公开(公告)号：CA2208775C

公开(公告)日：2005-07-05

申请号：CA2208775

申请日：1995-12-16

Applicant: BASF AG

Inventor： MELDER JOHANN-PETER ,  SCHNURR WERNER ,  FLICK KLEMENS ,  EBEL KLAUS ,  REHFINGER ALWIN ,  HARDER WOLFGANG ,  FISCHER ROLF ,  WITZEL TOM

IPC: B01J23/89 ,  B01J23/76 ,  B01J23/889 ,  B01J27/18 ,  B01J37/02 ,  C07B61/00 ,  C07C253/30 ,  C07C255/24

Abstract: Aliphatic alpha,omega-aminonitriles are prepared by partially hydrogenating aliphatic alpha,omega-dinitriles at an increased temperature and pressure in the presence of a solvent and a catalyst. The catalyst contains (a) a compound based on a metal selected from the group made up of nickel, cobalt, iron, ruthenium and rhodium; (b) 0.01 to 25 % by weight in relation to (a) of a promoter based on a metal selected from the group comprising of palladium, platinum, iridiu m, osmium, copper, silver, gold, chromium, molybdenum. tungsten, manganese, rhenium, zinc, cadmium, lead, aluminium, tin, phosphoru s, arsenic, antimony, bismuth, silicium, titanium, zirconium and rare earth metals; and (c) 0 to 5 % by weight in relation to (a) of a compound based on an alkaline or alkaline-earth metal, provided that component (a) not be based on iron or iron and a metal selected from th e group comprising cobalt, ruthenium and rhodium when (b) is a promoter based on a metal selected from the group comprising titanium, manganese, chromium and molybdenum. Moreover, when component (a) is a compound based only on ruthenium or on rhodium, ruthenium and rhodium, or nickel and rhodium, promoter (b) may be dispensed with.

公开(公告)号：ES2224062T3

公开(公告)日：2005-03-01

申请号：ES02722181

申请日：2002-03-06

Applicant: BASF AG

Inventor： WEIGL HAGEN ,  EBEL KLAUS ,  HUBER SYLVIA ,  KUSCHE ANDREAS ,  ELLER KARSTEN ,  HESSE MICHAEL

IPC: B01J23/89 ,  B01J27/045 ,  B01J37/02 ,  B01J37/20 ,  C07B61/00 ,  C07C31/20 ,  C07D307/28 ,  C07D309/18 ,  C07D319/12

Abstract: Procedimiento para la obtención de éteres cíclicos e insaturados de la fórmula general I en la cual Z significa ¿(CHR4)q- o ¿(CHR4)q-O-, q significa 0, 1, 2 o 3, y R1, R2, R3 y R4 significan hidrógeno o alquilo con 1 a 4 átomos de carbono, mediante reacción de dioles de la fórmula general II en la cual tienen Z, R1, R2 y R3 los significados anteriormente indicados, en fase líquida a temperaturas desde 150 hasta 300ºC en presencia de un catalizador soportado, que contiene cobalto y que está dotado de azufre y que no está activado antes de su empleo por reducción, que contiene cobalto y un metal precioso aplicado por impregnación de sol ¿del grupo de platino, paladio, rodio, iridio, rutenio, osmio, renio o sus mezclas ¿ sobre un soporte inerte, caracterizado porque se agrega agua.

公开(公告)号：DE59910608D1

公开(公告)日：2004-11-04

申请号：DE59910608

申请日：1999-01-08

Applicant: BASF AG

Inventor： EBEL KLAUS ,  EIERMANN MATTHIAS ,  NARBESHUBER THOMAS ,  GEHRER EUGEN

IPC: B01J29/00 ,  B01J29/06 ,  B01J29/08 ,  B01J29/40 ,  B01J29/86 ,  C07B61/00 ,  C07C231/12 ,  C07C233/02 ,  C07C233/05 ,  C07D207/26 ,  C07D207/267

Abstract: Molecular sieves, especially zeolites, are used as catalysts for production of N-alkenyl-carboxylic acid amides by dehydration of N-(2-hydroxyalkyl)-carboxylic acid amides and/or respective diethers.

公开(公告)号：AT267156T

公开(公告)日：2004-06-15

申请号：AT00987276

申请日：2000-11-21

Applicant: BASF AG

Inventor： EBEL KLAUS ,  STOCK FRANK

IPC: C07B61/00 ,  C07C29/56 ,  C07C33/02

Abstract: Process for the isomerization of precursor allyl alcohols to product allyl alcohols in the presence of tungsten oxo(VI) complexes comprising additional nitrogen-containing ligands at temperatures of from 50 to 300° C., wherein, in the catalyst, as well as the nitrogen bases known as additional nitrogen-containing ligands, or instead of these nitrogen bases, aminoalcohols such as triethanolamine, diethanolamine, monoethanolamine, tripropanolamine, dipropanolamine, 3-amino-1-propanol, 1-amino-2-propanol, 2-amino-1-propanol, butyldiethanolamine, methyldiisopropanolamine, N,N'-bis(2-hydroxybenzyl)-1,2-diaminoethane or N-(2-hydroxybenzyl)amine are present as additional nitrogen-containing ligands. The process is particularly suitable for the preparation of tertiary product allyl alcohols, such as linalool, by isomerizing primary or secondary allyl alcohols, such as geraniol and nerol.

公开(公告)号：ZA200303030B

公开(公告)日：2004-04-19

申请号：ZA200303030

申请日：2003-04-17

Applicant: BASF AG

Inventor： EBEL KLAUS ,  HAESE FRANK

IPC: C07D215/30 ,  B01J23/30 ,  B01J31/18 ,  B01J31/22 ,  C07B61/00 ,  C07C29/56 ,  C07C33/03 ,  C07C211/65 ,  C07C215/08 ,  C07C215/76 ,  C07D213/16 ,  C07F11/00 ,  C07C ,  B01J

公开(公告)号：CA2459960A1

公开(公告)日：2003-03-27

申请号：CA2459960

申请日：2002-09-03

Applicant: BASF AG

Inventor： WEIGL HAGEN ,  EBEL KLAUS

IPC: C07D471/04 ,  C07D471/14

Abstract: The invention relates to a method for producing imidazo[1, 2-a]-5, 6, 7,8- tetrahydropyridine-8-ones, by reacting .gamma.-butyrolactones with imidazole s. The invention also relates to novel imidazo[1, 2-a]-5, 6, 7,8- tetrahydropyridine-8-ones and the use thereof for producing imidazo[1, 2- a]pyridines.

公开(公告)号：ES2169381T3

公开(公告)日：2002-07-01

申请号：ES97919014

申请日：1997-09-01

Applicant: BASF AG

Inventor： EBEL KLAUS ,  FISCHER ROLF ,  FLICK KLEMENS ,  MERGER MARTIN ,  VOIT GUIDO

IPC: B01J23/78 ,  C07B61/00 ,  C07C209/48 ,  C07C211/12 ,  C07C253/30 ,  C07C255/24

Abstract: A process for preparing aliphatic alpha,omega-amino nitrites by partial hydrogenation of aliphatic alpha,omega-dinitriles in the presence of a catalyst, wherein the catalyst used for the partial hydrogenation comprises(a) iron or a compound based on iron or mixtures thereof and(b) from 0.01 to 5% by weight, based on (a), of a promoter based on 2,3,4 or 5 elements selected from the group consisting of aluminum, silicon, zirconium, titanium and vanadium and(c) from 0 to 5% by weight, based on (a), of a compound based on an alkali metal or alkaline earth metal.

公开(公告)号：ZA200104256B

公开(公告)日：2002-05-24

申请号：ZA200104256

申请日：2001-05-24

Applicant: BASF AG

Inventor： EIERMANN MATTHIAS ,  TRAGUT CHRISTIAN ,  EBEL KLAUS

IPC: C07C303/16 ,  C07C309/04 ,  C07C

Abstract: The invention relates to a process for the prepartaion of alkanesulfonic acids, comprising the following steps:(a) oxidation of alkylmercaptans and/or dialkyl disulfides and/or dialkyl polysulfides having from three to nine sulfur atoms with nitric acid to form alkanesulfonic acids, water, nitrogen oxides and other byproducts,(b) regeneration of the nitrogen oxides obtained from step (a) with oxygen to give nitric acid and recycling of the nitric acid to step (a),where steps (a) and (b) are carried out in reaction chambers separate from one another.

公开(公告)号：PL347973A1

公开(公告)日：2002-05-06

申请号：PL34797399

申请日：1999-11-22

Applicant: BASF AG

Inventor： EIERMANN MATTHIAS ,  TRAGUT CHRISTIAN ,  EBEL KLAUS

IPC: C07C303/16 ,  C07C309/04

Abstract: The invention relates to a process for the prepartaion of alkanesulfonic acids, comprising the following steps:(a) oxidation of alkylmercaptans and/or dialkyl disulfides and/or dialkyl polysulfides having from three to nine sulfur atoms with nitric acid to form alkanesulfonic acids, water, nitrogen oxides and other byproducts,(b) regeneration of the nitrogen oxides obtained from step (a) with oxygen to give nitric acid and recycling of the nitric acid to step (a),where steps (a) and (b) are carried out in reaction chambers separate from one another.

公开(公告)号：DE10047163A1

公开(公告)日：2002-04-11

申请号：DE10047163

申请日：2000-09-22

Applicant: BASF AG

Inventor： EIERMANN MATTHIAS ,  EBEL KLAUS

IPC: C07C201/06 ,  C07B43/02 ,  C07B61/00 ,  C07C201/08 ,  C07C205/06 ,  C07C253/30

Abstract: A method for the nitration of aromatic hydrocarbons (I) by liquid-phase reaction with a nitrogen oxide (NO, N2O3, NO2 or N2O4) and an oxygen-containing gas stream in presence of a heterogeneous oxide catalyst, in which the reaction is started in presence of at least 0.1 mol% water (based on I).