-
公开(公告)号:DE3261467D1
公开(公告)日:1985-01-17
申请号:DE3261467
申请日:1982-08-18
Applicant: BASF AG
Inventor: HENNE ANDREAS DR , HESSE ANTON DR , JACOBI MANFRED DR , SCHORNICK GUNNAR DR , VYVIAL RUDOLF , HOLOCH KLAUS DR
-
公开(公告)号:DE3167097D1
公开(公告)日:1984-12-13
申请号:DE3167097
申请日:1981-08-29
Applicant: BASF AG
Inventor: HENNE ANDREAS DR , HESSE ANTON DR , HEIL GUENTER DR , SCHORNICK GUNNAR DR
-
公开(公告)号:DE3417943A1
公开(公告)日:1984-11-22
申请号:DE3417943
申请日:1984-05-15
Applicant: BASF AG
Inventor: TRAUTMANN WALTER DR , HENNE ANDREAS DR , SEUFERT WALTER DR , SCHWENDEMANN VOLKER DR , THEOBALD HANS DR
IPC: C07C69/145 , C07F7/18 , C07C33/025 , C07C33/03 , C07D309/12
Abstract: The invention relates to a process for the preparation of the trans-isomer of an alkenyloxy compound of the formula (I> CH3-(CH2)m-CH = CH-(CH2)n.OR in which m and n in each case represent an integer from 1 to 10 and R represents a hydrogen atom, an aliphatic C1- to C4-acyl radical, a trialkylsilyl radical or a tetrahydropyranyl radical, from the cis-isomer by rearrangement/isomerisation by means of short-wave light in the presence of a disulphide compound as sensitiser.
-
公开(公告)号:ES2191137T3
公开(公告)日:2003-09-01
申请号:ES97115339
申请日:1997-09-04
Applicant: BASF AG
Inventor: MERCKER HANS JOCHEN DR , PAPE FRANK-FRIEDRICH DR , SIMON JOACHIM DR , HENNE ANDREAS DR , HESSE MICHAEL DR , KOHLER ULRICH DR
IPC: C07D307/33 , B01J23/72 , B01J23/78 , C07B61/00 , C07D307/32 , C07D315/00
Abstract: Gas phase dehydration of butan-1,4-diol (I) to gamma -butyrolactone (II) is carried out in the presence of a catalyst (III) containing copper (Cu), which contains 4-40 wt.% Cu and 0-5 wt.% sodium oxide (Na2O) on a support of 80-100 wt.% silica (SiO2) and 0-20 wt.% calcium oxide (CaO). Also claimed is catalyst (III) per se.
-
公开(公告)号:AT205186T
公开(公告)日:2001-09-15
申请号:AT98103195
申请日:1998-02-24
Applicant: BASF AG
Inventor: KNEUPER HEINZ-JOSEF DR , WEYER HANS-JUERGEN DR , NEUHAUSER HORST DR , MELDER JOHANN-PETER DR , HENNE ANDREAS DR , ROSS KARL-HEINZ DR , BECKER RAINER DR
IPC: B01J27/18 , B01J31/02 , C07B61/00 , C07C209/48 , C07C211/09 , C07C253/14 , C07C253/34 , C07C255/04
Abstract: Removal of halides (I) from mixtures containing nitriles (II) containing (I) comprises (a) thermal treatment; (b) treatment with a base; and (c) separation of the base. Also claimed are methods of preparing amines.
-
公开(公告)号:DE19803515A1
公开(公告)日:1999-08-05
申请号:DE19803515
申请日:1998-01-30
Applicant: BASF AG
Inventor: FRIEDRICH WOLFGANG , KNEUPER HEINZ-JOSEF DR , ELLER KARSTEN DR , HENNE ANDREAS DR , LEBKUECHER ROLF DR
IPC: B01J31/02 , C07B61/00 , C07C213/02 , C07C217/08 , C07C217/48 , C07C253/30 , C07C255/13 , C07C255/37 , C07D487/04 , C07D471/04
Abstract: A process for the production of beta -alkoxy-nitriles which is carried out in the presence of a basic diazabicycloalkene catalyst. Production of beta -alkoxy-nitriles which involves reaction of alpha , beta -unsaturated nitriles with mono-, di- or tri- valent alcohols in the presence of a basic diazabicycloalkene of formula (1), at (-) 20-200 degrees C. n, m = 1-6; and where the 1-4 H atoms are optionally substituted by R -R ; R -R = 1-20C alkyl, 6-20C aryl or 7-20C arylalkyl. An Independent claim is also included for a production process of a gamma -alkoxy-amine by hydrogenation of the beta -alkoxy-nitrile in the presence of a hydrogenation catalyst and the catalyst of formula (1).
-
公开(公告)号:DE59505564D1
公开(公告)日:1999-05-12
申请号:DE59505564
申请日:1995-08-09
Applicant: BASF AG
Inventor: BECKER RAINER DR , MENGER VOLKMAR DR , REIF WOLFGANG DR , HENNE ANDREAS DR
IPC: B01J23/88 , B01J21/06 , B01J23/755 , B01J37/03 , C07B61/00 , C07C209/16 , C07C211/09
Abstract: Prepn. of a diamine (I) involves reacting an aminoalcohol (II) with ammonia or a prim. or sec. amine and hydrogen at 1-400 bars and 80-250 degrees C in presence of a catalyst (A) contg. the following oxygen-contg. metal cpds. in amts. (by wt.) 20-85% Zr cpd. (calculated as ZrO2), 1-30% Cu cpd. (calculated as CuO), 30-70% Ni cpd. (calculated as NiO), 0.1-5% cpd. of molybdenum (calculated as MoO3) and 0-10% cpds. of aluminium and/or manganese (calculated as Al2O3 or MnO2). Pref. (I) is NR R -Y-NR R , (II) is HO-Y-NR R and (III) is NHR R . R , R = 1-20C alkyl, 3-12C cycloalkyl, aryl, 7-20C aralkyl or 7-20C alkaryl; or R +R = (CH2)m-X-(CH2)n; R , R = H or as R , R ; X = O, CH2 or NR ; R = 1-20C alkyl, 3-12C cycloalkyl, aryl, 7-20C aralkyl or 7-20C alkaryl; Y = 2-12C alkylene chain, opt. substd. by 1-5 1-4C alkyl.
-
公开(公告)号:DE59600460D1
公开(公告)日:1998-10-01
申请号:DE59600460
申请日:1996-01-04
Applicant: BASF AG
Inventor: DINGERDISSEN UWE DR , HENNE ANDREAS DR , HERRMANN JUERGEN , PFEFFINGER JOACHIM , STOPS PETER
IPC: C07C209/60
-
公开(公告)号:DE4429547A1
公开(公告)日:1996-02-22
申请号:DE4429547
申请日:1994-08-19
Applicant: BASF AG
Inventor: BECKER RAINER DR , MENGER VOLKMAR DR , REIF WOLFGANG DR , HENNE ANDREAS DR
IPC: B01J23/88 , B01J21/06 , B01J23/755 , B01J37/03 , C07B61/00 , C07C209/16 , C07C211/09
Abstract: Prepn. of a diamine (I) involves reacting an aminoalcohol (II) with ammonia or a prim. or sec. amine and hydrogen at 1-400 bars and 80-250 degrees C in presence of a catalyst (A) contg. the following oxygen-contg. metal cpds. in amts. (by wt.) 20-85% Zr cpd. (calculated as ZrO2), 1-30% Cu cpd. (calculated as CuO), 30-70% Ni cpd. (calculated as NiO), 0.1-5% cpd. of molybdenum (calculated as MoO3) and 0-10% cpds. of aluminium and/or manganese (calculated as Al2O3 or MnO2). Pref. (I) is NR R -Y-NR R , (II) is HO-Y-NR R and (III) is NHR R . R , R = 1-20C alkyl, 3-12C cycloalkyl, aryl, 7-20C aralkyl or 7-20C alkaryl; or R +R = (CH2)m-X-(CH2)n; R , R = H or as R , R ; X = O, CH2 or NR ; R = 1-20C alkyl, 3-12C cycloalkyl, aryl, 7-20C aralkyl or 7-20C alkaryl; Y = 2-12C alkylene chain, opt. substd. by 1-5 1-4C alkyl.
-
公开(公告)号:DE3465314D1
公开(公告)日:1987-09-17
申请号:DE3465314
申请日:1984-08-29
Applicant: BASF AG
Inventor: HOLOCH KLAUS DR , HENNE ANDREAS DR , LECHTKEN PETER DR
-
-
-
-
-
-
-
-
-