10021191A1
公开(公告)日:2001-11-08
申请号:DE10021191
申请日:2000-05-03
Applicant: BASF AG
Inventor: OHLBACH FRANK , WINTERLING HELMUT , ANSMANN ANDREAS , FISCHER ROLF , MELDER JOHANN-PETER , MAIXNER STEFAN , BASLER PETER , LUYKEN HERMANN
IPC: C08J5/18 , C08G69/04 , C08G69/14 , C08G69/16 , C07D201/08 , C07D201/16 , C07D223/10
Abstract: The invention relates to a method for producing a polymer. Said method is characterized as follows: a) a mixture (I) containing 6-aminocapronitrile and water is converted into a mixture (II) containing caprolactam, ammonia, water, high boilers and low boilers in the presence of a catalyst; then b) the ammonia is removed from mixture (II) to obtain a mixture (III) containing caprolactam, water, high boilers and low boilers; subsequently c) the water is completely or partially eliminated from mixture (III) to obtain a mixture (IV) containing caprolactam, high boilers and low boilers; and finally d) mixture (IV) is subjected to a polymerization reaction. The invention also relates to a polymer obtained according to said method, to its use in the production of fibres, flat material and moulded bodies that are obtained using a polymer of this type.
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公开(公告)号:CZ298974B6
公开(公告)日:2008-03-26
申请号:CZ20031428
申请日:2001-11-22
Applicant: BASF AG
Inventor: WINTERLING HELMUT , FISCHER MICHAEL
Abstract: Zpusob prípravy polyamidu zahrnující polymeraci výchozích monomeru v prítomnosti regulátoru retezceobsahujícího nitrilovou skupinu a funkcní skupinuschopnou tvorby karboxamidové skupiny v množství od 2,3 do 10 mmol, vztaženo na 1 mol karboxamidových skupin polyamidu.
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公开(公告)号:DE502004004653D1
公开(公告)日:2007-09-27
申请号:DE502004004653
申请日:2004-05-06
Applicant: BASF AG
Inventor: WINTERLING HELMUT , DEMETER JUERGEN , DEININGER JUERGEN , KORY GAD , SOETJE OLIVER , WILMS AXEL , WEISS ROBERT , KREMPEL KURT , BENISCH CHRISTOPH
Abstract: Polyamide, whose main chain contains a chemically bound amine selected from the group consisting of 2-methyl-1,5-diaminopentane and 1-amino-2-R-cyclopent-1-ene, where R is a functional group capable of combining with an amino group to form an amide group, and processes for preparing such a polyamide and fibers, films and moldings comprising such a polyamide.
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公开(公告)号:PL1611184T3
公开(公告)日:2007-02-28
申请号:PL04721865
申请日:2004-03-19
Applicant: BASF AG
Inventor: DEININGER JÜRGEN , DEMETER JÜRGEN , KORY GAD , SÖTJE OLIVER , WINTERLING HELMUT , ZEHNER PETER , HEEGER MICHAEL , GANN MARTIN , POLT AXEL , TREULING ULRICH , WEINLE WERNER
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公开(公告)号:DE502004001613D1
公开(公告)日:2006-11-09
申请号:DE502004001613
申请日:2004-03-19
Applicant: BASF AG
Inventor: DEININGER JUERGEN , DEMETER JUERGEN , KORY GAD , SOETJE OLIVER , WINTERLING HELMUT , ZEHNER PETER , HEEGER MICHAEL , GANN MARTIN , POLT AXEL , TREULING ULRICH , WEINLE WERNER
Abstract: Polyamides, oligomers thereof or mixtures thereof, if required with further reaction products, are prepared by reacting aminonitriles or dinitriles and diamines or a mixture containing aminonitrile, dinitrile and diamine, and, if required, further polyamide-forming monomers and/oligomers with water in a reactor ( 1 ) having a vertically oriented longitudinal axis, by a process in which, in the reactor ( 1 ), the reaction product is removed from the bottom and ammonia formed and any further low molecular weight compounds formed and water are taken off via the top ( 2 ), wherein the reactor ( 1 ) has at least two chambers ( 4 ) arranged one on top of the other in the longitudinal direction, the chambers ( 4 ) being separated from one another by liquid-tight trays ( 5 ), each chamber ( 4 ) being connected by a liquid overflow ( 6 ) to the chamber ( 4 ) directly underneath and a liquid product stream being taken off by the liquid overflow ( 6 ) of the lowermost chamber ( 4 ), the gas space ( 7 ) above the liquid level in each chamber ( 4 ) being connected to the chamber ( 4 ) arranged directly above in each case by one or more conduit pipes ( 8 ) which in each case opens or open into a gas distributor ( 9 ) having orifices ( 11 ) for gas exit below the liquid level, and comprising in each case at least one baffle plate ( 12 ) which is arranged vertically around each gas distributor ( 9 ) and whose upper end terminates below the liquid level and whose lower end terminates above the liquid-tight tray ( 5 ) of the chamber ( 4 ) and which separates each chamber ( 4 ) into one or more gassed ( 13 ) and into one or more ungassed ( 14 ) spaces.
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公开(公告)号:AT340819T
公开(公告)日:2006-10-15
申请号:AT04721865
申请日:2004-03-19
Applicant: BASF AG
Inventor: DEININGER JUERGEN , DEMETER JUERGEN , KORY GAD , SOETJE OLIVER , WINTERLING HELMUT , ZEHNER PETER , HEEGER MICHAEL , GANN MARTIN , POLT AXEL , TREULING ULRICH , WEINLE WERNER
Abstract: Polyamides, oligomers thereof or mixtures thereof, if required with further reaction products, are prepared by reacting aminonitriles or dinitriles and diamines or a mixture containing aminonitrile, dinitrile and diamine, and, if required, further polyamide-forming monomers and/oligomers with water in a reactor ( 1 ) having a vertically oriented longitudinal axis, by a process in which, in the reactor ( 1 ), the reaction product is removed from the bottom and ammonia formed and any further low molecular weight compounds formed and water are taken off via the top ( 2 ), wherein the reactor ( 1 ) has at least two chambers ( 4 ) arranged one on top of the other in the longitudinal direction, the chambers ( 4 ) being separated from one another by liquid-tight trays ( 5 ), each chamber ( 4 ) being connected by a liquid overflow ( 6 ) to the chamber ( 4 ) directly underneath and a liquid product stream being taken off by the liquid overflow ( 6 ) of the lowermost chamber ( 4 ), the gas space ( 7 ) above the liquid level in each chamber ( 4 ) being connected to the chamber ( 4 ) arranged directly above in each case by one or more conduit pipes ( 8 ) which in each case opens or open into a gas distributor ( 9 ) having orifices ( 11 ) for gas exit below the liquid level, and comprising in each case at least one baffle plate ( 12 ) which is arranged vertically around each gas distributor ( 9 ) and whose upper end terminates below the liquid level and whose lower end terminates above the liquid-tight tray ( 5 ) of the chamber ( 4 ) and which separates each chamber ( 4 ) into one or more gassed ( 13 ) and into one or more ungassed ( 14 ) spaces.
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