PROCEDIMIENTO PARA LA OBTENCION DE UN POLIMERO, POLIMERO OBTENIDO MEDIANTE EL MISMO; USO DE ESTE ULTIMO Y FIBRAS, MATERIALES DE ESTRUCTURA PLANA Y CUERPOS MOLDEADOS OBTENIDOS USANDO DICHO POLIMERO

    公开(公告)号:AR029914A1

    公开(公告)日:2003-07-23

    申请号:ARP010101992

    申请日:2001-04-27

    Applicant: BASF AG

    Abstract: Procedimientos para la obtencion de caprolactama, así como procedimientos para la obtencion de polímeros usando caprolactama son generalmente conocidos. Los procedimientos de purificacion del producto citado obtenido tienen la desventaja, que son técnicamente complicados y requieren mucha energía, especialmente, por las numerosas etapas de separacion. Se provee un procedimiento que permite obtener polímeros a base de caprolactama de manera técnicamente sencilla y con ahorro de energía, obteniéndose polímeros con índices característicos de producto comparables con polímeros a base de caprolactama purificados mediante procedimientos técnicamente más complicados y con mayor consumo de energía. Procedimiento para la obtencion de un polímero usando caprolactama en donde: a) se hace reaccionar una mezcla (I) que contiene 6-aminocapronitrilo y agua, dando una mezcla (II) que contiene caprolactama, amoníaco, agua componentes de alto punto de ebullicion y componentes de bajo punto de ebullicion, en presencia de un solido que fomenta catalíticamente la reaccion, luego b) se elimina el amoníaco de la mezcla (II), obteniéndose una mezcla (III) que contienen caprolactama, agua, componentes de alto punto de ebullicion y componentes de bajo punto de ebullicion, luego c) se elimina el agua parcial o completamente de la mezcla (III), obteniéndose una mezcla (IV) que contienen caprolactama, componentes de alto punto de ebullicion y componentes de bajo punto de ebullicion, y luego d) se polimeriza la mezcla (IV), así como un polímero obtenido segun este procedimiento, a su uso para la fabricacion de fibras, materiales de estructura plana y cuerpos moldeados, así como a fibras, materiales de estructura plana y cuerpos moldeados obtenidos usando tal polímero.

    METHOD FOR PRODUCING A POLYMER, USING CAPROLACTAM

    公开(公告)号:CA2407814A1

    公开(公告)日:2002-10-31

    申请号:CA2407814

    申请日:2001-04-30

    Applicant: BASF AG

    Abstract: The invention relates to a method for producing a polymer. Said method is characterized as follows: a) a mixture (I) containing 6-aminocapronitrile an d water is converted into a mixture (II) containing caprolactam, ammonia, wate r, high boilers and low boilers in the presence of a catalyst; then b) the ammonia is removed from mixture (II) to obtain a mixture (III) containing caprolactam, water, high boilers and low boilers; subsequently c) the water is completely or partially eliminated from mixture (III) to obtain a mixture (I V) containing caprolactam, high boilers and low boilers; and finally d) mixture (IV) is subjected to a polymerization reaction. The invention also relates t o a polymer obtained according to said method, to its use in the production of fibres, flat material and moulded bodies that are obtained using a polymer o f this type.

    15.
    发明专利
    未知

    公开(公告)号:DE10021191A1

    公开(公告)日:2001-11-08

    申请号:DE10021191

    申请日:2000-05-03

    Applicant: BASF AG

    Abstract: The invention relates to a method for producing a polymer. Said method is characterized as follows: a) a mixture (I) containing 6-aminocapronitrile and water is converted into a mixture (II) containing caprolactam, ammonia, water, high boilers and low boilers in the presence of a catalyst; then b) the ammonia is removed from mixture (II) to obtain a mixture (III) containing caprolactam, water, high boilers and low boilers; subsequently c) the water is completely or partially eliminated from mixture (III) to obtain a mixture (IV) containing caprolactam, high boilers and low boilers; and finally d) mixture (IV) is subjected to a polymerization reaction. The invention also relates to a polymer obtained according to said method, to its use in the production of fibres, flat material and moulded bodies that are obtained using a polymer of this type.

    Polyamidy
    16.
    发明专利

    公开(公告)号:CZ298974B6

    公开(公告)日:2008-03-26

    申请号:CZ20031428

    申请日:2001-11-22

    Applicant: BASF AG

    Abstract: Zpusob prípravy polyamidu zahrnující polymeraci výchozích monomeru v prítomnosti regulátoru retezceobsahujícího nitrilovou skupinu a funkcní skupinuschopnou tvorby karboxamidové skupiny v množství od 2,3 do 10 mmol, vztaženo na 1 mol karboxamidových skupin polyamidu.

    19.
    发明专利
    未知

    公开(公告)号:DE502004001613D1

    公开(公告)日:2006-11-09

    申请号:DE502004001613

    申请日:2004-03-19

    Applicant: BASF AG

    Abstract: Polyamides, oligomers thereof or mixtures thereof, if required with further reaction products, are prepared by reacting aminonitriles or dinitriles and diamines or a mixture containing aminonitrile, dinitrile and diamine, and, if required, further polyamide-forming monomers and/oligomers with water in a reactor ( 1 ) having a vertically oriented longitudinal axis, by a process in which, in the reactor ( 1 ), the reaction product is removed from the bottom and ammonia formed and any further low molecular weight compounds formed and water are taken off via the top ( 2 ), wherein the reactor ( 1 ) has at least two chambers ( 4 ) arranged one on top of the other in the longitudinal direction, the chambers ( 4 ) being separated from one another by liquid-tight trays ( 5 ), each chamber ( 4 ) being connected by a liquid overflow ( 6 ) to the chamber ( 4 ) directly underneath and a liquid product stream being taken off by the liquid overflow ( 6 ) of the lowermost chamber ( 4 ), the gas space ( 7 ) above the liquid level in each chamber ( 4 ) being connected to the chamber ( 4 ) arranged directly above in each case by one or more conduit pipes ( 8 ) which in each case opens or open into a gas distributor ( 9 ) having orifices ( 11 ) for gas exit below the liquid level, and comprising in each case at least one baffle plate ( 12 ) which is arranged vertically around each gas distributor ( 9 ) and whose upper end terminates below the liquid level and whose lower end terminates above the liquid-tight tray ( 5 ) of the chamber ( 4 ) and which separates each chamber ( 4 ) into one or more gassed ( 13 ) and into one or more ungassed ( 14 ) spaces.

    20.
    发明专利
    未知

    公开(公告)号:AT340819T

    公开(公告)日:2006-10-15

    申请号:AT04721865

    申请日:2004-03-19

    Applicant: BASF AG

    Abstract: Polyamides, oligomers thereof or mixtures thereof, if required with further reaction products, are prepared by reacting aminonitriles or dinitriles and diamines or a mixture containing aminonitrile, dinitrile and diamine, and, if required, further polyamide-forming monomers and/oligomers with water in a reactor ( 1 ) having a vertically oriented longitudinal axis, by a process in which, in the reactor ( 1 ), the reaction product is removed from the bottom and ammonia formed and any further low molecular weight compounds formed and water are taken off via the top ( 2 ), wherein the reactor ( 1 ) has at least two chambers ( 4 ) arranged one on top of the other in the longitudinal direction, the chambers ( 4 ) being separated from one another by liquid-tight trays ( 5 ), each chamber ( 4 ) being connected by a liquid overflow ( 6 ) to the chamber ( 4 ) directly underneath and a liquid product stream being taken off by the liquid overflow ( 6 ) of the lowermost chamber ( 4 ), the gas space ( 7 ) above the liquid level in each chamber ( 4 ) being connected to the chamber ( 4 ) arranged directly above in each case by one or more conduit pipes ( 8 ) which in each case opens or open into a gas distributor ( 9 ) having orifices ( 11 ) for gas exit below the liquid level, and comprising in each case at least one baffle plate ( 12 ) which is arranged vertically around each gas distributor ( 9 ) and whose upper end terminates below the liquid level and whose lower end terminates above the liquid-tight tray ( 5 ) of the chamber ( 4 ) and which separates each chamber ( 4 ) into one or more gassed ( 13 ) and into one or more ungassed ( 14 ) spaces.

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