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公开(公告)号:DE4139256A1
公开(公告)日:1993-06-03
申请号:DE4139256
申请日:1991-11-29
Applicant: BASF AG
Inventor: EVERTZ KASPAR DR , SAIVE ROLAND DR , FUNK GUIDO DR , KOELLE PETER DR , KONRAD RAINER DR
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22.
公开(公告)号:AT74930T
公开(公告)日:1992-05-15
申请号:AT87115311
申请日:1987-10-20
Applicant: BASF AG
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公开(公告)号:DE59306422D1
公开(公告)日:1997-06-19
申请号:DE59306422
申请日:1993-02-03
Applicant: BASF AG
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公开(公告)号:ES2098081T3
公开(公告)日:1997-04-16
申请号:ES94111341
申请日:1994-07-21
Applicant: BASF AG
Inventor: LUX MARTIN DR , FUNK GUIDO DR , SAIVE ROLAND DR , GOERTZ HANS-HELMUT DR , KONRAD RAINER DR
IPC: C09K3/16 , C08F2/34 , C08F2/44 , C08F10/00 , C08F10/02 , C08F110/02 , C08K5/17 , C08K5/20 , C08L23/02
Abstract: A process for the preparation of homopolymers of ethylene or copolymers of ethylene with secondary amounts of other C3- to C12-alk-1-enes by catalytic polymerisation in a suspension or in the gas phase in the presence of an antistatic at a temperature of from 50 to 120 DEG C and at a pressure of from 5 to 50 bar, characterised in that the antistatic employed is a mixture of the following substances: a) a metal salt of medialanic acid of formula (I) , b) a metal salt of an anthranilic acid of formula (II) , where the organic radical R is either alpha ) -CO-(CH2)x-CH3 (III alpha ) or ss) -CO-(CH2)y-CH=CH-(CH2)z-CH3 (IIIss), where x, y and z are each an integer, and x is in the range from 6 to 18, y is in the range from 1 to 16, z is in the range from 1 to 16 and y + z is in the range from 4 to 17, and c) a polyamine obtainable by reacting epichlorohydrin with an aliphatic primary monoamine or an N-alkylalkylenediamine of the formula (IV> R NH-R -NH2 (IV), where R is a C8-C24-alkyl radical and R is a C2-C6-alkylene radical. d
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公开(公告)号:DE59401850D1
公开(公告)日:1997-04-03
申请号:DE59401850
申请日:1994-07-21
Applicant: BASF AG
Inventor: LUX MARTIN DR , FUNK GUIDO DR , SAIVE ROLAND DR , GOERTZ HANS-HELMUT DR , KONRAD RAINER DR
IPC: C09K3/16 , C08F2/34 , C08F2/44 , C08F10/00 , C08F10/02 , C08F110/02 , C08K5/17 , C08K5/20 , C08L23/02
Abstract: A process for the preparation of homopolymers of ethylene or copolymers of ethylene with secondary amounts of other C3- to C12-alk-1-enes by catalytic polymerisation in a suspension or in the gas phase in the presence of an antistatic at a temperature of from 50 to 120 DEG C and at a pressure of from 5 to 50 bar, characterised in that the antistatic employed is a mixture of the following substances: a) a metal salt of medialanic acid of formula (I) , b) a metal salt of an anthranilic acid of formula (II) , where the organic radical R is either alpha ) -CO-(CH2)x-CH3 (III alpha ) or ss) -CO-(CH2)y-CH=CH-(CH2)z-CH3 (IIIss), where x, y and z are each an integer, and x is in the range from 6 to 18, y is in the range from 1 to 16, z is in the range from 1 to 16 and y + z is in the range from 4 to 17, and c) a polyamine obtainable by reacting epichlorohydrin with an aliphatic primary monoamine or an N-alkylalkylenediamine of the formula (IV> R NH-R -NH2 (IV), where R is a C8-C24-alkyl radical and R is a C2-C6-alkylene radical. d
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公开(公告)号:ES2096703T3
公开(公告)日:1997-03-16
申请号:ES92119651
申请日:1992-11-19
Applicant: BASF AG
Inventor: RIEGER BERNHARD DR , LILGE DIETER DR , EVERTZ KASPAR DR , KONRAD RAINER DR
IPC: C08F4/622 , C08F4/642 , C08F4/646 , C08F4/659 , C08F4/6592 , C08F4/68 , C08F210/02 , C08F210/16
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公开(公告)号:AT149183T
公开(公告)日:1997-03-15
申请号:AT94111341
申请日:1994-07-21
Applicant: BASF AG
Inventor: LUX MARTIN DR , FUNK GUIDO DR , SAIVE ROLAND DR , GOERTZ HANS-HELMUT DR , KONRAD RAINER DR
IPC: C09K3/16 , C08F2/34 , C08F2/44 , C08F10/00 , C08F10/02 , C08F110/02 , C08K5/17 , C08K5/20 , C08L23/02
Abstract: A process for the preparation of homopolymers of ethylene or copolymers of ethylene with secondary amounts of other C3- to C12-alk-1-enes by catalytic polymerisation in a suspension or in the gas phase in the presence of an antistatic at a temperature of from 50 to 120 DEG C and at a pressure of from 5 to 50 bar, characterised in that the antistatic employed is a mixture of the following substances: a) a metal salt of medialanic acid of formula (I) , b) a metal salt of an anthranilic acid of formula (II) , where the organic radical R is either alpha ) -CO-(CH2)x-CH3 (III alpha ) or ss) -CO-(CH2)y-CH=CH-(CH2)z-CH3 (IIIss), where x, y and z are each an integer, and x is in the range from 6 to 18, y is in the range from 1 to 16, z is in the range from 1 to 16 and y + z is in the range from 4 to 17, and c) a polyamine obtainable by reacting epichlorohydrin with an aliphatic primary monoamine or an N-alkylalkylenediamine of the formula (IV> R NH-R -NH2 (IV), where R is a C8-C24-alkyl radical and R is a C2-C6-alkylene radical. d
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公开(公告)号:DE58909684D1
公开(公告)日:1996-06-27
申请号:DE58909684
申请日:1989-11-07
Applicant: BASF AG
Inventor: SAIVE ROLAND DR , FUNK GUIDO DR , SCHMIDT-THUEMMES JUERGEN DR , KONRAD RAINER DR , BAUER PETER
IPC: C08F2/00 , C08F2/14 , C08F2/34 , C08F6/00 , C08F4/68 , C08F6/06 , C08F8/00 , C08F8/14 , C08F10/02 , C08F210/16
Abstract: The invention relates to a process for the preparation of low-pressure ethylene polymers by polymerising the monomers in the presence of a Ziegler catalyst system, in which process the solid ethylene polymer obtained is reacted in the melt with additives which are able to form acids by esterification. The ester-forming additives are preferably epoxide compounds.
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公开(公告)号:AT138394T
公开(公告)日:1996-06-15
申请号:AT89120554
申请日:1989-11-07
Applicant: BASF AG
Inventor: SAIVE ROLAND DR , FUNK GUIDO DR , SCHMIDT-THUEMMES JUERGEN DR , KONRAD RAINER DR , BAUER PETER
IPC: C08F6/00 , C08F2/00 , C08F2/14 , C08F2/34 , C08F4/68 , C08F6/06 , C08F8/00 , C08F8/14 , C08F10/02 , C08F210/16
Abstract: The invention relates to a process for the preparation of low-pressure ethylene polymers by polymerising the monomers in the presence of a Ziegler catalyst system, in which process the solid ethylene polymer obtained is reacted in the melt with additives which are able to form acids by esterification. The ester-forming additives are preferably epoxide compounds.
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公开(公告)号:DE59001946D1
公开(公告)日:1993-08-19
申请号:DE59001946
申请日:1990-04-30
Applicant: BASF AG
Inventor: BAUER PETER , KONRAD RAINER DR , MORGENSTERN HERBERT , SCHUCH HORST DR
Abstract: For producing extrudates from ultra-high molecular weight polyethylene, the cooled feed zone of a single-screw extruder is charged with particulate to powdered polyethylene, which is compressed, melted in a conveying zone of the extruder and discharged with the extrudate being moulded into shape and cooled. In this method, the polyethylene is worked in the conveying zone with a shear rate in the radial clearance between screw shaft and extruder barrel of 50 to 1000 sec , is heated to a temperature of 180 to 280 DEG C and is subsequently transferred into a zone without any screw shaft, in which the final moulding of the extrudate takes place.
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