公开(公告)号：NO20024648D0

公开(公告)日：2002-09-27

申请号：NO20024648

申请日：2002-09-27

Applicant: BASF AG

Inventor： ARNOLD HEIKO ,  ERDBRUEGGER CRISTINA FREIRE ,  HEIDEMANN THOMAS ,  MEYER GERALD ,  UNVERRICHT SIGNE ,  FRENZEL ANDREA ,  WULFF-DOERING JOACHIM ,  ANSMANN ANDREAS

IPC: B01J35/06 ,  B01J23/42 ,  B01J23/44 ,  B01J23/48 ,  B01J23/50 ,  B01J23/70 ,  B01J23/755 ,  B01J37/02 ,  C07B61/00 ,  C07C5/02 ,  C07C5/03 ,  C07C5/08 ,  C07C7/163 ,  C07C7/167 ,  C07C11/04 ,  C07C11/06 ,  C07C11/08 ,  B01J

Abstract: In a coated catalyst having a core and at least one shell surrounding the core, the core is made up of an inert support material, the shell or shells is/are made up of a porous support substance, with the shell being attached physically to the core, and a catalytically active metal selected from the group consisting of the metals of the 10th and 11th groups of the Periodic Table of the Elements is present in finely divided form or a precursor of the catalytically active metal is present in uniformly distributed form in the shell or shells. The coated catalyst of the present invention is suitable for the reduction of unsaturated hydrocarbons. Here, better selectivities than in the case of previously known coated catalysts can be achieved. A process for producing the coated catalyst is also described.

公开(公告)号：DE10046609A1

公开(公告)日：2002-04-04

申请号：DE10046609

申请日：2000-09-20

Applicant: BASF AG

Inventor： KAIBEL GERD ,  OOST CARSTEN ,  STROEZEL MANFRED ,  MEYER GERALD ,  TRUEBENBACH PETER ,  SARTOR KARL-HEINZ ,  HENERS JUERGEN

IPC: B01D3/14 ,  B01D3/32 ,  B01D3/42 ,  C07B63/00 ,  C10G7/00 ,  C10G7/02 ,  C10G7/12 ,  C07C7/04 ,  B01D3/00

Abstract: The invention relates to a method for carrying out the distillative separation of C5+ cuts into a low boiler fraction (A), a medium boiler fraction (B) and into a high boiler fraction (C) inside one or more partition columns (TK). A partition (T) is arranged inside said partition column(s) in a longitudinal direction of the column(s) while forming an upper common column area (1), a lower common column area (6), a feed part (2, 4) having a reinforcing part (2) and stripping part (4), as well as while forming a withdrawal part (3, 5) also having a reinforcing part (5) and stripping part (3). The inventive method involves the following steps: supplying the C5+ cuts (A, B, C) in the middle area of the feed part (2, 4); discharging the high boiler fraction (C) out of the bottom of the column; discharging the low boiler fraction (A) via the top of the column, and; discharging the middle boiler fraction (B) out of the middle area of the withdrawal part (3, 5). The dividing up ratio of the liquid reflux at the upper end of the partition (T) is set such that the proportion of high-boiling key constituents in the liquid reflux above the stripping part (3) of the withdrawal part at the upper end of the partition (T) ranges from 10 to 80 %, preferably, from 30 to 50 % of the limiting value permitted in the middle boiler fraction (B). In addition, the heating capacity in the bottom evaporator of the partition column (TK) is set such that the concentration of the light-boiling key constituents in the liquid at the lower end of the partition (T) ranges from 10 to 80 %, preferably, from 30 to 50 % of the limiting value permitted in the middle boiler fraction (B).

公开(公告)号：DE10033958A1

公开(公告)日：2002-01-24

申请号：DE10033958

申请日：2000-07-13

Applicant: BASF AG

Inventor： HILL THOMAS ,  KAIBEL GERD ,  MEYER GERALD ,  NIEKERKEN JOERG ,  SCHOENMAKERS HARTMUT

IPC: B01D3/14 ,  C07C41/06 ,  C07C41/42 ,  C07C7/04 ,  C07C7/05 ,  C07C7/163

Abstract: Distillation apparatus, consisting of a partitioned column or a system of thermally coupled distillation columns, includes inlet lines for a hydrocarbon mixture, hydrogen and alcohol, outlet lines for low, medium and high boilers and heterogeneous hydrogenation and etherification catalysts, all located in specific segments of the apparatus. In operation hydrogen is obtained as low boiler and ether as high boiler. Distillation apparatus consists of a partitioned column or a system of thermally coupled distillation columns, including the following segments: (a) highest region of the overall arrangement; (b) concentration region of the feed unit; (c) distillation region of the feed unit; (d) upper region of the withdrawal unit; (e) lower region of the withdrawal unit; and (f) lowest region of the overall arrangement. Also provided are: a hydrocarbon mixture inlet point between segments (b) and (c); a medium boilers outlet point between (d) and (e); a low boilers outlet point in (a); a low boilers outlet point in (f); at least one hydrogen inlet point below (a); at least one alcohol inlet point in (a), (b) and/or (c); inserts containing a heterogeneous hydrogenation catalyst in (a), (d), (e) and/or (f); and inserts containing a heterogeneous etherification catalyst in (a), (b), (c) and/or (f). In operation hydrogen is obtained as low boiler and ether as high boiler. An Independent claim is included for a process for reactive distillation of hydrocarbon mixtures using the apparatus.

公开(公告)号：DE10022465A1

公开(公告)日：2001-11-15

申请号：DE10022465

申请日：2000-05-09

Applicant: BASF AG

Inventor： MEYER GERALD ,  KAIBEL GERD ,  BOHNER GERD ,  KINDLER KLAUS

IPC: C07C7/08 ,  B01D3/14 ,  B01D3/40 ,  C07C5/09 ,  C07C7/00 ,  C07C11/167 ,  C10G7/08 ,  C10G70/00 ,  C10G70/02

Abstract: Processing of a 4C cut from the fractionation of crude oil comprises: (A) extractive distillation; (B) selective hydrogenation by heterogeneous catalysis; and (C) distillation to obtain 1,3-butadiene whereby steps (A) and (B) are carried out in individual columns or thermally coupled columns and step (C) is carried out in a second column. An Independent claim is also included for an apparatus to carry out the process comprising a separating wall column (TK) in which the separating wall lies in the longitudinal axis of the column to form a common upper column section (1), a common lower column section (6), inlet sections (2a, 2b, 4) and outlets sections (3a, 3b, 5a, 5b) whereby hydrogen (H) is added to the lower section (6); unreacted hydrogen is separated from the vapor stream of condensable light boiling components from (TK) in a condenser (K) with recycle via a compressor (V) to the lower section (6); with passage of the 1,3-butadiene containing stream (B) from the outlet sections (3a, 3b, 5a, 5b) of (TK) at a position beneath the inlet (F) for sections (2a, 2b, 4); and passage of the stream (B) for purification by distillation (step (C)).

公开(公告)号：AU6015001A

公开(公告)日：2001-10-08

申请号：AU6015001

申请日：2001-03-23

Applicant: BASF AG

Inventor： ARNOLD HEIKO ,  ERDBRUGGER CRISTINA FREIRE ,  HEIDEMANN THOMAS ,  MEYER GERALD ,  UNVERRICHT SIGNE ,  FRENZEL ANDREA ,  WULFF-DORING JOACHIM ,  ANSMANN ANDREAS

IPC: B01J35/06 ,  B01J23/42 ,  B01J23/44 ,  B01J23/48 ,  B01J23/50 ,  B01J23/70 ,  B01J23/755 ,  B01J37/02 ,  C07B61/00 ,  C07C5/02 ,  C07C5/03 ,  C07C5/08 ,  C07C7/163 ,  C07C7/167 ,  C07C11/04 ,  C07C11/06 ,  C07C11/08

Abstract: In a coated catalyst having a core and at least one shell surrounding the core, the core is made up of an inert support material, the shell or shells is/are made up of a porous support substance, with the shell being attached physically to the core, and a catalytically active metal selected from the group consisting of the metals of the 10th and 11th groups of the Periodic Table of the Elements is present in finely divided form or a precursor of the catalytically active metal is present in uniformly distributed form in the shell or shells. The coated catalyst of the present invention is suitable for the reduction of unsaturated hydrocarbons. Here, better selectivities than in the case of previously known coated catalysts can be achieved. A process for producing the coated catalyst is also described.

公开(公告)号：CA2403899A1

公开(公告)日：2001-10-04

申请号：CA2403899

申请日：2001-03-23

Applicant: BASF AG

Inventor： WULFF-DORING JOACHIM ,  UNVERRICHT SIGNE ,  FREIRE ERDBRUGGER CRISTINA ,  MEYER GERALD ,  ARNOLD HEIKO ,  ANSMANN ANDREAS ,  FRENZEL ANDREA ,  HEIDEMANN THOMAS

IPC: B01J35/06 ,  B01J23/42 ,  B01J23/44 ,  B01J23/48 ,  B01J23/50 ,  B01J23/70 ,  B01J23/755 ,  B01J37/02 ,  C07B61/00 ,  C07C5/02 ,  C07C5/03 ,  C07C5/08 ,  C07C7/163 ,  C07C7/167 ,  C07C11/04 ,  C07C11/06 ,  C07C11/08

Abstract: The invention relates to a shell catalyst with a core and at least one shell surrounding the core, said core being composed of an inert carrier material, and the at least one shell being composed of a porous carrier substance. The shell is physically adhered to the core and the at least one shell contains a catalytically active metal selected from the group of metals of the 10th and 11th group of the periodic table of elements in a finely divided form, or a precursor of the catalytically active metal in a uniformly divided form. The inventive shell catalyst is suitable for reducing unsaturated hydrocarbons a nd allows for better selectivities in comparison with shell catalysts known so far. The invention further relates to a method for producing the inventive shell catalyst.

公开(公告)号：DE19854635A1

公开(公告)日：2000-05-31

申请号：DE19854635

申请日：1998-11-26

Applicant: BASF AG

Inventor： MEYER GERALD ,  SCHWAB EKKEHARD ,  LANDES HELMUT ,  KNOEZINGER HELMUT

IPC: B01J21/06 ,  B01J23/38 ,  B01J37/02 ,  B01J37/08 ,  B01J31/16 ,  B01J31/12 ,  C07B35/04

Abstract: Catalyst contains a catalytically active metal in the form of its chloride-free dissolved amine complexes, aetylacetonate or allyl complexes on a modified carrier. An Independent claim is also included for a process for the production of the catalyst comprising: (a) thermally treating the carrier material; (b) impregnating the carrier material with a modifier in the gas or liquid phase; (c) optionally hydrolyzing the modified carrier material at 20-200 degrees C in O2 or in air or in a H2O-containing gas stream; (d) optionally drying at 100-500 degrees C; (e) optionally calcining at 200-1000 degrees C; (f) applying the catalytically active metal by impregnating or ion exchange; (g) drying at 20-500 degrees C; and (h) optionally calcining at up to 1000 degrees C.

公开(公告)号：BR9713939A

公开(公告)日：2000-03-21

申请号：BR9713939

申请日：1997-12-10

Applicant: BASF AG

Inventor： FISCHER JAKOB ,  SIEGEL WOLFGANG ,  MUNDINGER KLAUS ,  MEYER GERALD

IPC: C07C7/167 ,  C07C253/10 ,  C07C255/04 ,  C07C255/07

Abstract: The disclosure is a process for preparing mixtures of monoolefinic C5 mononitriles having nonconjugated C=C- and C=N bonding by catalytic hydrocyanation of a hydrocarbon mixture containing 1,3-butadiene, by first diminishing the proportion of those components in the hydrocarbon mixture which impair the catalytic hydrocyanation and then subjecting the resulting mixture to catalytic hydrocyanation.

公开(公告)号：CA2264305A1

公开(公告)日：1999-09-27

申请号：CA2264305

申请日：1999-03-25

Applicant: BASF AG

Inventor： MEYER GERALD ,  SCHWAB PETER ,  BREITSCHEIDEL BORIS ,  SCHULZ RALF ,  SCHULZ MICHAEL

IPC: B01J23/36 ,  C07B61/00 ,  C07C6/02 ,  C07C7/163 ,  C07C11/06 ,  C07C41/06 ,  C10G35/06 ,  C07C11/02 ,  C07C7/08

Abstract: The preparation of olefins from steam cracker or refinery C4 streams is carried out by A) if desired, extractive distillation of butadiene from the C4 stream using a butadiene-selective solvent, B) selective hydrogenation of butadienes and acetylenic impurities in the steam cracker or refinery C4 stream or the stream from step A), with simultaneous or subsequent, at least partial isomerization of 1-butene to 2-butene, C) removal of i-butene from the C4 stream obtained in step B) by reaction with an alcohol to form an ether, D) removal of oxygen-containing impurities from the C4 stream obtained in step C) using adsorber materials, E) two-stage metathesis of the butenes in the C4 stream obtained in step D) by conversion of 1-butene and 2-butene present in the C4 stream into propene and 2-pentene and subsequent reaction of the 2-pentene with ethene in the presence of a metathesis catalyst to form propene and 1-butene.

公开(公告)号：ZA977945B

公开(公告)日：1999-03-04

申请号：ZA977945

申请日：1997-09-04

Applicant: BASF AG

Inventor： FLICK KLEMENS ,  ERDBRUEGGER CHRISTINA F ,  BROECKER FRANZ JOSEF ,  MEYER GERALD ,  SCHWAB EKKEHARD ,  HERION CHRISTOF

IPC: B01J23/56 ,  B01J23/38 ,  B01J23/44 ,  B01J23/50 ,  B01J23/60 ,  B01J23/62 ,  B01J35/06 ,  B01J37/02 ,  C07B61/00 ,  C07C5/05 ,  C07C5/09 ,  C07C7/163 ,  C07C11/02 ,  C07C11/06 ,  C07C11/08 ,  C07C ,  B01J ,  C10G

Abstract: Process for hydrogenating unsaturated 2-8 C hydrocarbons, especially 2-8 C alkynes and/or 4-8 C alkynenes and/or 4-8 C alkadienes into fluid containing them comprises contacting with a catalyst in the presence of hydrogen. The catalyst is produced by applying an active material as catalyst and/or promoter on a gauze or foil as support. Also claimed is a process for catalytic distillation comprising the above hydrogenation with simultaneous distillation or rectification on the catalyst.