公开(公告)号：DE59307290D1

公开(公告)日：1997-10-16

申请号：DE59307290

申请日：1993-01-28

Applicant: BASF AG

Inventor： JAEGER ULRICH DR ,  BECK ERICH DR ,  REICH WOLFGANG DR ,  BRONSTERT BERND DR ,  HUEMMER WOLFGANG DR

IPC: C08F299/06 ,  C08G18/08 ,  C08G18/38 ,  C08G18/67 ,  C08G18/78 ,  C08G18/79 ,  C08J3/03 ,  C09D175/14

公开(公告)号：DE19539533A1

公开(公告)日：1997-04-30

申请号：DE19539533

申请日：1995-10-24

Applicant: BASF AG

Inventor： BECHTEL SIEGFRIED ,  ULONSKA ARMIN DR ,  HEILIG EDWIN ,  REICH WOLFGANG DR

IPC: B01D21/28 ,  B01J19/10 ,  B06B1/02 ,  B01D19/00 ,  B01J8/16

公开(公告)号：DE4445853A1

公开(公告)日：1996-06-27

申请号：DE4445853

申请日：1994-12-22

Applicant: BASF AG

Inventor： SEELERT STEFAN DR ,  HINGMANN ROLAND DR ,  MARCZINKE BERND LOTHAR DR ,  REICH WOLFGANG DR

IPC: C08F8/00 ,  C08K5/103 ,  C08L23/14 ,  C08F255/02

Abstract: Partly crosslinked plastic materials (A) with a melt flow index 230/2.16 of 0.1-100 g/10 minutes are obtd from: (a1) a polymer contg: (a1.1) 25-97 wt% of a copolymer of propylene with 0.1-15 wt% 2-10C alkene-1, and (a1.2) 3-75 wt% of a copolymer of propylene with 15-80 wt% 2-10C alkene-1; or (a2) a polymer contg: (a2.1) 25-97 wt% propylene homopolymer, and (a2.2) 3-75 wt% copolymer (a1.2) as above; or (a3) a propylene homopolymer with a melt flow index 230/2 of 0.1-100 g/10 minutes; or (a4) a statistical propylene copolymer contg less than 15 wt% 2-10C alkene-1 comonomer; and (b) a cpd of formula: (H2C=CR-COO)nX (I) R = H or 1-4C alkyl; X = 1-30C alkyl or 7-30C aralkyl, opt contg in-chain O and/or N atom(s); and n = 2 or 3; and these materials (A) are obtd by reacting (a1), (a2), (a3) or (a4) with cpd (b) at 180-280 deg C and 1-100 bar for a mean residence time of 0.2-10 minutes. Also claimed are: (i) a process for the prodn of (A) by reacting the above polymers with (b) at 190-260 deg C and 1-60 bar for a mean residence time of 0.2-5 minutes, pref immediately after prodn of the polymer in a mixer connected to the polymerisation reactor; and (ii) films, fibres and mouldings made from (A).

公开(公告)号：ES2083887T3

公开(公告)日：1996-04-16

申请号：ES94116764

申请日：1994-10-25

Applicant: BASF AG

Inventor： KEMPTER FRITZ ERDMANN DR ,  REICH WOLFGANG DR ,  HOFMANN JURGEN

IPC: C08F2/02 ,  C08F2/06 ,  C08F8/14 ,  C08F8/00 ,  C08F20/10 ,  C08F220/14 ,  C08F290/00 ,  C08F299/00 ,  C09D4/06 ,  C09D5/03 ,  C09D133/04

Abstract: A process for the preparation of free-radical-crosslinkable copolymers by polymer-analogous reaction of A) a copolymer (A) comprising a1) from 20 to 85 mol % of a monomer (a1) containing the methacrylic acid structural unit and a2) from 15 to 80 mol % of another free-radical-polymerising monomer (a2), where a3) from 5 to 50 mol % of the total amount of the monomers (a1) and (a2) are monomers (a3) carrying functional groups which are capable of a condensation or addition reaction, with B) an olefinically unsaturated monomer (B) carrying a functional group which is complementary to that of the monomers (a3), characterised in that the polymer-analogous reaction is carried out at from 90 to 150 DEG C and at a mean residence time of from 3 to 20 minutes in highly concentrated solution or in bulk. The free-radical-crosslinkable copolymers which can be prepared by this process are used as binders for powder coatings (paints).

公开(公告)号：DE59400150D1

公开(公告)日：1996-04-11

申请号：DE59400150

申请日：1994-10-25

Applicant: BASF AG

Inventor： KEMPTER FRITZ ERDMANN DR ,  REICH WOLFGANG DR ,  HOFMANN JUERGEN

IPC: C08F8/00 ,  C08F2/02 ,  C08F2/06 ,  C08F8/14 ,  C08F20/10 ,  C08F220/14 ,  C08F290/00 ,  C08F299/00 ,  C09D4/06 ,  C09D5/03 ,  C09D133/04

Abstract: A process for the preparation of free-radical-crosslinkable copolymers by polymer-analogous reaction of A) a copolymer (A) comprising a1) from 20 to 85 mol % of a monomer (a1) containing the methacrylic acid structural unit and a2) from 15 to 80 mol % of another free-radical-polymerising monomer (a2), where a3) from 5 to 50 mol % of the total amount of the monomers (a1) and (a2) are monomers (a3) carrying functional groups which are capable of a condensation or addition reaction, with B) an olefinically unsaturated monomer (B) carrying a functional group which is complementary to that of the monomers (a3), characterised in that the polymer-analogous reaction is carried out at from 90 to 150 DEG C and at a mean residence time of from 3 to 20 minutes in highly concentrated solution or in bulk. The free-radical-crosslinkable copolymers which can be prepared by this process are used as binders for powder coatings (paints).

公开(公告)号：DE4337482A1

公开(公告)日：1995-05-04

申请号：DE4337482

申请日：1993-11-03

Applicant: BASF AG

Inventor： KEMPTER FRITZ ERDMANN DR ,  REICH WOLFGANG DR ,  HOFMANN JUERGEN

IPC: C08F8/00 ,  C08F2/02 ,  C08F2/06 ,  C08F8/14 ,  C08F20/10 ,  C08F220/14 ,  C08F290/00 ,  C08F299/00 ,  C09D4/06 ,  C09D5/03 ,  C09D133/04 ,  C08F220/00 ,  C08J3/24 ,  C08J3/28 ,  B05D3/06 ,  B29B7/42

Abstract: A process for the preparation of free-radical-crosslinkable copolymers by polymer-analogous reaction of A) a copolymer (A) comprising a1) from 20 to 85 mol % of a monomer (a1) containing the methacrylic acid structural unit and a2) from 15 to 80 mol % of another free-radical-polymerising monomer (a2), where a3) from 5 to 50 mol % of the total amount of the monomers (a1) and (a2) are monomers (a3) carrying functional groups which are capable of a condensation or addition reaction, with B) an olefinically unsaturated monomer (B) carrying a functional group which is complementary to that of the monomers (a3), characterised in that the polymer-analogous reaction is carried out at from 90 to 150 DEG C and at a mean residence time of from 3 to 20 minutes in highly concentrated solution or in bulk. The free-radical-crosslinkable copolymers which can be prepared by this process are used as binders for powder coatings (paints).

公开(公告)号：ES2083887T5

公开(公告)日：1999-11-01

申请号：ES94116764

申请日：1994-10-25

Applicant: BASF AG

Inventor： KEMPTER FRITZ ERDMANN DR ,  REICH WOLFGANG DR ,  HOFMANN JURGEN

IPC: C08F2/02 ,  C08F2/06 ,  C08F8/14 ,  C08F8/00 ,  C08F20/10 ,  C08F220/14 ,  C08F290/00 ,  C08F299/00 ,  C09D4/06 ,  C09D5/03 ,  C09D133/04

Abstract: A process for the preparation of free-radical-crosslinkable copolymers by polymer-analogous reaction of A) a copolymer (A) comprising a1) from 20 to 85 mol % of a monomer (a1) containing the methacrylic acid structural unit and a2) from 15 to 80 mol % of another free-radical-polymerising monomer (a2), where a3) from 5 to 50 mol % of the total amount of the monomers (a1) and (a2) are monomers (a3) carrying functional groups which are capable of a condensation or addition reaction, with B) an olefinically unsaturated monomer (B) carrying a functional group which is complementary to that of the monomers (a3), characterised in that the polymer-analogous reaction is carried out at from 90 to 150 DEG C and at a mean residence time of from 3 to 20 minutes in highly concentrated solution or in bulk. The free-radical-crosslinkable copolymers which can be prepared by this process are used as binders for powder coatings (paints).

公开(公告)号：DE19753322A1

公开(公告)日：1999-06-10

申请号：DE19753322

申请日：1997-12-02

Applicant: BASF AG

Inventor： KOENIGER RAINER DR ,  PAULUS WOLFGANG DR ,  REICH WOLFGANG DR ,  BECK ERICH DR ,  WOLF LOTHAR

IPC: C07C67/08 ,  C07C67/26 ,  C07C69/54 ,  C08F2/42 ,  C08F2/46 ,  C08F20/18 ,  C08F20/32 ,  C08F299/02 ,  C08G59/17 ,  C08L63/10 ,  C09D4/02 ,  C09D4/06 ,  C09D163/10 ,  C08L33/14 ,  C08L33/08 ,  C08L33/10 ,  C08J3/28

Abstract: A mixture (I) of acrylic or methacrylic compounds contains 40-95 wt.% epoxy (meth)acrylate and is prepared by: (a) esterification of hydroxyl compounds with acrylic acid or methacrylic acid; (b) optionally addition of further acrylic acid or methacrylic acid and (c) reaction of the excess acrylic or methacrylic acid with epoxide in the presence of the ester product from (a). Independent claims are included for: (i) a radiation curable composition (II) containing (I); and (ii) a process for the curing of (II) by subjecting (II) to energy intensive light or electron beams.

公开(公告)号：DE19732621A1

公开(公告)日：1999-02-04

申请号：DE19732621

申请日：1997-07-29

Applicant: BASF AG

Inventor： SCHWARTZ MANFRED DR ,  MENZEL KLAUS ,  BECHERT BERTOLD ,  BECK ERICH DR ,  REICH WOLFGANG DR

IPC: C04B41/48 ,  C04B41/52 ,  C04B41/63 ,  C04B41/70 ,  C08F2/46 ,  C09D175/16 ,  C09D183/07 ,  B05D7/24 ,  C08F220/18 ,  C09D167/07 ,  C09D171/02 ,  C09D163/10 ,  C09D161/28 ,  C09D133/04

Abstract: The use of radiation-curable preparations contains polymer(s) P1 with ethylenic double bonds for coating moulded products containing mineral binders (mineral mouldings). Also claimed is (i) a process for the production of coated mineral mouldings by applying this type of preparation to the surface of a moulded product, possibly removing any solvent, and hardening with UV or electron beam radiation; (ii) coated mineral mouldings obtained by this process.

公开(公告)号：DE19716020A1

公开(公告)日：1998-10-22

申请号：DE19716020

申请日：1997-04-17

Applicant: BASF AG

Inventor： KOKEL NICOLAS DR ,  MENZEL KLAUS DIPL ING ,  REICH WOLFGANG DR

IPC: C09D175/04 ,  C09D175/16 ,  C08J3/03 ,  C08L75/04 ,  D06N3/00 ,  C08G18/40 ,  C08G18/65 ,  C08G18/34 ,  C08G18/38 ,  C08G18/10 ,  C08G18/67

Abstract: The present invention describes aqueous dispersions which are substantially free of protective colloids or emulsifiers, containing in a dispersed form a) a polyurethane (A) containing hydrophilic groups, causing water dispersion of said polyurethane which is substantially free of C-C double bonds and b) a prepolymer containing 0.1 to 1 mol radically polymerizable C-C double bonds per 100 gr. of prepolymer.