公开(公告)号：BG64232B1

公开(公告)日：2004-06-30

申请号：BG10365899

申请日：1999-08-10

Applicant: BASF AG

Inventor： VON DEYN WOLFGANG ,  HILL REGINA L ,  KARDORFF UWE ,  BAUMANN ERNST ,  ENGEL STEFAN ,  MAYER GUIDO ,  WITSCHEL MATTHIAS ,  RACK MICHAEL ,  GOETZ NORBERT ,  GEBHARDT JOACHIM ,  MISSLITZ ULF ,  WALTER HELMUT ,  WESTPHALEN KARL-OTTO ,  OTTEN MARTINA ,  RHEINHEIMER JOACHIM

IPC: C07D277/10 ,  A01N43/72 ,  A01N43/76 ,  A01N43/78 ,  A01N43/80 ,  C07D231/20 ,  C07D237/00 ,  C07D261/00 ,  C07D261/04 ,  C07D261/20 ,  C07D263/10 ,  C07D273/00 ,  C07D277/20 ,  C07D277/34 ,  C07D291/04 ,  C07D311/00 ,  C07D403/10 ,  C07D413/10 ,  C07D417/10 ,  C07D419/10 ,  C07D498/10

Abstract: The invention relates to benzoyl derivatives with the formula where R1, R2 are hydrogen, nitro, halogen, cyano, alkyl, halogenalkyl, alkoxy, halogenalkoxy, alkylthio, halogenalkylthio, alkylsulphenyl, halogenalkylsulphenyl, alkylsulphonyl or halogenalkyl sulphonyl, R3 is hydrogen, halogen or alkyl, R4 & R5 are hydrogen, halogen, cyano, nitro, alkyl, alkoxy, alkylthio, dialkylamino, phenyl or carbonyl, the latter six groups could be substituted, X is O, S, NR9, CO or CR1OR11; Y is O, S, NR12, CO or CR13R14 and R15, optionally substituted pyrazol which is bound in the 4th place and carries hydroxy- or sulphonyloxygroup in the 5th place. The invention also relates to salts of the derivatives which can be used in agriculture, to a method and intermediate products for their preparation, to forms containing them, and to the application of the derivatives or the forms containing them, as herbicides. 24 claims

公开(公告)号：ES2207988T3

公开(公告)日：2004-06-01

申请号：ES99972625

申请日：1999-11-06

Applicant: BASF AG

Inventor： MAYWALD VOLKER ,  STEINMETZ ADRIAN ,  RACK MICHAEL ,  GOTZ NORBERT ,  GOTZ ROLAND ,  HENKELMANN JOCHEM

IPC: C07D231/20

Abstract: The invention relates to a process for preparing 1-substituted 5- and/or 3-hydroxypyrazoles of the formulae I and IIin which R1 is C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C3-C6-cycloalkyl or C1-C4-alkoxy, where these groups may be substituted by halogen, C1-C4-alkoxy, phenoxy, C1-C6-alkoxycarbonyl, C1-C6-alkylthiocarbonyl or by a cyclic ring system having 3-14 ring atoms, which comprises reactingan alkyl 3-alkoxyacrylate of the formula IIIin which R2, R3 independently of one another are C1-C6-alkyl or C3-C6-cycloalkyl with a hydrazine of the formula IVin which R1 is as defined abovea) at a pH of 6-11 to give 5-hydroxypyrazoles of the formula I orb) at a pH of 11-14 to give 3-hydroxypyrazoles of the formula II.

公开(公告)号：AU2003274037A1

公开(公告)日：2004-05-13

申请号：AU2003274037

申请日：2003-10-17

Applicant: BASF AG

Inventor： REINHARD ROBERT ,  HAMPRECHT GERHARD ,  PUHL MICHAEL ,  SEITZ WERNER ,  RAPADO LILIANA PARRA ,  SCANNELL-LANSKY ANNEGRET ,  GROSSMANN KLAUS ,  SCHIFFER HELMUT ,  WITSCHEL MATTHIAS ,  ZAGAR CYRILL ,  LANDES ANDREAS ,  RACK MICHAEL

IPC: A01N43/36 ,  C07D207/24 ,  C07D207/26 ,  C07D207/277 ,  C07D403/06 ,  C07D405/04 ,  C07D409/04 ,  A01N43/34

Abstract: The invention relates to 1-phenylpyrrolidin-2-one-3-carboxamides of the formula I where the variables R 1 , R 2 , R 3 , X, Y, A, n, R a , R b , R c , R d and R e are as defined in claim 1 and to their agriculturally useful salts. Moreover, the invention relates to the use of compounds I and/or their salts as herbicides; crop protection compositions comprising at least one 1-phenylpyrrolidin-2-one-3-carboxamide of the formula I and/or at least one agriculturally useful salt of I as active substances; and also a method for controlling unwanted vegetation, which comprises allowing a herbicidally effective amount of at least one 1-phenylpyrrolidin-2-one-3-carboxamide of the formula I or an agriculturally useful salt of I to act on plants, their habitat or on seed.

公开(公告)号：ES2203832T3

公开(公告)日：2004-04-16

申请号：ES97954936

申请日：1997-12-19

Applicant: BASF AG

Inventor： HILL REGINA LUISE ,  KARDORFF UWE ,  RACK MICHAEL ,  GOTZ NORBERT ,  BAUMANN ERNST ,  VON DEYN WOLFGANG

IPC: C07D231/20 ,  A01N20060101 ,  A01N43/56 ,  C07D20060101 ,  C07D231/14 ,  C07D231/22 ,  C07D231/24 ,  C07D409/10 ,  C07D409/12

Abstract: PCT No. PCT/EP97/07210 Sec. 371 Date Jun. 23, 1999 Sec. 102(e) Date Jun. 23, 1999 PCT Filed Dec. 19, 1997 PCT Pub. No. WO98/29392 PCT Pub. Date Jul. 9, 1998The invention relates to 4-benzoylpyrazoles of the formula I and their agriculturally useful salts thereof, processes and intermediates; compositions thereof; and use thereof for controlling undesireable plants.

公开(公告)号：PT1131299E

公开(公告)日：2004-02-27

申请号：PT99972625

申请日：1999-11-06

Applicant: BASF AG

Inventor： HENKELMANN JOCHEM ,  RACK MICHAEL ,  GOTZ NORBERT ,  MAYWALD VOLKER ,  GOTZ ROLAND ,  STEINMETZ ADRIAN ,  BECKER HEIKE ,  BAYETO JUAN JOSE AISCAR

IPC: C07D231/20

Abstract: The invention relates to a process for preparing 1-substituted 5- and/or 3-hydroxypyrazoles of the formulae I and IIin which R1 is C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C3-C6-cycloalkyl or C1-C4-alkoxy, where these groups may be substituted by halogen, C1-C4-alkoxy, phenoxy, C1-C6-alkoxycarbonyl, C1-C6-alkylthiocarbonyl or by a cyclic ring system having 3-14 ring atoms, which comprises reactingan alkyl 3-alkoxyacrylate of the formula IIIin which R2, R3 independently of one another are C1-C6-alkyl or C3-C6-cycloalkyl with a hydrazine of the formula IVin which R1 is as defined abovea) at a pH of 6-11 to give 5-hydroxypyrazoles of the formula I orb) at a pH of 11-14 to give 3-hydroxypyrazoles of the formula II.

公开(公告)号：AU2003227654A1

公开(公告)日：2003-11-10

申请号：AU2003227654

申请日：2003-04-22

Applicant: BASF AG

Inventor： RACK MICHAEL ,  WITSCHEL MATTHIAS ,  ZAGAR CYRILL ,  LANDES ANDREAS ,  WAGNER OLIVER

IPC: A01N43/80 ,  C07D261/08 ,  C07D413/04 ,  C07D413/14 ,  C07D417/04

Abstract: 3-Heteroaryl-substituted isoxazolines of the formula I where: X is substituted 5-membered heteroaryl having one to four nitrogen atoms or one to three nitrogen atoms and one oxygen or sulfur atom or one oxygen or sulfur atom; or substituted 6-membered heteroaryl having one to four nitrogen atoms; where the abovementioned 5-membered heteroaryl is not pyrazolyl or thienyl; R 1 -R 7 are hydrogen, alkyl or haloalkyl; Y is unsubstituted or substituted aryl, or benzo[1,4]dioxonyl, benzo[1,3]dioxolanyl, 2,3-dihydrobenzofuranyl or benzimidazole; or unsubstituted or substituted 5- to 6-membered heteroaryl; and their agriculturally useful salts, processes and intermediates for their preparation, and the use of these compounds or of the compositions comprising these compounds for controlling unwanted plants are described.

公开(公告)号：DE59710822D1

公开(公告)日：2003-11-06

申请号：DE59710822

申请日：1997-12-19

Applicant: BASF AG

Inventor： KARDORFF UWE ,  HILL LUISE ,  RACK MICHAEL ,  VON DEYN WOLFGANG ,  ENGEL STEFAN ,  OTTEN MARTINA ,  WITSCHEL MATTHIAS ,  BAUMANN ERNST ,  RHEINHEIMER JOACHIM ,  MAYER GUIDO ,  MISSLITZ ULF ,  WESTPHALEN KARL-OTTO ,  WALTER HELMUT

IPC: A01N33/24 ,  A01N33/26 ,  A01N37/18 ,  A01N37/42 ,  A01N41/10 ,  A01N43/08 ,  A01N43/16 ,  A01N43/18 ,  A01N43/32 ,  C07C45/46 ,  C07C233/65 ,  C07C235/78 ,  C07C243/38 ,  C07C251/60 ,  C07C251/86 ,  C07C259/10 ,  C07C317/44 ,  C07C317/46 ,  C07C327/56 ,  C07D309/04 ,  C07D309/06 ,  C07D319/12 ,  C07D333/28 ,  C07D335/02

Abstract: The invention relates to 2-benzoylcyclohexane-1,3-diones of the formula IwhereR1, R2 are hydrogen, nitro, halogen, cyano, thiocyanato, alkyl, haloalkyl, alkoxyalkyl, alkenyl, alkynyl, -OR5, -OCOR6, -OSO2R6, -SH, -S(O)nR7, -SO2OR5, -SO2NR5R8, -NR8SO2R6 or -NR8COR6;R3 is hydrogen, alkyl, haloalkyl, alkenyl or alkynyl;R4 is hydrogen, unsubstituted or substituted alkyl, cycloalkyl, alkenyl, cycloalkenyl, alkynyl, -COR9, -CO2R9, -COSR9 or -CONR8R9;X is oxygen or sulfur;Z is oxygen or NR8;m is 0 or 1;n is 0, 1 or 2;R5 is hydrogen, alkyl, haloalkyl, alkoxyalkyl, alkenyl or alkynyl;R6 is alkyl or haloalkyl;R7 is alkyl, haloalkyl, alkoxyalkyl, alkenyl or alkynyl;R8 is hydrogen or alkyl;R9 is alkyl, alkenyl, alkynyl, phenyl or benzyl;R10 is alkyl, haloalkyl, alkenyl or alkynyl;Q is an unsubstituted or substituted cyclohexane-1,3-dione ring which is linked in the 2-position;where m is 1 if R3 is hydrogen;and the agriculturally useful salts thereof;processes and intermediates for the preparation of the compounds of the formula I; compositions comprising them; and the use of these derivatives or compositions comprising them for controlling undesired plants.

公开(公告)号：DK0960100T3

公开(公告)日：2003-11-03

申请号：DK97954936

申请日：1997-12-19

Applicant: BASF AG

Inventor： HILL REGINA LUISE ,  KARDORFF UWE ,  RACK MICHAEL ,  GOETZ NORBERT ,  BAUMANN ERNST ,  VON DEYN WOLFGANG ,  ENGEL STEFAN ,  MAYER GUIDO ,  OTTEN MARTINA ,  REINHEIMER JOACHIM ,  WITSCHEL MATTHIAS ,  MISSLITZ ULF ,  WALTER HELMUT ,  WESTPHALEN KARL-OTTO

IPC: C07D231/20 ,  A01N20060101 ,  A01N43/56 ,  C07D20060101 ,  C07D231/14 ,  C07D231/22 ,  C07D231/24 ,  C07D409/10 ,  C07D409/12

Abstract: PCT No. PCT/EP97/07210 Sec. 371 Date Jun. 23, 1999 Sec. 102(e) Date Jun. 23, 1999 PCT Filed Dec. 19, 1997 PCT Pub. No. WO98/29392 PCT Pub. Date Jul. 9, 1998The invention relates to 4-benzoylpyrazoles of the formula I and their agriculturally useful salts thereof, processes and intermediates; compositions thereof; and use thereof for controlling undesireable plants.

公开(公告)号：EA003753B1

公开(公告)日：2003-08-28

申请号：EA200100522

申请日：1999-11-06

Applicant: BASF AG

Inventor： MAYWALD VOLKER ,  STEINMETZ ADRIAN ,  RACK MICHAEL ,  GOETZ ROLAND ,  HENKELMANN JOCHEM ,  BECKER HEIKE ,  AISCAR BAYETO JUAN JOSE ,  GOETZ NORBERT

IPC: C07D231/20

Abstract: Изобретениеотноситсяк способуполучения 1-замещенных 5- и/или 3-гидроксипиразоловформул I и IIгде Rозначает C-Салкил, C-Салкенил, C-Салкинил, C-СциклоалкилилиС-Салкокси, причемэтигруппымогутбытьзамещеныгалогеном, C-Салкокси, фенокси, C-Салкоксикарбонилом, C-Салкилтиокарбониломилициклическойсистемойс 3-14 атомамицикла, причемсложныйалкиловыйэфир 3-алкоксиакриловойкислотыформулы IIIгде R, Rнезависимодруготдругаозначают C-Салкилили C-Сциклоалкил, подвергаютвзаимодействиюс гидразиномформулы IVгде Rимеетвышеприведенноезначение,а) сполучениемпризначениирН, равном 6-11, 5-гидроксипиразоловформулы Iилиб) сполучениемпризначениирН, равном 11-14, 3-гидроксипиразоловформулы II.

公开(公告)号：NZ511645A

公开(公告)日：2003-07-25

申请号：NZ51164599

申请日：1999-11-06

Applicant: BASF AG

Inventor： GOTZ NORBERT ,  GOTZ ROLAND ,  HENKELMANN JOCHEM ,  BECKER HEIKE ,  AISCAR BAYETO JUAN JOSE ,  MAYWALD VOLKER ,  STEINMETZ ADRIAN ,  RACK MICHAEL

IPC: C07D231/20

Abstract: A process for preparing a 1-substituted 5- and/or 3-hydroxypyrazole of the formulae I and II, respectively in which R1 is C1 -C6 -alkyl, C2 -C6 -alkenyl, C2 -C6 -alkynyl, C3 -C6 -cycloalkyl or C1 -C4 -alkoxy. These groups may be substituted by halogen, C1 -C4 -alkoxy, phenoxy, C1 -C6 -alkoxycarbonyl, C1 -C6 -alkylthiocarbonyl or by a cyclic ring system having 3-14 ring atoms. An alkyl vinyl of formula V, reacts with phosgene VIa, "diphosgene" VIb or "triphosgene" VIc, producing an acyl chloride of the formula VII. The alkyl vinyl R2 is C1 -C6 -alkyl or C3 -C6 -cycloalkyl. The acyl chloride is converted by the elimination of hydrogen chloride into 3-alkoxyacryloyl chloride of the formula VIII. Esterifying the 3-alkoxyacryloyl chloride with an alcohol of formula IX, in which R3 is C1 -C6 -alkyl or C3 -C6 -cycloalkyl. This results in the alkyl 3-alkoxyacrylate of the formula III, Reacting the alkyl 3-alkoxyacrylate with a hydrazine of the formula IV, where R1 is defined above a)at a pH of 6-11 to give 5-hydroxypyrazoles of the formula I or b) b) at a pH of 11-14 to give 3-hydroxypyrazoles of the formula II. A 1-substituted 5- and/or 3-hydroxypyrazole of the formulae I and II produced from the above stated process.