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    PYRAZOLO(1,5A)PYRIMIDINES, THEIR PREPARATION AND THEIR USE
    34.
    发明专利
    PYRAZOLO(1,5A)PYRIMIDINES, THEIR PREPARATION AND THEIR USE 未知

    公开(公告)号：CA2217778A1

    公开(公告)日：1996-11-14

    申请号：CA2217778

    申请日：1996-04-26

    Applicant: BASF AG

    Inventor： OBERDORF KLAUS ,  SAUTER HUBERT ,  BAYER HERBERT ,  AMMERMANN EBERHARD ,  MUELLER BERND ,  LORENZ GISELA ,  GROTE THOMAS ,  BENOIT REMY ,  STRATHMANN SIEGFRIED

    IPC: A01N43/54 ,  A01N43/90 ,  C07D487/04

    Abstract: Pyrazolo-(1,5a)-pyrimidines have formula (I), in which the indexes and substituents have the following meanings: n equals 0 or 1; Y stands for 0, S, NRa, OCH2*, SCH2*, NRaCH2*, CH2O*, CH2S*, CH2NRa*, CH2CH2, CRa=Rb or CC, the positions with an * indicating the bond to the phenyl ring; R' stands for H3COCO-o=CHOCH3, H3CNH-CO-o=CHOCH3, H3CO-CO-o=NOCH3, H3CNH-CO-o=NOCH3, H2N-CO-o=NOCH3, HO-CO-o=NOCH3, H3CO-CO-o=CHCH3, H3CO-CO-o=CHCH2CH3, H3C-CO-o=CHOCH3, H3C-CO-o=NOCH3, H3CCH2-CO-o=NOCH3, in which o indicates a C atom bound to the phenyl ring, N(OCH3)-CO2CH3, N(CH3)-CO2CH3, N(CH2CH3)-CO2CH3, or a group R'.1o=NOCH3, R'.2-o=NOCH3, R'.3-o=NOCH3 or R'.4-o=NOCH3; m equals 0, 1, 2 or 3; the residues R" may be different when m is greater than 1; R" stands for cyano, halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio or haloalkylthio; R1, R3 stand for hydrogen, cyano, nitro, hydroxy, amino, halogen, alkyl, alkyl halide, alkoxy, alkoxy halide, alkylthio, alkylthio halide, aryl, arylalkyl, aryloxy, arylalkoxy, arylthio, heteroaryl, heteroarylalkyl, heteroaryloxy, heteroarylalkoxy, heteroarylthio or NRcRd, NRcNRdRe, CO-Rc, CO2-Rc, CO-NRcRd, O-CO-Rc, O-CO2-Rc, O-CO-NRcRd, NRc-CO-Rd, NRc-CO2-Rd or NRc-CO-NRdRe; R2 stands for hydrogen, halogen, alkyl, alkyl halide, alkoxy, alkoxy halide, aryl, aryloxy, heteroaryl, heteroaryloxy, CORc, CO2-Rc or CRf=NORg; R4 stands for hydrogen, cyano, nitro, nitroso, halogen, alkyl, alkyl halide, alkoxy, alkoxy halide, alkylthio, alkylthio halide, aryl, arylalkyl, aryloxy, arylalkoxy, arylthio, heteroaryl, heteroarylalkyl, heteroaryloxy, heteroarylalkoxy, heteroarylthio or NRcRd, CORc, CO2-Rc or CRf=NORg; Ra, Rb stand for hydrogen, halogen, C1-C4 alkyl or C1C4 alkyl halide; Rc, Rd and Re stand for hydrogen, alkyl, alkenyl, alkinyl, aryl, arylalkyl, heteroaryl or heteroarylalkyl; Rf stands for hydrogen, cyano, halogen, or optionally substituted alkyl, alkyloxy, alkylthio, alkenyl, alkenyloxy, alkenylthio, alkinyl, alkinyloxy, alkinylthio, cycloalkyl, cycloalkyloxy, cycloalkylthio, heterocyclyl, heterocyclyloxy, heterocyclylthio, aryl, aryloxy, arylthio, heteroaryl, heteroaryloxy or heteroarylthio; Rg stands for hydrogen or optionally substituted alkyl, alkenyl, alkinyl, cycloalkyl, heterocyclyl, aryl or heteroaryl. Also disclosed are a process for preparing the same and their use.

    PROCESS FOR PREPARATION OF ORTHO-/(IMINOOXY)-METHYL/-BENZOIC ACIDS
    35.
    发明专利
    PROCESS FOR PREPARATION OF ORTHO-/(IMINOOXY)-METHYL/-BENZOIC ACIDS 未知

    公开(公告)号：HU212602B

    公开(公告)日：1996-09-30

    申请号：HU9300978

    申请日：1993-04-02

    Applicant: BASF AG

    Inventor： BENOIT REMY ,  SAUTER HUBERT

    IPC: C07C249/12 ,  C07C251/60 ,  C07C253/30 ,  C07C255/17 ,  C07C255/57 ,  C07C255/61 ,  C07C259/04 ,  C07C259/12 ,  C07C259/14 ,  C07C259/18 ,  C07C317/24 ,  C07C323/47 ,  C07C323/63 ,  C07D209/14 ,  C07D209/48 ,  C07D213/53 ,  C07D213/57 ,  C07D239/26 ,  C07D277/20 ,  C07D277/38 ,  C07D333/24 ,  C07D333/36 ,  C07C251/04

    Abstract: Process for the preparation of an o-iminooxymethylbenzoic acid of the general formula I in which m denotes an integer from 0 to 3, X denotes alkyl, alkoxy, nitro, cyano, or halogen, R1 and R2 denote hydrogen, cyano, hydroxyl, alkyl, cycloalkyl, alkenyl, cycloalkenyl, alkynyl, alkoxy, alkylthio, benzylthio, benzylamino, alkylcarbonyl, optionally substituted phenylcarbonyl, optionally substituted benzylcarbonyl, alkoxycarbonyl, optionally substituted phenoxycarbonyl, optionally substituted benzyloxycarbonyl, optionally substituted aryl, optionally substituted aryloxy, optionally substituted arylthio, optionally substituted arylalkyl, optionally substituted arylalkenyl, optionally substituted aryloxyalkyl, optionally substituted arylthioalkyl, optionally substituted hetaryl, optionally substituted hetaryloxy, optionally substituted hetarylthio, optionally substituted heteroarylalkyl, optionally substituted hetarylalkenyl, optionally substituted hetaryloxyalkyl, hetarylthioalkyl, optionally substituted heterocyclyl, optionally substituted heterocyclyloxy, or denote N(R )2, where R denotes H, alkyl or phenyl, or denote -CO-N(R )2, where R denotes H, alkyl or phenyl, or R and R together with the C atom which they substitute can form a carbo- or heterocyclic ring, or R or R denotes halogen or the group denotes the radical where n denotes the integers 1 to 4 and the radicals R denote H, halogen, cyano, nitro; alkyl, alkoxy, aryl, aryloxy, benzyloxy, hetaryl and hetaryloxy, by reacting an oxime of the general formula II in which R1 and R2 have the abovementioned meanings, with a lactone of the general formula III in which X and m have the abovementioned meaning, if appropriate in the presence of a base or of a diluent, and o-iminooxymethylbenzoic acids of the abovementioned formula.

    37.
    发明专利
    未知

    公开(公告)号：BR9404837A

    公开(公告)日：1995-08-01

    申请号：BR9404837

    申请日：1994-12-02

    Applicant: BASF AG

    Inventor： BAYER HERBERT ,  SAUTER HUBERT ,  BENOIT REMY ,  MULLER RUTH ,  AMMERMANN EBERHARD ,  LORENZ GISELA

    IPC: A01N37/52 ,  C07C251/48 ,  C07C255/64 ,  C07C327/44 ,  C07C327/58 ,  C07C381/00 ,  A01N35/10 ,  A01N37/18

    Abstract: Thioimidates of the formula I in which the substituents and the index have the following meanings: R is alkyl; R is alkyl or cyclopropyl; m is 0, 1, 2 or 3; R is cyano, nitro, hydroxyl, mercapto, halogen, amino, optionally substituted alkyl, cycloalkyl, optionally substituted alkoxy, cycloalkoxy, alkylthio, alkylamino, dialkylamino, alkenyl, alkenyloxy, alkynyl, alkynyloxy, phenyl, phenoxy, C(=O)R , C(=O)OR , C(=O)NR R , C(=S)NR R , OC(=O)R , NR , NR C(=O)OR , S(=O)R , S(=O)OR , CR =NR , C(R )=NOR , C(XR )=NOR , N=CR R , or two adjacent R groups together form a group CH=CH-CH=CH; X is oxygen, sulphur or amino (NR ); R , R and R independently of one another are hydrogen or alkyl, their salts, their preparation, intermediates herefor, and their use.

    PROCESS FOR PRODUCING ORTHO-/(IMKINOOXY)-METHYL/-BENZOIC ACIDS
    39.
    发明专利
    PROCESS FOR PRODUCING ORTHO-/(IMKINOOXY)-METHYL/-BENZOIC ACIDS 未知

    公开(公告)号：HUT64015A

    公开(公告)日：1993-11-29

    申请号：HU9300978

    申请日：1993-04-02

    Applicant: BASF AG

    Inventor： BENOIT REMY ,  SAUTER HUBERT

    IPC: C07C249/12 ,  C07C251/60 ,  C07C255/17 ,  C07C255/57 ,  C07C255/61 ,  C07C259/04 ,  C07C259/12 ,  C07C253/30 ,  C07C259/14 ,  C07C259/18 ,  C07C317/24 ,  C07C323/47 ,  C07C323/63 ,  C07D209/14 ,  C07D209/48 ,  C07D213/53 ,  C07D213/57 ,  C07D239/26 ,  C07D277/20 ,  C07D277/38 ,  C07D333/24 ,  C07D333/36 ,  C07C255/64 ,  C07C255/40 ,  C07D307/88

    Abstract: Process for the preparation of an o-iminooxymethylbenzoic acid of the general formula I in which m denotes an integer from 0 to 3, X denotes alkyl, alkoxy, nitro, cyano, or halogen, R1 and R2 denote hydrogen, cyano, hydroxyl, alkyl, cycloalkyl, alkenyl, cycloalkenyl, alkynyl, alkoxy, alkylthio, benzylthio, benzylamino, alkylcarbonyl, optionally substituted phenylcarbonyl, optionally substituted benzylcarbonyl, alkoxycarbonyl, optionally substituted phenoxycarbonyl, optionally substituted benzyloxycarbonyl, optionally substituted aryl, optionally substituted aryloxy, optionally substituted arylthio, optionally substituted arylalkyl, optionally substituted arylalkenyl, optionally substituted aryloxyalkyl, optionally substituted arylthioalkyl, optionally substituted hetaryl, optionally substituted hetaryloxy, optionally substituted hetarylthio, optionally substituted heteroarylalkyl, optionally substituted hetarylalkenyl, optionally substituted hetaryloxyalkyl, hetarylthioalkyl, optionally substituted heterocyclyl, optionally substituted heterocyclyloxy, or denote N(R )2, where R denotes H, alkyl or phenyl, or denote -CO-N(R )2, where R denotes H, alkyl or phenyl, or R and R together with the C atom which they substitute can form a carbo- or heterocyclic ring, or R or R denotes halogen or the group denotes the radical where n denotes the integers 1 to 4 and the radicals R denote H, halogen, cyano, nitro; alkyl, alkoxy, aryl, aryloxy, benzyloxy, hetaryl and hetaryloxy, by reacting an oxime of the general formula II in which R1 and R2 have the abovementioned meanings, with a lactone of the general formula III in which X and m have the abovementioned meaning, if appropriate in the presence of a base or of a diluent, and o-iminooxymethylbenzoic acids of the abovementioned formula.

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