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公开(公告)号：ZA200502075B
公开(公告)日：2006-05-31
申请号：ZA200502075
申请日：2005-03-11
Applicant: BASF AG
Inventor： LENZ ROBERT , PASTRE JOERG , BOEHLING RALF , HAUK ALEXANDER , KARL JOERN , ADAMI CHRISTOPH
IPC: A23K1/16 , A01N1/00 , A01N3/00 , A61K31/19 , A61P3/00 , B01D9/02 , C07C20060101 , C07C51/09 , C07C51/41 , C07C53/06
Abstract: Formic acid-formates are produced by (a) partial hydrolysis of methyl formate (MF) with water, (b) distillation to give (S1) formic acid and water, (c) conversion of the other product from (b) (mainly MF) into a stream (S2) containing formate and water by reaction with aqueous strong base and distillation of methanol, and (d) combination of (S1) with (S2). A method for the production of formic acid-formates (I) involves: (a) partial hydrolysis of methyl formate (MF) with water; (b) distillation to give a stream (S1) containing formic acid and water; (c) conversion of the MF- and possibly methanol-containing stream from (b) into a formate- and water-containing stream (S2) by (i) reaction with a basic compound of an acid with a pKa value of at least 3 in presence of water followed by (ii) removal of methanol by distillation; and (d) combination of streams (S1) and (S2). An Independent claim is also included for apparatus for the production of (I), comprising: (A) a reactor for the hydrolysis of MF; (B) a distillation column for separating a stream containing MF, formic acid, methanol and water; (C) a column for the hydrolysis of MF with a basic compound with removal of methanol by distillation (with an inlet for the base above the inlet for the product from (B)); and (D) a column connected to the bottom of (B) for removing water from the stream containing formic acid and water.
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公开(公告)号：BRPI0409827A
公开(公告)日：2006-04-25
申请号：BRPI0409827
申请日：2004-05-14
Applicant: BASF AG
Inventor： HAUK ALEXANDER , ADAMI CHRISTOPH , KARL JOERN , LENZ ROBERT
Abstract: A process is proposed for preparing acid formates by providing a liquid stream I containing formic acid and a liquid stream II containing a metal formate, and mixing the liquid stream I with the liquid stream II, obtaining the corresponding acid formate, which comprises feeding, to the liquid stream I or a precursor thereof, to the liquid stream II or a precursor thereof, or to the mixture of the liquid streams I and II, a liquid stream III containing the following components at contents of in each case >0.1% by weight: metal formate, metal methoxide, methanol and MeFo (MeFo), which is produced in a process for preparing MeFo by carbonylating methanol in a reactor at a pressure up to 50 MPa absolute in the presence of a metal methoxide as homogeneous catalyst.
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公开(公告)号：BRPI0409191A
公开(公告)日：2006-04-11
申请号：BRPI0409191
申请日：2004-04-07
Applicant: BASF AG
Inventor： MACHHAMMER OTTO , CRONE SVEN , BORGMEIER FRIEDER , MUELLER-ENGEL KLAUS JOACHIM , ADAMI CHRISTOPH , DIEFENBACHER ARMIN
IPC: C07C51/215 , C07C57/05
Abstract: Disclosed is a method for the heterogeneously catalyzed partial direct oxidation of propane and/or isobutane. According to said method, target product is separated from the product gas mixture obtained in the reaction stage in a reprocessing stage, the remaining product gas mixture is divided into two partial quantities having the same composition, one partial quantity is redirected into the reaction stage while the other partial quantity is discharged, and both the reaction stage and the reprocessing stage are operated at an increased pressure.
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公开(公告)号：NO20050534A
公开(公告)日：2005-03-02
申请号：NO20050534
申请日：2005-01-31
Applicant: BASF AG
Inventor： PASTRE JORG , KARL JORN , ADAMI CHRISTOPH , HAUK ALEXANDER , LENZ ROBERT , BOHLING RALF
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公开(公告)号：NO20044447L
公开(公告)日：2004-11-18
申请号：NO20044447
申请日：2004-10-19
Applicant: BASF AG
Inventor： KAIBEL GERD , ZEHNER PETER , ROPER MICHAEL , SLANY MICHAEL , SCHAFER MARTIN , KARL JORN , ADAMI CHRISTOPH
IPC: C07C67/36
Abstract: The invention relates to a process for the preparation of methyl formate by reacting methanol with carbon monoxide at a pressure of from 0.5 to 10 MPa abs. and a temperature of from 50 to 150° C. in the presence of a metal alkoxide as catalyst in a reactor, in which a gas stream is withdrawn from the reactor, entrained methyl formate is removed from this gas stream by condensation, and all or some of the remaining gas stream is returned to the reactor as circulating-gas stream and a mean gas superficial velocity of from 1 to 20 cm/s is set in at least one region of the reactor in which the gas flows essentially in one direction.
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Patent Agency Ranking46.发明专利
公开(公告)号：AU2003277856A1
公开(公告)日：2004-04-08
申请号：AU2003277856
申请日：2003-09-12
Applicant: BASF AG
Inventor： WALSDORFF CHRISTIAN , FIENE MARTIN , ADAMI CHRISTOPH , STROFER ECKHARD , HARTH KLAUS
Abstract: Production of chlorine by catalytic gas-phase oxidation of hydrogen chloride (HCl), in which an HCl-containing gas and an oxygen-containing gas are fed into a reaction zone containing a fixed bed of catalyst to give a product gas comprising chlorine, oxygen, HCl and water vapor, comprises removing a recycle stream from the product gas and recycling it to the reaction zone.
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公开(公告)号：DE10217528A1
公开(公告)日：2003-11-06
申请号：DE10217528
申请日：2002-04-19
Applicant: BASF AG
Inventor： ADAMI CHRISTOPH , SLANY MICHAEL , KARL JOERN , KAIBEL GERD , SCHAEFER MARTIN , ZEHNER PETER , ROEPER MICHAEL
Abstract: The invention relates to a process for the preparation of methyl formate by reacting methanol with carbon monoxide at a pressure of from 0.5 to 10 MPa abs. and a temperature of from 50 to 150° C. in the presence of a metal alkoxide as catalyst in a reactor, in which a gas stream is withdrawn from the reactor, entrained methyl formate is removed from this gas stream by condensation, and all or some of the remaining gas stream is returned to the reactor as circulating-gas stream and a mean gas superficial velocity of from 1 to 20 cm/s is set in at least one region of the reactor in which the gas flows essentially in one direction.
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公开(公告)号：AU2003226810A1
公开(公告)日：2003-11-03
申请号：AU2003226810
申请日：2003-04-15
Applicant: BASF AG
Inventor： ADAMI CHRISTOPH , SLANY MICHAEL , KARL JORN , KAIBEL GERD , SCHAFER MARTIN , ZEHNER PETER , ROPER MICHAEL
Abstract: The invention relates to a process for the preparation of methyl formate by reacting methanol with carbon monoxide at a pressure of from 0.5 to 10 MPa abs. and a temperature of from 50 to 150° C. in the presence of a metal alkoxide as catalyst in a reactor, in which a gas stream is withdrawn from the reactor, entrained methyl formate is removed from this gas stream by condensation, and all or some of the remaining gas stream is returned to the reactor as circulating-gas stream and a mean gas superficial velocity of from 1 to 20 cm/s is set in at least one region of the reactor in which the gas flows essentially in one direction.
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公开(公告)号：RU2416595C2
公开(公告)日：2011-04-20
申请号：RU2007103613
申请日：2005-05-04
Applicant: BASF AG
Inventor： DIETERLE MARTIN , DIEFENBACHER ARMIN , SCHINDLER GOETZ-PETER , KLANNER CATHARINA , MUELLER-ENGEL KLAUS-JOACHIM , ADAMI CHRISTOPH
IPC: B01J8/04 , C07C45/33 , C07C45/35 , C07C47/22 , C07C51/16 , C07C51/215 , C07C51/235 , C07C51/25 , C07C57/05 , C07C57/055
Abstract: Изобретениеотноситсяк усовершенствованномуспособуснижениятемпературыгорячейточкинеподвижногослоякатализаторав процессеполученияакролеинаилиакриловойкислотыилиихсмесигетерогеннокатализируемымчастичнымокислениемв газовойфазепропена, прикоторомисходнуюсмесь 2 реакционногогаза, содержащуюпропилени молекулярныйкислород, атакжемолекулярныйазоти пропанв качествеинертныхгазов-разбавителей, вкотороймолярноеотношениемолекулярногокислородак пропилену O2:С3Н6≥1, приповышеннойтемпературепропускаютчерезнеподвижныйслойкатализатора, активнаямассакоторогопредставляетсобой, поменьшеймере, одинполиметаллическийоксид, содержащийэлементыМо, Fe и Bi, вкоторомисходнаясмесь 2 реакционногогаза, впересчетенаобщийобъем, содержитот 7 до 9 об.% пропилена, от 9,8 до 15,5 об.% молекулярногокислорода, от 10,5 до 15,5 об.% пропанаи от 40 до 60 об.% молекулярногоазота, приусловии, чтомолярноеотношение V1 содержащегосяв исходнойсмеси 2 реакционногогазапропанак содержащемусяв исходнойсмеси 2 реакционногогазапропиленусоставляетот 1,5 до 2,2, молярноеотношение V2 содержащегосяв исходнойсмеси 2 реакционногогазамолекулярногоазотак содержащемусяв исходнойсмеси 2 реакционногогазамолекулярномукислородусоставляетот 3,5 до 4,5, амолярноеотношение V3 содержащегосяв исходнойсмеси 2 реакционногогазамолекулярногокислородак содержащемусяв исходнойсмеси 2 реакционногогазапропиленусоставляетот 1,4 до 2,14. 26 з.п. ф-лы, 1 ил., 3 табл.
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公开(公告)号：MY141769A
公开(公告)日：2010-06-30
申请号：MYPI20052287
申请日：2005-05-19
Applicant: BASF AG
Inventor： DIETERLE MARTIN , DIEFENBACHER ARMIN , SCHINDLER GOETZ-PETER , KLANNER CATHARINA , MUELLER-ENGEL KLAUS JOACHIM , ADAMI CHRISTOPH
IPC: C07C45/35 , B01J8/04 , C07C45/33 , C07C51/215 , C07C51/25
Abstract: A PROCESS FOR PREPARING ACROLEIN OR ACRYLIC ACID OR A MIXTURE THEREOF BY HETEROGENEOUSLY CATALYZED PARTIAL GAS OXIDATION OF PROPYLENE, IN WHICH THE STARTING REACTION GAS MIXTURE HAS THE FOLLOWING CONTENTS: FROM 6 TO 9% BY VOLUME OF PROPYLENE, FROM 8 TO 18% BY VOLUME OF MOLECULAR OXYGEN, FROM 6 TO 30% BY VOLUME OF PROPANE AND FROM 32 TO 72% BY VOLUME OF MOLECULAR NITROGEN.
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