公开(公告)号：NO20024359D0

公开(公告)日：2002-09-12

申请号：NO20024359

申请日：2002-09-12

Applicant: UNION CARBIDE CHEM PLASTIC

Inventor： ARGYROPOULOS JOHN NICHOLAS ,  KANEL JEFFREY SCOTT ,  TULCHINSKY MICHAEL LEO ,  MILLER DAVID JAMES ,  MORRISON DONALD LEE ,  FOLEY PAUL ,  BRYANT DAVID ROBERT ,  PHILLIPS AILENE GARDNER ,  ROESCH BRIAN MICHAEL ,  BRIGGS JOHN ROBERT ,  LEE MAX MIN ,  MAHER JOHN MICHAEL

IPC: B01D11/04 ,  B01J23/46 ,  B01J31/18 ,  B01J31/24 ,  B01J31/40 ,  B01J38/00 ,  C07B61/00 ,  C07B63/00 ,  C07C45/50 ,  C07C45/80 ,  C07C47/19 ,  C07F9/02 ,  B01J

Abstract: This invention relates to a process for separating one or more organophosphorus ligand degradation products, one or more reaction byproducts and one or more products from a continuously generated reaction product fluid comprising one or more unreacted reactants, a metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand, said one or more organophosphorus ligand degradation products, said one or more reaction byproducts, said one or more products, one or more nonpolar solvents and one or more polar solvents by phase separation wherein (i) the selectivity of the nonpolar phase for the organophosphorus ligand with respect to the one or more products is expressed by a partition coefficient ratio Ef1which is a value greater than about 2.5, (ii) the selectivity of the nonpolar phase for the organophosphorus ligand with respect to the one or more organophosphorus ligand degradation products is expressed by a partition coefficient ratio Ef2 which is a value greater than about 2.5, and (iii) the selectivity of the nonpolar phase for the organophosphorus ligand with respect to the one or more reaction byproducts is expressed by a partition coefficient ratio Ef3 which is a value greater than about 2.5.

公开(公告)号：AU4572201A

公开(公告)日：2001-09-24

申请号：AU4572201

申请日：2001-03-14

Applicant: UNION CARBIDE CHEM PLASTIC

Inventor： KANEL JEFFREY SCOTT ,  ARGYROPOULOS JOHN NICHOLAS ,  PHILLIPS AILENE GARDNER ,  ROESCH BRAIN MICHAEL ,  BRIGGS JOHN ROBERT ,  LEE MIN MAX ,  MAHER JOHN MICHAEL ,  BRYANT DAVID ROBERT

IPC: C07B63/00 ,  C07C45/50 ,  B01J31/00

Abstract: This invention relates to a process for separating one or more products from a reaction product fluid comprising a metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand, said one or more products, one or more nonpolar reaction solvents and one or more polar reaction solvents, wherein said process comprises (1) subjecting said reaction product fluid to fractional countercurrent extraction with at least two immiscible extraction solvents, said at least two immiscible extraction solvents comprising at least one nonpolar extraction solvent and at least one polar extraction solvent, to obtain a nonpolar phase comprising said metal-organophosphorus ligand complex catalyst, said optionally free organophosphorus ligand, said one or more nonpolar reaction solvents and said at least one nonpolar extraction solvent and a polar phase comprising said one or more products, said one or more polar reaction solvents and said at least one polar extraction solvent, and (2) recovering said polar phase from said nonpolar phase; wherein (i) the organophosphorus ligand has a partition coefficient Kp1 defined herein between the nonpolar phase and the polar phase of greater than about 5, and (ii) the one or more products have a partition coefficient Kp2 defined herein between the nonpolar phase and the polar phase of less than about 2.0.

公开(公告)号：AU4365101A

公开(公告)日：2001-09-24

申请号：AU4365101

申请日：2001-03-14

Applicant: UNION CARBIDE CHEM PLASTIC

Inventor： ARGYROPOULOS JOHN NICHOLAS ,  KANEL JEFFREY SCOTT ,  TULCHINSKY MICHAEL LEO ,  MILLER DAVID JAMES ,  MORRISON DONALD LEE ,  FOLEY PAUL ,  BRYANT DAVID ROBERT

IPC: B01J31/40 ,  B01J31/00 ,  B01J38/00 ,  C07B61/00 ,  C07B63/00 ,  C07C29/136 ,  C07C31/20 ,  C07C67/31 ,  C07C67/313 ,  C07C67/58 ,  C07C69/675 ,  C07C69/716 ,  C07C227/02 ,  C07C227/08 ,  C07C229/08

Abstract: This invention relates to a process for separating one or more organophosphorus ligand degradation products, one or more reaction byproducts and one or more formylester products from a reaction product fluid comprising one or more unreacted unsaturated ester reactants, a metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand, said one or more organophosphorus ligand degradation products, said one or more reaction byproducts, said one or more products, a polar solvent and a nonpolar solvent by phase separation wherein(i) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more products is expressed by a partition coefficient ratio Ef1 which is a value greater than about 2.5, (ii) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more organophosphorus ligand degradation products is expressed by a partition coefficient ratio Ef2 which is a value greater than about 2.5, and (iii) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more reaction byproducts is expressed by a partition coefficient ratio Ef3 which is a value greater than about 2.5.

公开(公告)号：CA2403091A1

公开(公告)日：2001-09-20

申请号：CA2403091

申请日：2001-03-14

Applicant: UNION CARBIDE CHEM PLASTIC

Inventor： BRYANT DAVID ROBERT ,  MORRISON DONALD LEE ,  FOLEY PAUL ,  ARGYROPOULOS JOHN NICHOLAS ,  ROESCH BRIAN MICHAEL ,  KANEL JEFFREY SCOTT ,  BRIGGS JOHN ROBERT ,  MAHER JOHN MICHAEL ,  PHILLIPS AILENE GARDNER ,  LEE MAX MIN ,  TULCHINSKY MICHAEL LEO ,  MILLER DAVID JAMES

IPC: B01D11/04 ,  B01J23/46 ,  B01J31/18 ,  B01J31/24 ,  B01J31/40 ,  B01J38/00 ,  C07B61/00 ,  C07B63/00 ,  C07C45/50 ,  C07C45/80 ,  C07C47/19 ,  C07F9/02

Abstract: This invention relates to a process for separating one or more organophosphorus ligand degradation products, one or more reaction byproducts and one or more products from a continuously generated reaction product fluid comprising one or more unreacted reactants, a metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand, said one or more organophosphorus ligand degradation products, said one or more reaction byproducts, said one or more products, one or more nonpolar solvents and one or more polar solvents by phase separation wherein (i) the selectivity of the nonpolar phase for the organophosphorus ligand with respect to the one or more products is expressed by a partition coefficient ratio Ef1which is a value greater than about 2.5, (ii) the selectivity of the nonpolar phase for the organophosphorus ligand with respect to the one or more organophosphorus ligand degradation products is expressed by a partition coefficient ratio Ef2 which is a value greater than about 2.5, and (iii) the selectivity of the nonpolar phase for the organophosphorus ligand with respect to the one or more reaction byproducts is expressed by a partition coefficient ratio Ef3 which is a value greater than about 2.5.

公开(公告)号：CA2402140A1

公开(公告)日：2001-09-20

申请号：CA2402140

申请日：2001-03-14

Applicant: UNION CARBIDE CHEM PLASTIC

Inventor： ARGYROPOULOS JOHN NICHOLAS ,  BRYANT DAVID ROBERT ,  KANEL JEFFREY SCOTT ,  MILLER DAVID JAMES ,  TULCHINSKY MICHAEL LEO ,  MORRISON DONALD LEE ,  FOLEY PAUL

IPC: B01J31/40 ,  B01J31/00 ,  B01J38/00 ,  C07B61/00 ,  C07B63/00 ,  C07C29/136 ,  C07C31/20 ,  C07C67/31 ,  C07C67/313 ,  C07C67/58 ,  C07C69/675 ,  C07C69/716 ,  C07C227/02 ,  C07C227/08 ,  C07C229/08

Abstract: This invention relates to a process for separating one or more organophosphorus ligand degradation products, one or more reaction byproducts and one or more formylester products from a reaction product fluid comprising one or more unreacted unsaturated ester reactants, a metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand, said one or more organophosphorus ligand degradation products, said one or more reaction byproducts, said one or more products, a polar solvent and a nonpolar solvent by phase separation wherein(i) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more products is expressed by a partition coefficient ratio Ef1 which is a value greater than about 2.5, (ii) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more organophosphorus ligand degradation products is expressed by a partition coefficient ratio Ef2 which is a value greater than about 2.5, and (iii) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more reaction byproducts is expressed by a partition coefficient ratio Ef3 which is a value greater than about 2.5.

公开(公告)号：DE69518487T2

公开(公告)日：2001-04-19

申请号：DE69518487

申请日：1995-11-13

Applicant: UNION CARBIDE CHEM PLASTIC

Inventor： NIELSEN KENNETH ANDREW ,  ARGYROPOULOS JOHN NICHOLAS ,  WAGNER BURKHARD ERIC

IPC: B01D1/18 ,  B01J37/02 ,  B05D1/02 ,  C08J3/12 ,  C09D5/02 ,  B01J35/00 ,  C09D5/03 ,  B01J37/00

Abstract: This invention relates to methods for spraying liquid compositions containing volatile solvent by using compressed fluids, such as carbon dioxide or ethane, to form solid particulates, coating powders, and catalyst materials, which can be produced with narrow particle size distributions and can be sprayed at higher solids levels, in ambient air or with heated air applied to just the spray instead of a spray chamber. Novel catalyst supports can be produced having a beneficial morphology such as for olefin catalysis. Drier water-borne coatings can be applied to substrates by using compressed fluids to spray water-borne coating compositions having conventional water levels, thereby reducing runs and sags and shortening dry times.

公开(公告)号：PT711586E

公开(公告)日：2000-12-29

申请号：PT95308100

申请日：1995-11-13

Applicant: UNION CARBIDE CHEM PLASTIC

Inventor： WAGNER BURKHARD ERIC ,  ARGYROPOULOS JOHN NICHOLAS ,  NIELSEN KENNETH ANDREW

IPC: B01D1/18 ,  B01J37/02 ,  B05D1/02 ,  C08J3/12 ,  C09D5/02 ,  B01J35/00 ,  C09D5/03 ,  B01J37/00

Abstract: This invention relates to methods for spraying liquid compositions containing volatile solvent by using compressed fluids, such as carbon dioxide or ethane, to form solid particulates, coating powders, and catalyst materials, which can be produced with narrow particle size distributions and can be sprayed at higher solids levels, in ambient air or with heated air applied to just the spray instead of a spray chamber. Novel catalyst supports can be produced having a beneficial morphology such as for olefin catalysis. Drier water-borne coatings can be applied to substrates by using compressed fluids to spray water-borne coating compositions having conventional water levels, thereby reducing runs and sags and shortening dry times.

公开(公告)号：NO20005584A

公开(公告)日：2000-11-06

申请号：NO20005584

申请日：2000-11-06

Applicant: UNION CARBIDE CHEM PLASTIC

Inventor： ARGYROPOULOS JOHN NICHOLAS ,  BAILEY RICHARD H ,  HOY KENNETH LOOK ,  RIGGS KEVIN JOSEPH ,  GILLIAM GERALD ROBERT

IPC: B05D1/04 ,  B05B5/04 ,  C08J3/09 ,  C09D5/00 ,  C09D5/24 ,  C09D201/00 ,  H01B1/22 ,  H01B1/24

CPC classification number: C09D5/002 ,  C08J3/092 ,  C09D5/24 ,  H01B1/22 ,  H01B1/24

公开(公告)号：ES2105279T3

公开(公告)日：1997-10-16

申请号：ES93914075

申请日：1993-05-24

Applicant: UNION CARBIDE CHEM PLASTIC

Inventor： JENKINS RICHARD DUANE ,  BASSET DAVID ROBINSON ,  SHAY GREGORY DEAN ,  SMITH DANNY ELWOOD ,  ARGYROPOULOS JOHN NICHOLAS ,  LOFTUS JAMES EDWARD

IPC: C08F246/00 ,  C08F290/06 ,  C08G65/26 ,  C09D7/00 ,  C08F220/28 ,  C08F220/04 ,  C09D4/00

公开(公告)号：AU5405394A

公开(公告)日：1994-05-09

申请号：AU5405394

申请日：1993-10-14

Applicant: UNION CARBIDE CHEM PLASTIC

Inventor： ARGYROPOULOS JOHN NICHOLAS ,  HILKER BRIAN LEE

IPC: B05D1/02 ,  C08J3/02 ,  C08J3/09 ,  C09D133/06 ,  C09D7/00 ,  C09D157/04

Abstract: The present invention relates to copolymers which are particularly suitable in coating compositions which are sprayed with compressed fluids which act as viscosity reducing diluents.