45.
    发明专利
    未知

    公开(公告)号:DE59405315D1

    公开(公告)日:1998-04-02

    申请号:DE59405315

    申请日:1994-05-17

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP94/01591 Sec. 371 Date Nov. 9, 1995 Sec. 102(e) Date Nov. 9, 1995 PCT Filed May 17, 1994 PCT Pub. No. WO94/28042 PCT Pub. Date Dec. 8, 1994Multiphase block copolymers of propylene comprising a) a polymer of propylene with from 0 to 5% by weight of further C2-C10 1-alkenes, b) a copolymer of propylene with from 5 to 98% by weight of further C2-C10 1-alkenes, the multiphase block copolymers having a melting point of less than 155 DEG C. and a stiffness (shear modulus G) conforming to the following condition (I): (I) where Ma) denotes the amount of propylene polymer a) and Mco denotes the amount of the multiphase block copolymer. are obtainable in particular by polymerization by means of metallocene-containing catalyst systems.\!

    50.
    发明专利
    未知

    公开(公告)号:ES2084490T3

    公开(公告)日:1996-05-01

    申请号:ES93906586

    申请日:1993-03-23

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP93/00694 Sec. 371 Date Jun. 13, 1994 Sec. 102(e) Date Jun. 13, 1994 PCT Filed Mar. 23, 1993 PCT Pub. No. WO93/20113 PCT Pub. Date Oct. 14, 1993.Catalyst systems for the polymerization of C2-C10-alk-1-enes contain, as active components, a) a metallocene complex of the general formula I III, IV or v of the Periodic Table of elements or a metal selected from the group consisting of the lanthanides, X is fluorine, chlorine, bromine, iodine, hydrogen, C1-C10-alkyl, C6-C15-aryl or -OR7, R7 is C1-C10-alkyl, C6-C15-aryl, alkylaryl, arylalkyl, fluoroalkyl or fluoroaryl, in each case having 1 to 10 carbon atoms in the alkyl radical and 6 to 20 carbon atoms in the aryl radical, n is the valency of M minus two, R1 to R6 are each hydrogen, C1-C10-alkyl, 5-membered to 7-membered cycloalkyl which in turn may carry C1-C10-alkyl as a substituent, C6-C15-aryl or arylalkyl, where two adjacent radicals together may furthermore form a cyclic group of 4 to 15 carbon atoms, or Si(R8)3, R8 is C1-C10-alkyl, C6-C15-aryl or C3-C10-cycloalkyl, E1 and E2 are independent of one another and are each Si(R9)2, Ge(R9)2, Sn(R9)2 or C(R9)2-C(R9)2 and R9 is C1-C10-alkyl, C3-C10-cycloalkyl or C6-C15-aryl, and b) an open-chain or cyclic alumoxane compound of the general formula II or III II n integer of from 5 to 30.

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