44.
    发明专利
    未知

    公开(公告)号:DE59906941D1

    公开(公告)日:2003-10-16

    申请号:DE59906941

    申请日:1999-12-22

    Applicant: BASF AG

    Abstract: Preparation of guanidine derivatives (I) comprises reacting O-alkylisourea salts (II) with an amine (III) in the presence of seed crystals of (I). Preparation of guanidine derivatives of formula (I) comprises reacting O-alkylisourea salts of formula (II) with an amine of formula (III) in the presence of seed crystals of (I). R1 = 1-8C alkylene or a divalent 5-10C cycloaliphatic group; R2 = H or 1-8C alkyl; or NR1R2 = 5-6 membered ring substituted by Z; Z = COOR3, SO2OR3 or PO(OR3)(OR4); R3 = H, alkalimetal or an equivalent of an alkaline earth metal; and R4 = as for R3 or 1-6C alkyl; R5 = 1-8C alkyl; X = equivalent of an anion.

    Method for isolating methyl glycine nitrile-N,N-diacetonitriles from an aqueous crude mixture

    公开(公告)号:AU2006245831B2

    公开(公告)日:2011-02-24

    申请号:AU2006245831

    申请日:2006-05-03

    Applicant: BASF AG

    Abstract: The invention relates to a process for isolating methylglycinenitrile-N,N-diacetonitrile (MGDN) from an aqueous emulsion which comprises MGDN and has an MGDN content of 3-50% by weight in a crystallizer, comprising the steps: (a) the aqueous emulsion is, starting from a temperature above the solidification point, cooled to a temperature below the solidification point, the cooling rate averaged over time not exceeding 5 K/h, until substantially the entirety of the emulsified MGDN has solidified, (b) the resulting aqueous suspension is cooled further and/or concentrated, and the cooling rate may be greater than in step (a).

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