公开(公告)号：ES2229299T3

公开(公告)日：2005-04-16

申请号：ES97111330

申请日：1997-07-04

Applicant: BASF AG

Inventor： SCHEHLMANN VOLKER DR ,  SCHADE CHRISTIAN DR ,  SANNER AXEL DR ,  SPERLING KARIN DR ,  WEKEL HANS-ULRICH DR

IPC: A61K8/72 ,  A61K8/00 ,  A61K8/81 ,  A61K8/89 ,  A61Q1/00 ,  A61Q1/04 ,  A61Q1/06 ,  A61Q1/10 ,  A61Q17/04 ,  A61Q19/00 ,  A61K7/48

Abstract: LA PRESENTE INVENCION TRATA DE UN MEDIO COSMETICO O FARMACEUTICO QUE CONTIENE AL MENOS UN POLIMERO O COPOLIMERO, QUE SE PUEDE OBTENER MEDIANTE POLIMERIZACION RADICAL POR EMULSIONAMIENTO O EN SUSPENSION EN PRESENCIA DE AL MENOS UN REACTIVO DE TRANSMISION POR CADENA, QUE MUESTRA UNA TEMPERATURA DE TRANSICION VITREA SUPERIOR A LOS 35 (GRADOS) C Y UN CONTENIDO DE COMPONENTES ORGANICOS VOLATILES 0,5 % , Y QUE ESTA COMPUESTO AL MENOS EN UN 20 % EN PESO DE UN ESTER DE ACIDO (META)CRILICO.

公开(公告)号：DE59700377D1

公开(公告)日：1999-10-07

申请号：DE59700377

申请日：1997-01-07

Applicant: BASF AG

Inventor： SCHADE CHRISTIAN DR

IPC: C08L57/00 ,  C08F2/16 ,  C08F2/20 ,  C08F2/22 ,  C08F2/24 ,  C08F2/44

Abstract: The production of water-insoluble polymers (I) comprises the radical polymerisation of ethylenically unsaturated monomers (II) in an aqueous gel phase with a viscosity of at least 800 mPa.s, in which the gel-former (III) has an average molecular weight of more than 20,000. Also claimed are polymer dispersions obtained by the above process.

公开(公告)号：DE19804912A1

公开(公告)日：1999-08-12

申请号：DE19804912

申请日：1998-02-07

Applicant: BASF AG

Inventor： FISCHER WOLFGANG DR ,  BUECHNER EUGEN-WALTER DR ,  DEIMLING AXEL DR ,  GAUSEPOHL HERMANN DR ,  SCHADE CHRISTIAN DR

IPC: B01J19/18 ,  C08F2/00 ,  C08F279/02 ,  C08F287/00 ,  C08F279/00

Abstract: The present invention relates to a method for producing impact-resistant modified styrene polymers, wherein said method comprises the anionic polymerisation of styrene in the presence of a rubber in one or more serially-mounted polymerisation reactors. The rubber is produced in the shape of a solution during a process carried out immediately upstream. The rubber solvent, which has a boiling point lower than that of the styrene or ethyl benzene, is removed by distillation with vaporisation cooling from at least one of said polymerisation reactors using the heat generated during the polymerisation process, and is further fed back to the rubber production step.

公开(公告)号：ES2122735T3

公开(公告)日：1998-12-16

申请号：ES96104924

申请日：1996-03-28

Applicant: BASF AG

Inventor： SCHADE CHRISTIAN DR

IPC: C08F2/06 ,  C08F2/22 ,  C08F2/44 ,  C08J3/03 ,  C09K23/52

Abstract: Aq. polymer dispersions (X) are prepd. by radical aq. emulsion polymerisation of a mixt. contg. at least one gp. of ethylenic unsatd. radical polymerisable monomers. The mixt. comprises 30 - 90 wt.% monomers (A) with a min. solubility of 5 wt.% in water at the chosen polymerisation temp. and pressure (w.r.t. mixt.) and 10 - 70 wt.% monomers (B) with solubility in water less than 5 wt.% under the same conditions. The mixt. contains no surfactant monomers (C). Some or all of the emulsion polymerisation takes place in a dispersant medium comprising water and an organic solvent (S) whose solubility in water is max. 10 wt.% under the above conditions. The dispersant comprises at least 20 wt.% (S) and there is sufficient (S) present to form aq. and organic phases, but the water / (S) mass ratio is not greater than 1 : 2. Also claimed are (i) the prepn. of (X) by the above method; and (ii) oil-in-water emulsions contg. (D).

公开(公告)号：DE19646437A1

公开(公告)日：1998-05-14

申请号：DE19646437

申请日：1996-11-11

Applicant: BASF AG

Inventor： BOECKH DIETER DR ,  JAEGER HANS-ULRICH DR ,  LUX JUERGEN ALFRED DR ,  STEIN STEFAN DR ,  DETERING JUERGEN DR ,  SCHADE CHRISTIAN DR

IPC: C08F226/06 ,  C11D3/00 ,  C11D3/37 ,  D06P1/52 ,  D06P5/08 ,  D06M15/356

Abstract: The use of polymerizates, containing at least 5 mol % quaternized 1-vinyl-imidazol units of formula (I) wherein R = C1-C25 alkyl, C5-C10 cycloalkyl or benzyl, R , R , R are the same or different, mean H, CH3 and C2H5 and X is an anion, as a colour fixing and colour transfer inhibiting additive to detergent post-treatment agents and detergents.

公开(公告)号：DE19546698A1

公开(公告)日：1997-06-19

申请号：DE19546698

申请日：1995-12-14

Applicant: BASF AG

Inventor： SCHADE CHRISTIAN DR ,  WEKEL HANS-ULRICH DR ,  SANNER AXEL DR ,  SPERLING KARIN DR

IPC: A61K47/32 ,  A61K8/72 ,  A61K8/81 ,  A61K9/10 ,  A61K31/74 ,  A61Q19/00 ,  C08F220/04 ,  C08F222/00 ,  C08F222/02 ,  C08F222/04 ,  C08F290/06 ,  C09K3/00 ,  C09K23/00 ,  C09K23/52 ,  B01F17/52 ,  A61K7/50

Abstract: The disclosure relates to a copolymer obtainable by radically initiated polymerisation of the following: A) 70-99.9 wt.% an olefinically unsaturated C3-C5 monocarboxylic acid, an olefinically unsaturated C4-C8 dicarboxylic acid or its anhydride, or a mixture of such carboxylic acids; with B) 0.1-30 wt.% one or more multiply olefinically unsaturated carboxylic acid derivatives of formula (I) in which Z is a vinyl or allyl group or structure (a), R , R are hydrogen or methyl, R is hydrogen, methyl or ethyl, R is a singly or multiply olefinically unsaturated alkenyl or cycloalkenyl group or a singly or doubly olefinically unsaturated arylalkylene group, X is oxygen or NH, Y is oxygen, NH or N-alkyl, n is a number between 0 and 50; and C) 0-29.9 wt.% other copolymerisable monomers. The proposed copolymer can be used as a thickener or dispergent for aqueous systems.

公开(公告)号：DE19519338A1

公开(公告)日：1996-11-28

申请号：DE19519338

申请日：1995-05-26

Applicant: BASF AG

Inventor： SCHADE CHRISTIAN DR ,  BOECKH DIETER DR ,  SANNER AXEL DR ,  JAEGER HANS-ULRICH DR

IPC: C08F2/18 ,  C08F2/32 ,  C08F6/24 ,  C08F26/00 ,  C08F26/02 ,  C08F26/06 ,  C08L39/00 ,  C11D3/37 ,  C08J3/03 ,  C11D3/28

Abstract: The invention concerns polymer and surfactant mixtures containing in suspended form in at least one surfactant between 1 and 50 wt.% of a polymer comprising: a) between 10 and 100 wt.% of at least one vinylimidazole or a derivative thereof, an open-chain or cyclic N-vinylamide, N-vinyloxazolidone, N-vinyltriazole or mixtures of said monomers; b) between 0 and 90 wt.% of other copolymerizable monoethylenically unsaturated monomers; and c) between 0 and 30 wt.% of at least one monomer with at least two ethylenically unsaturated, non-conjugated double bonds. The invention further concerns a process for preparing these mixtures by polymerization of said monomers in a surfactant, and the use of the mixtures as additives for washing agents.

公开(公告)号：DE19505750A1

公开(公告)日：1996-08-22

申请号：DE19505750

申请日：1995-02-20

Applicant: BASF AG

Inventor： SCHADE CHRISTIAN DR ,  SCHNEIDER KARL-HEINRICH DR

IPC: C08F2/24 ,  C08F2/32 ,  C08F26/06 ,  C08F226/06 ,  C09K23/00 ,  C09K23/52 ,  C11D3/00 ,  C11D3/37 ,  B01F17/52

Abstract: The invention concerns agglomerated finely divided cross-linked vinyl imidazole copolymers obtainable by radically initiated polymerisation of N-vinyl imidazoles of formula (I) in which R, R and R are identical or different and represent H, C1-C4 alkyl or phenyl, with at least one cross-linking agent, optionally with other water-soluble monoethylenically unsaturated monomers and optionally with water-insoluble monoethylenically unsaturated monomers, in the aqueous phase of a water-in-oil emulsion in the presence of at least one emulsifier made from block copolymers of the type AB or ABA or from comb copolymers built up from A and B, A being a hydrophobic polymer block with a molar mass of more than 500 g/mol and B a hydrophilic polymer block with a molar mass of more than 500 g /mol, for stabilising the water-in-oil-monomer emulsion; followed by azeotropic distillation of the water from the water-in-oil-polymer suspension emulsion and isolation of the polymers. The invention also concerns processes for producing these agglomerated finely divided cross-linked vinyl imidazole copolymers and the use of the copolymers as additives to washing products to prevent colour transfer during washing.

公开(公告)号：DE59301439D1

公开(公告)日：1996-02-29

申请号：DE59301439

申请日：1993-06-02

Applicant: BASF AG

Inventor： BRUCHMANN BERND DR ,  MINGES ROLAND DR ,  SCHADE CHRISTIAN DR

IPC: B01J31/06 ,  C07B61/00 ,  C07C263/16 ,  C07C265/14 ,  C07D229/00 ,  C08F222/08 ,  C08F226/06 ,  C08G18/79

Abstract: The invention relates to a process for the preparation of polyisocyanates containing uretdione groups by catalytic dimerisation of monomeric isocyanates, polymers bearing imidazole groups being employed as catalysts.

公开(公告)号：DE4307114A1

公开(公告)日：1994-09-08

申请号：DE4307114

申请日：1993-03-06

Applicant: BASF AG

Inventor： KRONER MATTHIAS DR ,  SCHORNICK GUNNAR DR ,  BOECKH DIETER DR ,  BAUR RICHARD DR ,  POTTHOFF-KARL BIRGIT DR ,  SCHWENDEMANN VOLKER DR ,  SCHADE CHRISTIAN DR ,  KUD ALEXANDER DR

IPC: C08G69/08 ,  C08G69/10 ,  C08G73/00 ,  C08G73/10 ,  C09K23/52 ,  C11D3/37 ,  C08G69/48 ,  B01F17/52 ,  C02F5/12

Abstract: PCT No. PCT/EP94/00511 Sec. 371 Date Sep. 6, 1995 Sec. 102(e) Date Sep. 6, 1995 PCT Filed Feb. 23, 1994 PCT Pub. No. WO94/20563 PCT Pub. Date Sep. 15, 1994Process for the preparation of products of the reaction of polyaspartimides and amino acids by reaction of amino acids with polyaspartimides in aqueous medium at pH values at which at least 5% of the amino groups in the amino acids are in non-protonated form in equilibrium with the protonated form, and use of the reaction products obtainable in this way and of products of the reaction of polyaspartimides with alkanolamines or aminated C1-C30-fatty alcohol alkoxylates which contain as copolymerized units up to 50 mol % of ethylene oxide and/or propylene oxide per mol of fatty alcohol, as additive to detergents and cleaners, as scale inhibitor and as dispersant.