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21.发明申请
公开(公告)号：WO2015169831A1
公开(公告)日：2015-11-12
申请号：PCT/EP2015/059919
申请日：2015-05-06
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor： PIEMONTESI, Fabrizio , CATHELIN, Caroline , GUIDOTTI, Simona , LIGUORI, Dario , MORINI, Giampiero , TARTARI, Davide , VITALE, Gianni
IPC: C08F110/06 , C08F210/06 , C08F4/657
CPC classification number: C08F210/06 , C08F210/16 , C08F2500/04 , C08F2500/12 , C08F2500/26 , C08F4/6574
Abstract: Propylene-ethylene copolymers showing an ethylene content of between 0.1 and 10% by weight, a molecular weight distribution (MWD), expressed in terms of Mw/Mn, greater than 3.0 and a content of xylene soluble fraction (XS) and ethylene content (C2) such that the point defined by said values falls below the line given by the equation XS= 1.0296 . e 0.435C2 show high transparency and low melting temperature.
Abstract translation: 丙烯 - 乙烯共聚物，其乙烯含量为0.1〜10重量％，分子量分布（MWD）以Mw / Mn表示，大于3.0，二甲苯可溶成分（XS）含量和乙烯含量（ C2），使得由所述值定义的点落在由等式XS = 1.0296.e0.435C2给出的线下方显示高透明度和低熔融温度。
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公开(公告)号：WO2015135903A1
公开(公告)日：2015-09-17
申请号：PCT/EP2015/054900
申请日：2015-03-10
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor： GUIDOTTI, Simona , DALL'OCCO, Tiziano , LIGUORI, Dario , MORINI, Giampiero , PIEMONTESI, Fabrizio , VITALE, Gianni
IPC: C08F110/02 , C08F110/06 , C08F210/06 , C08F4/657 , C08F4/02 , C08F4/651
CPC classification number: C08F4/64 , C08F4/12 , C08F10/02 , C08F10/06 , C08F4/6545 , C08F4/6465 , C08F4/6574 , C08F110/06 , C08F2500/04 , C08F210/06 , C08F210/16 , C08F2500/12 , C08F4/022 , C08F4/651 , C08F110/02
Abstract: A solid catalyst component for the (co)polymerization of olefins CH 2 =CHR, in which R is hydrogen or a hydrocarbyl radical with 1-12 carbon atoms, comprising Ti, Mg, and Cl, and optionally an electron donor compound selected from the group consisting of ethers, amines, silanes, carbamates ketones, esters of aliphatic acids, alkyl and aryl esters of optionally substituted aromatic polycarboxylic acids, diol derivatives chosen among monoesters monocarbamates and monoesters monocarbonates or mixtures thereof characterized by the fact that it contains from 0.1 to 50%wt of Bi with respect to the total weight of said solid catalyst component.
Abstract translation: 用于烯烃CH 2 = CHR（其中R是氢或具有1-12个碳原子的烃基）的（共）聚合的固体催化剂组分，包含Ti，Mg和Cl，以及任选的电子给体化合物，其选自 由醚，胺，硅烷，氨基甲酸酯酮，脂肪酸的酯，任选取代的芳族多元羧酸的烷基和芳基酯，选自单酯单乳酸单酯和单酯单碳酸酯的二醇衍生物或其混合物，其特征在于其含有0.1至50 Bi的％wt相对于所述固体催化剂组分的总重量。
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公开(公告)号：WO2014184171A1
公开(公告)日：2014-11-20
申请号：PCT/EP2014/059717
申请日：2014-05-13
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor： MIGNOGNA, Alessandro , CHEVALIER, Reynald , GUIDOTTI, Simona , LIGUORI, Dario , MORINI, Giampiero , SCHNEIDER, Martin
CPC classification number: C08F110/06 , C07C271/44 , C07C2601/14 , C07C2602/08 , C08F4/6545 , C08F4/6543 , C08F4/651 , C08F2500/12 , C08F2500/15
Abstract: A solid catalyst component for the polymerization of olefins comprising Mg, Ti, Cl and at least an electron donor compound which is the reaction product obtained by bringing into contact a Mg compound and a Ti compound having at least a Ti-halogen bond with an electron donor selected from specific diphenol derivatives.
Abstract translation: 一种用于烯烃聚合的固体催化剂组分，包括Mg，Ti，Cl和至少一种电子给体化合物，它是通过与Mg化合物和至少具有Ti-卤素键的电子与电子接触而获得的反应产物 供体选自具体的二酚衍生物。
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公开(公告)号：WO2014161905A1
公开(公告)日：2014-10-09
申请号：PCT/EP2014/056625
申请日：2014-04-02
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor： GUIDOTTI, Simona , LIGUORI, Dario , MORINI, Giampiero , PIEMONTESI, Fabrizio
CPC classification number: C08F10/06 , C08F4/6421 , C08F4/6574 , C08F110/06 , C08F2410/01 , C08F2500/15
Abstract: A solid catalyst component for the (co)polymerization of olefins CH 2 =CHR, in which R is a hydrocarbyl radical with 1-12 carbon atoms, optionally in mixture with ethylene, comprising Ti, Mg, Cu, CI, and an electron donor compound characterized by the fact that the Cu/Ti weight ratio is lower than 0.5.
Abstract translation: 用于烯烃CH 2 = CHR（其中R是具有1-12个碳原子的烃基，任选与乙烯混合）的固体催化剂组分，其包含Ti，Mg，Cu，Cl和电子给体化合物 其特征在于Cu / Ti重量比低于0.5。
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公开(公告)号：WO2012052389A1
公开(公告)日：2012-04-26
申请号：PCT/EP2011/068084
申请日：2011-10-17
Applicant: BASELL POLIOLEFINE ITALIA S.R.L. , PATER, Joachim T., M. , GUIDOTTI, Simona , MIGNOGNA, Alessandro , MORINI, Giampiero , VITALE, Gianni
Inventor： PATER, Joachim T., M. , GUIDOTTI, Simona , MIGNOGNA, Alessandro , MORINI, Giampiero , VITALE, Gianni
CPC classification number: C08F10/06 , C08F4/651 , C08F4/6543
Abstract: A process for the preparation of high purity propylene polymers carried out in the presence of a catalyst comprising the product obtained by reacting:- an organo-aluminium compound, with - a solid catalyst component comprising Mg, Ti and electron donor compound selected from specific diolesters, said process being carried out employing an organo-aluminum/propylene ratio equal to or lower than 1.75 mmole/kg.
Abstract translation: 一种用于制备高纯度丙烯聚合物的方法，该催化剂在催化剂存在下进行，所述催化剂包括通过使有机铝化合物与包含Mg，Ti和选自特定二极体的电子给体化合物的固体催化剂组分反应而获得的产物 所述方法使用等于或低于1.75mmol / kg的有机铝/丙烯比进行。
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Patent Agency Ranking
公开(公告)号：WO2012052386A1
公开(公告)日：2012-04-26
申请号：PCT/EP2011/068077
申请日：2011-10-17
Applicant: BASELL POLIOLEFINE ITALIA S.R.L. , PATER, Joachim, T., M. , GUIDOTTI, Simona , MIGNOGNA, Alessandro , Morini, Giampiero , VITALE, Gianni
Inventor： PATER, Joachim, T., M. , GUIDOTTI, Simona , MIGNOGNA, Alessandro , Morini, Giampiero , VITALE, Gianni
CPC classification number: C08F10/06 , C08F110/06 , C08F4/651 , C08F4/6543 , C08F2500/12 , C08F2/34
Abstract: A process for the (co)polymerization of propylene carried out at a temperature ranging from 77 to 95°C in the presence of a catalyst comprising the product obtained by reacting: -an organo-aluminium compound, with -a solid catalyst component comprising Mg, Ti and electron donor compound selected from specific diolesters.
Abstract translation: 在丙烯存在下，在77至95℃的温度下进行丙烯（共）聚合的方法，所述催化剂包含通过以下方法获得的产物： - 有机铝化合物与包含Mg的固体催化剂组分 ，Ti和选自特定二极体的电子给体化合物。
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公开(公告)号：WO2012017038A1
公开(公告)日：2012-02-09
申请号：PCT/EP2011/063447
申请日：2011-08-04
Applicant: BASELL POLIOLEFINE ITALIA S.R.L. , MIGNOGNA, Alessandro , BALBONI, Davide , CRISTOFORI, Antonio , GUIDOTTI, Simona , MORINI, Giampiero , PATER, Jochem T. M.
Inventor： MIGNOGNA, Alessandro , BALBONI, Davide , CRISTOFORI, Antonio , GUIDOTTI, Simona , MORINI, Giampiero , PATER, Jochem T. M.
CPC classification number: C08F10/06 , C08F110/06 , C08F4/651 , C08F2500/12 , C08F2500/15 , C08F4/6545
Abstract: Catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor of Formula (I) in which R, R 1 and R 4 groups, equal to or different from each other, are C 1 -C 15 hydrocarbon groups and the R groups can be linked to form a cycle, R 2 -R 3 groups, equal to or different from each other, are selected from hydrogen and C 1 -C 15 hydrocarbon groups, the R 1 -R 4 groups can optionally contain an heteroatom selected from halogen, P, S, N,O and Si, n is an integer from 0 to 5 and said electron donor and Ti atoms being present in an amount such that their molar ratio is equal to, or lower than, 0.65.
Abstract translation: 包含Mg，Ti和其中R，R 1和R 4基团彼此相同或不同的R，R 1和R 4基团的式（I）的电子给体的烯烃聚合用催化剂组分是C1-C15烃基，R基团可以连接 为了形成一个循环，相同或不同的R2-R3基团选自氢和C1-C15烃基，R1-R4基团可任选地含有选自卤素，P，S，N，O的杂原子 和Si，n为0至5的整数，并且所述电子给体和Ti原子的存在量使得它们的摩尔比等于或低于0.65。
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公开(公告)号：WO2019115610A1
公开(公告)日：2019-06-20
申请号：PCT/EP2018/084554
申请日：2018-12-12
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor： GUIDOTTI, Simona , LIGUORI, Dario , MORINI, Giampiero
IPC: C08F4/657 , C08F4/654 , C08F110/06
CPC classification number: C08F110/06 , C08F2500/12 , C08F2500/15 , C08F4/6545 , C08F4/657
Abstract: A Mg compound based catalyst precursor comprising up 50% by mols, with respect to Mg, of a compound of formula K(OR 1 ) where R 1 is H or a C 1 -C 10 hydrocarbon group. When treated with transition metal compounds the said precursor are converted into catalyst with high activity in olefin polymerization.
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公开(公告)号：WO2018011086A1
公开(公告)日：2018-01-18
申请号：PCT/EP2017/067130
申请日：2017-07-07
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor： DALL'OCCO, Tiziano , GUIDOTTI, Simona , LIGUORI, Dario , MORINI, Giampiero
IPC: C08F210/16 , C08F4/651
Abstract: A catalyst component for the (co)polymerization of olefins, comprising Ti, Mg, halogen, an electron donor (ID) selected from aliphatic cyclic ethers or alkyl esters of aliphatic monocarboxylic acids and a compound of a metal selected from Zn or Cu which is devoid of Zn-C or Cu-C bonds in which the Mg/Ti molar ratio ranges from 4.0 to 50.0 is capable to produce LLDPE with excellent quality due to capability of comonomer randomization.
Abstract translation: 用于烯烃（共）聚合的催化剂组分包括Ti，Mg，卤素，选自脂肪族环状醚或脂肪族一元羧酸的烷基酯的电子供体（ID）和 选自无Zn-C或Cu-C键的Zn或Cu中的Mg / Ti摩尔比范围为4.0-50.0的金属由于共聚单体随机化的能力而能够生产具有优良品质的LLDPE。
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公开(公告)号：WO2013182585A1
公开(公告)日：2013-12-12
申请号：PCT/EP2013/061546
申请日：2013-06-05
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor： MIGNOGNA, Alessandro , GUIDOTTI, Simona , KASHULIN, Igor , MORINI, Giampiero , NIFANT'EV, Ilya , PATER, Joachim T. M.
IPC: C08F4/651 , C08F110/06
CPC classification number: C08F4/52 , C08F4/10 , C08F4/16 , C08F110/08 , C08F4/651 , C08F2500/15 , C08F2500/17 , C08F110/06 , C08F2500/12
Abstract: A catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor compound of the following formula (I) in which the R groups equal to or different from each other, are C 1 -C 15 hydrocarbon groups, the R 1 -R 2 groups, equal to or different from each other, are hydrogen, halogen or C 1 -C 15 hydrocarbon groups, optionally containing an heteroatom selected from halogen, P, S, N and Si, which can be fused together to form one or more cycles; n and m are integer from 0 to 3 with the proviso that at least one of them is different from 0 and that diisobutyl o-phenylenediacetate is excluded.
Abstract translation: 包含Mg，Ti和其中R基彼此相同或不同的下式（I）的电子给体化合物的烯烃聚合催化剂组分是C 1 -C 15烃基，R 1 -R 2基， 相同或不同的是氢，卤素或C 1 -C 15烃基，任选地含有选自卤素，P，S，N和Si的杂原子，其可以一起稠合形成一个或多个循环; n和m是0-3的整数，条件是它们中的至少一个不同于0，并且排除邻苯二乙酸二异丁酯。
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