-
公开(公告)号:DE10144013A1
公开(公告)日:2003-03-27
申请号:DE10144013
申请日:2001-09-07
Applicant: BASF AG
Inventor: STAMMER ACHIM , FISCHER MARTIN , QUAISER STEFAN , PICKENAECKER KARIN
IPC: B01D1/00 , B01D1/28 , B01D3/14 , B01D5/00 , C01B15/013 , C01B15/029
Abstract: Process for working up aqueous hydrogen peroxide solution (I) from direct synthesis comprises: (a) removing hardly volatile inorganic impurities (II) by feeding (I) into an n-stage evaporator cascade, (where n is at least 2) and a continuous evaporator is used at least in the n-th stage, and thermal separation into steam containing H2O2 and a residue containing (II); and (b) concentration of the steam to increase the H2O2 content. An Independent claim is included for a process for producing (I) containing at most 0.001 wt.% (II) by: (i) reacting hydrogen and oxygen in aqueous medium in the presence of catalyst(s) and inorganic protonic acid(s); and (ii) working the reaction mixture up by the specified process.
-
公开(公告)号:DE10048844A1
公开(公告)日:2002-04-11
申请号:DE10048844
申请日:2000-10-02
Applicant: BASF AG
Inventor: FISCHER MARTIN , BUTZ THOMAS
IPC: B01J23/42 , B01J23/44 , B01J23/46 , B01J23/62 , B01J23/64 , B01J23/652 , B01J27/186 , B01J37/02 , B01J37/03 , C01B15/029 , C07B35/02 , C07B61/00 , C07C29/17 , C07C37/07 , C23C18/18 , C23C18/44 , B01J23/40 , B01J23/56 , B01J23/89 , B01J8/00 , C07B31/00
Abstract: The invention relates to a supported catalyst consisting of metal of the platinum group. Said catalyst can be obtained by means of controlled electroless deposition of at least one metal of the platinum group from a precipitation solution containing i) at least one homogeneously dissolved compound consisting of metal of the platinum group, ii) a reducing agent, and iii) at least one collagen selected from iospoly acids and heteropoly acids of niobium, tantalum, molybdenum, tungsten and vanadium or the salts of the same. The invention also relates to a method for hydrogenating inorganic or organic compounds using the catalyst which is produced by means of controlled electroless deposition, especially for the direct synthesis of hydrogen peroxide.
-
43.
公开(公告)号:CA2195574C
公开(公告)日:2000-10-10
申请号:CA2195574
申请日:1995-07-07
Applicant: BASF AG
Inventor: MUELLER ULRICH , LINGELBACH PETER , BASSLER PETER , HARDER WOLFGANG , ELLER KARSTEN , KOHL VERONIKA , DEMBOWSKI JUERGEN , RIEBER NORBERT , FISCHER MARTIN
IPC: C07D301/06 , B01J23/40 , B01J29/04 , B01J29/74 , B01J29/76 , B01J29/89 , C01B15/029 , C07D301/04 , C07D301/12 , C07D303/04 , B01J37/02 , B01J29/076 , C08F8/08
Abstract: In an oxidation catalyst based an a titanium or vanadium silica-lite having a zeolite structure and containing from 0.01 to 20% by weight of one or more platinum metals selected from the group consisting of ruthenium, rhodium, palladium, osmium, iridium and platinum, the platinum metals are each present in at least two different bond energy states and preferably have no metal-metal bonds.
-
公开(公告)号:DE19836477A1
公开(公告)日:2000-02-17
申请号:DE19836477
申请日:1998-08-12
Applicant: BASF AG
Inventor: FISCHER JAKOB , SIEGEL WOLFGANG , BOMM VOLKER , FISCHER MARTIN , MUNDINGER KLAUS
IPC: C07D233/90
Abstract: 1,3-Dimethylimidazolium-4-carboxylate is produced by reacting 1-methyl-imidazole with dimethyl carbonate.
-
45.
公开(公告)号:DE19817794A1
公开(公告)日:1999-10-28
申请号:DE19817794
申请日:1998-04-21
Applicant: BASF AG
Inventor: FISCHER MARTIN , STAMMER ACHIM , QUAISER STEFAN
IPC: C01B15/01 , C01B15/013 , C01B15/029 , H01L21/306
Abstract: High purity aqueous hydrogen peroxide solutions, used for electronic substrate treatment and having an extremely low total organic carbon content, are new. High purity aqueous hydrogen peroxide solutions, used for treating substrates of electronic components, have a total organic carbon content of \}100 ppb. Independent claims are also included for the following: (i) production of high purity aqueous hydrogen peroxide solutions by one of the following methods performed in water and in the absence of organic compounds and their source materials: catalytic reaction of hydrogen and oxygen, electrochemical reduction of oxygen or electrolysis of acidic ammonium sulfate solutions; and (ii) high purity aqueous hydrogen peroxide solutions produced by the above process.
-
46.
公开(公告)号:CA2328952A1
公开(公告)日:1999-10-28
申请号:CA2328952
申请日:1999-04-19
Applicant: BASF AG
Inventor: FISCHER MARTIN , STAMMER ACHIM , QUAISER STEFAN
IPC: C01B15/01 , C01B15/013 , C01B15/029 , H01L21/306
Abstract: The invention relates to highly pure aqueous hydrogen peroxide solutions for the electronics industry and to a method for producing such solutions which are essentially free from organic compounds. The invention is characterized in that, in each case in water, hydrogen and oxygen are catalytically reacted, oxygen is electrochemically reduced or acid ammonium sulfate solutions are electrolyzed. The reactions are carried out in the absence of organic compounds and materials releasing such compounds.
-
公开(公告)号:FI103790B1
公开(公告)日:1999-09-30
申请号:FI934081
申请日:1993-09-17
Applicant: BASF AG
Inventor: MASSONNE KLEMENS , FISCHER MARTIN
IPC: C07C245/02 , C07C245/06 , C07C291/08 , C07C291/02 , C07C245/04
-
公开(公告)号:CA2232338A1
公开(公告)日:1997-05-01
申请号:CA2232338
申请日:1996-10-17
Applicant: BASF AG
Inventor: FISCHER MARTIN
IPC: B01J31/02 , B01J31/40 , B01J38/00 , C07D307/28
Abstract: Described is a method of separating a catalyst from a mixture of the catalyst with oligomers of vinyl oxirane such as is produced in the isomerization of vinyl oxirane to 2,5-dihydrofuran and from which practically all the lowboiling constituents have been distilled off. The mixture of oligomers and catalyst, consisting essentially of: a) an onium iodide, b) a Lewis acid selected from the group consisting of the chloride, bromide and iodide of cobalt, bismuth, tin and zinc and optionally and c) a donor ligand is intensively mixed (1) with a hydrocarbon or chlorohydrocarbon having 5 to 14 carbon atoms; (2) of the two phases formed, the phase containing the catalyst is separated off; and (3) the catalyst is recovered by distilling off the solvent.
-
公开(公告)号:ES2098120T3
公开(公告)日:1997-04-16
申请号:ES94901917
申请日:1993-11-30
Applicant: BASF AG
Inventor: BOECK STEFAN , HERZOG KLAUS , FISCHER ROLF , VOGEL HERBERT , FISCHER MARTIN
IPC: C07D301/10 , B01J23/50 , B01J23/96 , B01J38/12 , B01J38/16 , C07D303/04
Abstract: PCT No. PCT/EP93/03352 Sec. 371 Date Mar. 17, 1995 Sec. 102(e) Date Mar. 17, 1995 PCT Filed Nov. 30, 1993 PCT Pub. No. WO94/13653 PCT Pub. Date Jun. 23, 19943,4-Epoxy-1-butene is prepared by the gas phase epoxidation of 1,3-butadiene by means of oxygen or oxygen-containing gases over silver-containing catalysts and isolation of the 3,4-epoxy-1-butene from the reaction exit mixture by performing the gas phase epoxidation in the presence of from 6 to 80 mol % of water vapor, based on the gas mixture supplied to the reactor.
-
公开(公告)号:ZA956007B
公开(公告)日:1997-01-20
申请号:ZA956007
申请日:1995-07-19
Applicant: BASF AG
Inventor: MUELLER ULRICH , LINGELBACH PETER , BASSLER PETER , HARDER WOLFGANG , ELLER KARSTEN , KOHL VERONIKA , DEMBOWSKI JUERGEN , RIEBER NORBERT , FISCHER MARTIN
IPC: C07D301/06 , B01J23/40 , B01J29/04 , B01J29/74 , B01J29/76 , B01J29/89 , C01B15/029 , C07D301/04 , C07D301/12 , C07D303/04 , B01J , C07D , C01B
Abstract: PCT No. PCT/EP95/02651 Sec. 371 Date Jan. 21, 1997 Sec. 102(e) Date Jan. 21, 1997 PCT Filed Jul. 7, 1995 PCT Pub. No. WO96/02323 PCT Pub. Date Feb. 1, 1996In an oxidation catalyst based on a titanium or vanadium silicalite having a zeolite structure and containing from 0.01 to 20% by weight of one or more platinum metals selected from the group consisting of ruthenium, rhodium, palladium, osmium, iridium and platinum, the platinum metals are each present in at least two different bond energy states and preferably have no metal-metal bonds.
-
-
-
-
-
-
-
-
-