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    Prepn. of E-oxime ether(s) of phenyl-glyoxylic acid ester(s)
    21.
    发明专利
    Prepn. of E-oxime ether(s) of phenyl-glyoxylic acid ester(s) 未知

    公开(公告)号：DE4042273A1

    公开(公告)日：1992-07-02

    申请号：DE4042273

    申请日：1990-12-31

    Applicant: BASF AG

    Inventor： WINGERT HORST DR ,  WOLF BERND DR ,  BENOIT REMY DR ,  SAUTER HUBERT DR ,  HEPP MICHAEL DR ,  GRAMMENOS WASSILIOS DR ,  KUEKENHOEHNER THOMAS DR

    IPC: C07C51/367 ,  C07C65/24 ,  C07C69/738 ,  C07C235/34 ,  C07C249/08 ,  C07C251/48 ,  C07C253/14 ,  C07C255/17 ,  C07C317/24

    Abstract: Prepn. of E-oxime-ethers of phenylglyoxylic acid esters of formula (I) comprises (a) reacting a phenol Xm-Ph-PH in a base in the presence of a solvent to give a phenolate; (b) mixing with a lactone of formula (III); (c) distilling off solvent and reacting the mixt. at 50-250 deg.C in the melt; (d) washing with water and acid to give a 2-phenoxymethylbenzoic acid of formula (IV); Q = OH); (e) treating with phosgene or SOCl2 to give the 2-phenoxymethylbenzoyl chloride (IV; Q = Cl); (f) reacting with alkali(ne earth)metal cyanide opt. in the presence of prussic acid; (g) treating the 2-phenoxymethylbenzoyl cyanide (IV; Q = CN) with MeOH in the presence of acid to give (VIIb); (h) opt. splitting under acidic conditions to give (IV; Q = C(O)NHR) or (i) treating (IV; Q=R) with dimethyl sulphoxide in the presence of a base to give a beta ketosulphoxide (IV; Q = CH2SOCH3) and treating with a halogenating agent, and MeOH in acid to give (IV; Q = C(O)OMe); (k) reacting (IV; Q = C(O)OMe) and/or (VIIb) with O-methylhydroxylamine or its acid addn. salt to give (I). Q = R1CH2SOMe, OH, Cl, CN or C(O)NNR; X, Y = halo, 1-4C alkyl, 1-4C alkoxy or CF3; m = 0-4; n = 0-3; R = 1-4C alkyl.

    New amino-carbonyl-substd. iso-thiazole or isoxazole carboxylic acid d
    25.
    发明专利
    New amino-carbonyl-substd. iso-thiazole or isoxazole carboxylic acid d 未知

    公开(公告)号：DE3933898A1

    公开(公告)日：1991-04-18

    申请号：DE3933898

    申请日：1989-10-11

    Applicant: BASF AG

    Inventor： MAYWALD VOLKER DR ,  KUEKENHOEHNER THOMAS DR ,  FREUND WOLFGANG DR ,  HAMPRECHT GERHARD DR ,  WUERZER BRUNO DR ,  WESTPHALEN KARL-OTTO DR

    IPC: A01N43/80 ,  C07D261/18 ,  C07D275/02 ,  C07D275/03

    Abstract: Aminocarbonyl-substd. isoxazole and isothiazole derivs. of formula (Ia)-(Id) are new: X = O or S; R1 = H; halo; 1-6C alkyl; 1-4C alkoxy or alkylthio; benzyl; phenyl; phenoxy or phenylthio; 5-6 membered, satd. or aromatic heterocycle contg. 1 or 2 O, S or N, and opt. substd. by 1 or 2 halo, 1-3C alkyl, alkoxy or alkoxycarbonyl; 3-8C cycloalkyl(1-6C)alkyl; 2-6C alkenyl or alkynyl, both opt. substd. by 1-3 halo or 1-3C alkoxy and/or by one cyclopropyl or phenyl; or 3-8C cycloalkyl or 3-6C cycloalkenyl, both opt. substd. by 1-3 1-4C alkyl or halo; R'1 = 3-8C cycloalkyl(1-6C)alkyl; 2-6C alkenyl or alkynyl as for R1, or 3-6C cycloalkenyl opt. substd. by 1-3 halo or 1-4C alkyl; R2 = HCO, 4,5-dihydrooxazol-2-yl, COYR5 or CONR6R7; Y = O or S; R5 = H; 1-6C alkyl; R3 = H, 1-6C alkyl; R4 = H; OH, 1-4C alkoxy; 1-6C alkyl, etc., their environmentally acceptable salts are included.

    27.
    发明专利
    未知

    公开(公告)号：DE3918015A1

    公开(公告)日：1990-12-06

    申请号：DE3918015

    申请日：1989-06-02

    Applicant: BASF AG

    Inventor： HUELLMANN MICHAEL DR ,  KUEKENHOEHNER THOMAS DR ,  BRENNER KARL ,  BECKER RAINER DR ,  SCHOMMER CHARLES DR ,  IRGANG MATTHIAS DR

    IPC: B01J23/04 ,  B01J23/10 ,  B01J21/06 ,  B01J23/12 ,  C07B61/00 ,  C07C45/30 ,  C07C45/61 ,  C07C45/62 ,  C07C45/66 ,  C07C45/67 ,  C07C45/68 ,  C07C45/72 ,  C07C49/203 ,  C07C49/385

    Abstract: The muscone of the formula I is prepared by bringing open-chain 2,15-diketones of the general formula II CH3-CO-X-CO-CH3 (II> in which X represents one of the radicals -(-CH2-)@(a> -CH=CH-(-CH2-)@CH=CH- (b> -CH2-CH=CH-(-CH2-)@CH=CH-CH2- (c> -CH2-CH2-CH=CH-(-CH2-)@CH=CH-CH2-CH2- (d) or -CH2-CH2-CH2-CH=CH-(-CH2-)@CH=CH-CH2-CH2-CH2- (e), into contact at temperatures of 300 to 400 DEG C in the presence of 5 to 15 % by weight of water, relative to the amount of catalyst, in the gas phase over a fixed-bed catalyst which contains TiO2, CeO2 or ThO2 as the catalytically active compound and hydrogenating catalytically the unsaturated cyclic ketone formed in this reaction by intramolecular aldol condensation. Furthermore, the open-chain unsaturated ketones of the formulae IIb, IIc and IId and advantageous processes for their preparation and their use as intermediates for a simple industrial muscone synthesis are claimed.

    29.
    发明专利
    未知

    公开(公告)号：DE3905238A1

    公开(公告)日：1990-08-23

    申请号：DE3905238

    申请日：1989-02-21

    Applicant: BASF AG

    Inventor： SCHUBERT JUERGEN DR ,  WILD JOCHEN DR ,  HARREUS ALBRECHT DR ,  KUEKENHOEHNER THOMAS DR ,  SAUTER HUBERT DR ,  AMMERMANN EBERHARD DR ,  LORENZ GISELA DR

    IPC: A01N43/40 ,  C07D213/84

    Abstract: 2-Anilino-cyanopyridines of the formula in which X represents NO2, CN, halogen, SO2-alkyl, alkyl, cycloalkyl, haloalkyl, alkoxy, or represents phenoxy or phenylthio, each of which is optionally substituted in the phenyl radical, m represents an integer from 1-3, R represents hydrogen, halogen, alkoxy, haloalkyl, haloalkoxy, or represents phenoxy or phenylthio, each of which is optionally substituted in the phenyl radical, R and R represent hydrogen, NO2, halogen, CN, alkyl, SO2-alkyl, haloalkyl, SO2NR R , haloalkoxy, COOR , CONR R , R represents hydrogen, COOR , CONR R , CHO, COR , SO2R , C3-C6-alkenyl, C3-C6-alkynyl, and salts of the 2-anilino-cyanopyridines in which R represents hydrogen, with cations which are tolerated by plants, and fungicides containing these compounds.

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