33.
    发明专利
    未知

    公开(公告)号:DE59703923D1

    公开(公告)日:2001-08-02

    申请号:DE59703923

    申请日:1997-09-22

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP97/05186 Sec. 371 Date Apr. 1, 1999 Sec. 102(e) Date Apr. 1, 1999 PCT Filed Sep. 22, 1997 PCT Pub. No. WO98/14441 PCT Pub. Date Apr. 9, 1998A process for preparing phthalides of the general formula I, where R1, R2, R3 and R4 are independently hydrogen, C1-C4-alkyl or C1-C4-alkoxy, by hydrogenating phthalic anhydrides of the general formula II, where R1, R2, R3 and R4 are each as defined above, with hydrogen in the presence of suspended catalysts of the Raney type in a hydrogenation apparatus by using a mixing apparatus to mix a liquid phase, which includes the catalyst and the phthalic anhydride used and resulting phthalide, and a gas phase, which includes the hydrogenating hydrogen, comprises using the mixing apparatus to introduce a mixing intensity of at least 50 W/l into the liquid phase.

    36.
    发明专利
    未知

    公开(公告)号:DE59506673D1

    公开(公告)日:1999-09-30

    申请号:DE59506673

    申请日:1995-06-24

    Applicant: BASF AG

    Abstract: A catalyst (C) consisting of 85-100 wt.% copper oxide and zirconium oxide and 15-0 wt.% metal oxides of groups Ib to VIIb and VIII of the Periodic Table is new. Also claimed is the prepn. of amines by reaction of nitrile with ammonia, or prim. or sec. amine at 80-250 degrees C and 1-400 bar with hydrogen and a catalyst (C). Pref. prepn. of NR1R2-CH2R3 (I) comprises reaction of R3CN with NHR1R2. R1, R2 = H, 1-20C alkyl, 3-12C cycloalkyl, aryl, 7-20C aralkyl, 7-20C alkylaryl; R3 = 1-200C alkyl, 3-12C cycloalkyl, 1-20C alkyl (substd. with NH2, NHMe, NMe2 and/or OH), 2-30C alkoxyalkyl, (CH2-CHR5-O)nR4, aryl, 7-20C aralkyl or 7-20C alkylaryl; n = 2-30; R4 = H, 1-4C alkyl; R5 = H or Me.

Patent Agency Ranking