公开(公告)号：DE4304002A1

公开(公告)日：1994-08-18

申请号：DE4304002

申请日：1993-02-11

Applicant: BASF AG

Inventor： MERGER FRANZ DR ,  BRUDERMUELLER MARTIN DR ,  PRIESTER CLAUS-ULRICH DR ,  WITZEL TOM DR ,  VOIT GUIDO DR ,  HARDER WOLFGANG DR ,  FRIEDRICH WOLFGANG ,  FRANZ DIETER DR

IPC: C07C253/30 ,  C07C255/12 ,  C07C255/24

公开(公告)号：ES2047961T3

公开(公告)日：1994-03-01

申请号：ES91104288

申请日：1991-03-20

Applicant: BASF AG

Inventor： MERGER FRANZ DR ,  PRIESTER CLAUS-ULRICH DR ,  WITZEL TOM DR ,  KOPPENHOEFER GERHARD DR ,  HARDER WOLFGANG DR

IPC: B01J21/04 ,  B01J21/06 ,  B01J23/46 ,  B01J27/18 ,  C07B61/00 ,  C07C209/00 ,  C07C209/26 ,  C07C209/48 ,  C07C209/52 ,  C07C211/36

Abstract: Process for the preparation of 3-aminomethyl-3,5,5-trimethylcyclohexylamine from 3-cyano-3,5,5-trimethylcyclohexanone by carrying out the following steps in two reaction spaces spatially separated from one another: a) reacting the 3-cyano-3,5,5-trimethylcyclohexanone in a first reaction space with excess ammonia over acid metal oxide catalysts at temperatures of 20 to 150 DEG C and pressures of 15 to 500 bar and b) hydrogenating the reaction products formed in a second reaction space with hydrogen in the presence of excess ammonia over cobalt-, nickel-, ruthenium- and/or other noble metal-containing catalysts which may contain basic components or are present on neutral or basic supports at temperatures of 60 to 150 DEG C and pressures of 50 to 300 bar.

公开(公告)号：DE4215087A1

公开(公告)日：1993-11-11

申请号：DE4215087

申请日：1992-05-07

Applicant: BASF AG

Inventor： FUCHS HUGO DR ,  NEUBAUER GERALD DR ,  RITZ JOSEF DR ,  PRIESTER CLAUS-ULRICH DR

IPC: C07D201/12 ,  C07D223/10 ,  C08G69/14 ,  C08J11/14 ,  C08J11/16 ,  C08L77/02 ,  C08G69/46

Abstract: Process for the recovery of caprolactam from polycaprolactam by hydrolytic cleavage of polycaprolactam with 5 to 50 parts by weight of water per part by weight of polycaprolactam at a temperature from 200 to 350 DEG C at elevated pressure with the production of an aqueous solution or suspension which contains monomeric caprolactam, its oligomer and optionally polycaprolactam and subsequent removal of monomeric caprolactam from the aqueous solution or suspension by distillation or extraction, the hydrolytic cleavage being carried out at a pH from 5 to 10 with the additional use of alkali metal hydroxide.

公开(公告)号：DE58902281D1

公开(公告)日：1992-10-22

申请号：DE58902281

申请日：1989-07-01

Applicant: BASF AG

Inventor： MERGER FRANZ DR ,  HARDER WOLFGANG DR ,  HETTINGER PETER DR ,  PRIESTER CLAUS-ULRICH DR ,  FRANZ DIETER DR ,  VOGES DIETER DR

IPC: C07C253/18 ,  C07C255/12 ,  C07C255/13 ,  C07C255/24

公开(公告)号：DE4106340A1

公开(公告)日：1992-09-03

申请号：DE4106340

申请日：1991-02-28

Applicant: BASF AG

Inventor： MERGER FRANZ DR ,  PRIESTER CLAUS-ULRICH DR ,  WITZEL TOM DR ,  KOPPENHOEFER GERHARD DR ,  SCHUSTER LUDWIG DR

IPC: C07C209/48 ,  C07C211/09

Abstract: New 2,2-disubstituted pentane-1,5-diamines of formula H2N-(CH2)3-C(R1)(R2)-CH2NH2 (I) (in which R1 and R2 independently = 1-10C alkyl or 2-10C alkenyl or R1 and R2 together form a 4-7C alkylene chain which is opt. substd. by 1-5 1-4C alkyl gps), are prepd. from 2,2-disubstituted 4-cyano-butanals of formula NC-(CH2)2-C(R1)(R2)-CH=O (II) by (a) reacting the (II) in a first reaction chamber with excess ammonia over an a acidic heterogeneous catalyst at temps. of 20-150 deg.C and a pressure of 15-500 bar, and (b) hydrogenating the reaction prods. in a second reaction chamber with hydrogen in the presence of excess ammonia over Co-, Ni-, Ru- and/or other noble metal contg. catalysts, opt. with basic components or on basic or neutral carriers, at temps. of 60-150 deg. C and a press. of 50-500 bar. Pref. in (I) R1 and R2 are both both Me. Claimed cpds. (I) are 2-methyl-2-n-propyl- pentane-1,5-diamine (Ia), 2-n-butyl-2-ethyl-pentane-1,5-diamine (Ib) and 2-n-propyl-2-n-propyl-pentane-1,5-diamine (Ic).

公开(公告)号：DE3780318D1

公开(公告)日：1992-08-20

申请号：DE3780318

申请日：1987-01-23

Applicant: BASF AG

Inventor： HUTMACHER HANS-MARTIN ,  BROECKER FRANZ JOSEF DR ,  MERGER FRANZ DR ,  FISCHER ROLF DR ,  VAGT UWE DR ,  SCHNEIDER HEINZ-WALTER DR ,  RICHTER WOLFGANG DR ,  HARDER WOLFGANG DR ,  PRIESTER CLAUS-ULRICH DR

IPC: C07B61/00 ,  B01J21/16 ,  B01J23/00 ,  B01J23/74 ,  B01J23/755 ,  B01J25/02 ,  C07C67/00 ,  C07C227/00 ,  C07C227/04 ,  C07C227/08 ,  C07C229/04 ,  C07C229/08

Abstract: Esters of 6-aminocaproic acid are prepd. by reacting esters of 5-formyl-valeric acid with NH3 and H2, with alcohols as solvents, in presence of hydrogenation catalysts under increased pressure and at 40-95 deg. C. Pref. the catalyst is (i) prepd. by calcination of: ((MgaNi(II)bCo(II)cAl2)CO3(OH)16.4H2O at 200-600 deg. C, followed by redn. with H2 at raised temp., or (ii) 30-60 wt.% of finely divided Ni pptd. on Mg silicate. In the formulae, a = 0-4; b, c = 0-6; 2 x (a+b+c) = 12. Pref. alkanol solns. of 5-formyl valeric acid esters are led with NH3 over a fixed bed catalyst. Raney Ni or Raney Co may be used in a suspension process, opt. fixed in the reaction zone (electro)-magnetically. The catalyst is 0.2-2 kg of 5-formylvaleric acid ester/l of catalyst/h. Partic. methyl 5-formylvalerate is used, in soln. in methanol.

公开(公告)号：DE4021726A1

公开(公告)日：1992-01-09

申请号：DE4021726

申请日：1990-07-07

Applicant: BASF AG

Inventor： MERGER FANZ DR ,  PRIESTER CLAUS-ULRICH DR ,  WITZEL TOM DR ,  KOPPENHOEFER GERHARD DR ,  SCHUSTER LUDWIG DR

IPC: C07C209/48 ,  C07C211/09

Abstract: New 2,2-disubstituted pentane-1,5-diamines of formula H2N-(CH2)3-C(R1)(R2)-CH2NH2 (I) (in which R1 and R2 independently = 1-10C alkyl or 2-10C alkenyl or R1 and R2 together form a 4-7C alkylene chain which is opt. substd. by 1-5 1-4C alkyl gps), are prepd. from 2,2-disubstituted 4-cyano-butanals of formula NC-(CH2)2-C(R1)(R2)-CH=O (II) by (a) reacting the (II) in a first reaction chamber with excess ammonia over an a acidic heterogeneous catalyst at temps. of 20-150 deg.C and a pressure of 15-500 bar, and b) hydrogenating the reaction prods. in a second reaction chamber with hydrogen in the presence of excess ammonia over Co-, Ni-, Ru- and/or other noble metal contg. catalysts, opt. with basic components or on basic or neutral carriers, at temps. of 60-150 deg. C and a press. of 50-500 bar. Pref. in (I) R1 and R2 are both both Me. Claimed cpds. (I) are 2-methyl-2-n-propyl- pentane-1,5-diamine (Ia), 2-n-butyl-2-ethyl-pentane-1,5-diamine (Ib) and 2-n-propyl-2-n-propyl-pentane-1,5-diamine (Ic).

公开(公告)号：DE4020422A1

公开(公告)日：1992-01-02

申请号：DE4020422

申请日：1990-06-27

Applicant: BASF AG

Inventor： PATSCH MANFRED DR ,  MARSCHNER CLAUS DR ,  PRIESTER CLAUS-ULRICH DR

IPC: C09B19/00 ,  C09B62/002 ,  C09B62/02 ,  C09B62/04 ,  C09B62/44 ,  C09B62/503

Abstract: Triphendioxazine dyes suitable for dyeing or printing hydroxyl- or amido-containing substrates have the formula where n is 0 or 1, m is 1 or 2, R1 and R2 are each independently of the other hydrogen, chlorine, bromine, hydroxysulfonyl, C1-C4-alkyl, C1-C4-alkoxy, substituted or unsubstituted phenyl or substituted or unsubstituted phenoxy, R3 is halogen, carboxyl, C1-C4-alkyl, C1-C4-alkoxy, vinylsulfonyl or the radical -SO2-CH2CH2-Z, where Z is a leaving group, and Q1 and Q2 are each independently of the other a radical of the formula where R4 and R5 are each independently of the other hydrogen, C1-C4-alkyl or phenyl, R6 is hydrogen or a fiber-reactive radical, L1 and L2 are each independently of the other substituted or unsubstituted C2-C8-alkylene or phenylene, X is a chemical bond, oxygen, sulfur, imino, C1-C4-alkylimino, carbonyl or methylene, and Y is oxygen or sulfur, with the proviso that if n is 0, R6 is a fiber-reactive radical, and that the hydroxysulfonyl groups are each ortho to the substituents Q1 and Q2.

公开(公告)号：DE4010254A1

公开(公告)日：1991-10-02

申请号：DE4010254

申请日：1990-03-30

Applicant: BASF AG

Inventor： MERGER FRANZ DR ,  PRIESTER CLAUS-ULRICH DR ,  KOPPENHOEFER GERHARD DR ,  HARDER WOLFGANG DR ,  WITZEL TOM DR ,  LERMER HELMUT DR ,  KOEHLER ULRICH DR

IPC: B01J23/40 ,  B01J23/74 ,  B01J29/06 ,  C07B61/00 ,  C07C209/00 ,  C07C209/26 ,  C07C209/48 ,  C07C211/36

Abstract: Process for the preparation of 2-(3-aminopropyl)cycloalkylamines of the general formula I in which the index n is an integer from 1 to 4, from 2-(2-cyanoethyl)cycloalkanones of the general formula II in which the index n has the abovementioned meaning, by carrying out the following steps in two reaction spaces spatially separated from one another: a) reacting the 2-(2-cyanoethyl)cycloalkanones of the formula II in a first reaction space with excess ammonia over acidic heterogeneous catalysts at temperatures of 20 to 150 DEG C and pressures of 15 to 500 bar and b) hydrogenating the reaction products in a second reaction space with hydrogen in the presence of excess ammonia over cobalt-, nickel-, ruthenium- and/or other noble metal-containing catalysts which may contain basic components or are present on neutral or basic supports at temperatures of 60 to 150 DEG C and pressures of 100 to 500 bar, and also the novel compound 2-(3-aminopropyl)cyclopentylamine.

公开(公告)号：DE4010227A1

公开(公告)日：1991-10-02

申请号：DE4010227

申请日：1990-03-30

Applicant: BASF AG

Inventor： MERGER FRANZ DR ,  PRIESTER CLAUS-ULRICH DR ,  WITZEL TOM DR ,  KOPPENHOEFER GERHARD ,  HARDER WOLFGANG DR

IPC: B01J21/04 ,  B01J21/06 ,  B01J23/46 ,  B01J27/18 ,  C07B61/00 ,  C07C209/00 ,  C07C209/26 ,  C07C209/48 ,  C07C209/52 ,  C07C211/36

Abstract: Process for the preparation of 3-aminomethyl-3,5,5-trimethylcyclohexylamine from 3-cyano-3,5,5-trimethylcyclohexanone by carrying out the following steps in two reaction spaces spatially separated from one another: a) reacting the 3-cyano-3,5,5-trimethylcyclohexanone in a first reaction space with excess ammonia over acid metal oxide catalysts at temperatures of 20 to 150 DEG C and pressures of 15 to 500 bar and b) hydrogenating the reaction products formed in a second reaction space with hydrogen in the presence of excess ammonia over cobalt-, nickel-, ruthenium- and/or other noble metal-containing catalysts which may contain basic components or are present on neutral or basic supports at temperatures of 60 to 150 DEG C and pressures of 50 to 300 bar.